摘要:
Cyanoacrylate adhesive compositions which employ calixarene compounds as additives give substantially reduced fixture and cure times on de-activating substrates such as wood. The calixarene compounds are preferably employed at levels of about 0.1-1% by weight of the composition.The calixarene compounds particularly useful in this invention may be represented by the formula: ##STR1## where R.sup.1 is alkyl, alkoxy, substituted alkyl or substituted alkoxy; R.sup.2 is H or alkyl; and n=4, 6 or 8.
摘要翻译:使用杯芳烃化合物作为添加剂的氰基丙烯酸酯粘合剂组合物在去活化底物例如木材上显着降低夹具和固化时间。 杯芳烃化合物优选以组合物重量的约0.1-1%的量使用。 特别可用于本发明的杯芳烃化合物可以由下式表示:其中R 1是烷基,烷氧基,取代的烷基或取代的烷氧基; R2是H或烷基; n = 4,6或8。
摘要:
Cyanoacrylate adhesive compositions which employ calixarene compounds as accelerators give substantially reduced fixture and cure times on de-activating substrates such as wood. The calixarene compounds are preferably employed at levels of about 0.1-1% by weight of the composition.The calixarene compounds particularly useful in this invention may be represented by the formula: ##STR1## where R.sup.1 is alkyl, alkoxy, substituted alkyl or substituted alkoxy; R.sup.2 is H or alkyl; and n=4, 6, or 8.
摘要:
Cyanoacrylate adhesive compositions which employ calixarene compounds as additives give substantially reduced fixture and cure times on de-activating substrates such as wood. The calixarene compounds are preferably employed at levels of about 0.1-1% by weight of the composition. The calixarene compounds particularly useful in this invention may be represented by the formula: ##STR1## where R.sup.1 is alkyl, alkoxy, substituted alkyl or substituted alkoxy; R.sup.2 is H or alkyl; and n=4, 6, or 8.The compositions are further characterized by a thickener component, which may suitably be selected from various polymers such as poly(methyl methacrylate), methacrylate type copolymers, acrylic rubbers, polyvinyl acetate and poly(.alpha.-cyanoacrylate) or silicas treated with polydialkylsiloxanes or trialkylsilanes.
摘要:
Polyfunctional cationically polymerizable styryloxy compound of the formula ##STR1## where R.sup.1 and R.sup.2 are H, or one of R.sup.1 and R.sup.2 are H and the other is methyl; R.sup.3 and R.sup.4 are H, lower alkyl, or alkoxy if R.sup.2 is not methyl; R.sup.5 is a divalent hydrocarbon radical; G is any multivalent organic or inorganic radical free of amino, aliphatic hydroxyl, aliphatic thiol or other groups which interfere with cationic polymerization; and n is an integer of two or more.
摘要:
A curable thiol-ene formulation comprising(a) a polythiol(b) a 'ene compound having a plurality of groups of the formula: ##STR1## where Q is CH.sub.2, CHCH.sub.3, C(Ch.sub.3).sub.2, O, S, NR.sup.1 or SO.sub.2 R.sup.1 is H or alkyl, and m is 0-10, and(c) an effective amount of a free radical initiator.
摘要:
Compositions useful as UV curable conformal coatings are mixtures, substantially free of isocyanate condensation catalyst, of the following constituents:(i) a compound having two or more alkenyl or alkynyl groups;(ii) a compound having two or more mercapto groups;(iii) a compound having two or more isocyanate groups; and(iv) a free radical photoinitiator.The composition cures by a secondary mechanism in shadow areas and has a long pot life, for example 8-24 hours.
摘要:
Polymerization of acid activated compositions of acrylic monomers, peroxy initiators and ferrocene derivatives is inhibited by addition of 0.5-20% of a vinyl ether monomer. Bulk compositions activated by addition of a strong acid can be provided with a desired polymerization induction time directly related to the concentration of the vinyl ether. Compositions containing compounds which decompose to a strong acid upon exposure to actinic radiation, thereby activating polymerization, have increased shelf lives when vinyl ethers are included therein. The use of vinyl ether monomers having a functionality of two or more also provides increased adhesive bond strength after curing.
摘要:
Polyfunctional cationically polymerizable styryloxy compound of the formula ##STR1## where R.sup.1 and R.sup.2 are H, or one of R.sup.1 and R.sup.2 are H and the other is methyl; R.sup.3 and R.sup.4 are H, lower alkyl, or alkoxy if R.sup.2 is not methyl; R.sup.5 is a divalent hydrocarbon radical; G is any multivalent organic or inorganic radical free of amino, aliphatic hydroxyl, aliphatic thiol or other groups which interfere with cationic polymerization; and n is an integer of two or more.
摘要:
The present invention relates to dual curing compositions, which cure with moisture and photo radiation, such as UV light, and methods for preparing and using same. In particular, the compositions of the present invention contain a polyether or polyester backbone, photocurable portion(s) and moisture curable portion(s). The photo curable portion is a urethane or carbamate linkage terminated with a (meth)acryloxyalkyl group. The moisture curable portion is either: (1) a portion terminated with a polyalkoxysilyl group; or (2) a portion having a urea linkage terminated with an alkylpolyalkoxysilyl group.
摘要:
The subject invention provides a work support apparatus (20) including a spring pin assembly (32) for biasing a work piece (22) against a work stop (24), which includes a table (26) having a recess (30) with the spring pin assembly (32) disposed therein. The spring pin assembly (32) includes a housing having a side wall (48) and a top wall (50) having a circular opening (52) therethrough and a domed inner surface (54) extending upwardly from the side wall (48). A retaining pin (40) having a flat bottom surface (56) and a semi-spherical bottom portion (58) is urged against the domed inner surface (54) by a compression spring (42). A spring cup (44) transmits forces between the compression spring (42) and the flat bottom surface (56) of the retaining pin (40). A tool receiving device receives a tool for operating a holding mechanism (34) for securing the spring pin assembly (32) in the recess (30) such that the spring pin assembly (32) is removable from the top surface (28) of the table (26).