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1.发明授权公开(公告)号：US08404910B2
公开(公告)日：2013-03-26
申请号：US12707408
申请日：2010-02-17
IPC分类号： C07C1/00
CPC分类号： C10G3/45 , C01B3/12 , C01B3/323 , C01B3/38 , C01B2203/0233 , C01B2203/0283 , C01B2203/1211 , C01B2203/1241 , C10B49/22 , C10B53/02 , C10B57/06 , C10C5/00 , C10G3/50 , C10G2300/1011 , Y02E50/14 , Y02P20/145 , Y02P30/20
摘要： Methods are provided for producing low oxygen biomass-derived pyrolysis oil from carbonaceous biomass feedstock. The carbonaceous biomass feedstock is pyrolyzed in the presence of a steam reforming catalyst to produce char and pyrolysis gases. During pyrolysis, a portion of the oxygenated hydrocarbons in the pyrolysis gases is converted into hydrocarbons by steam reforming also yielding carbon oxides and hydrogen gas. The hydrogen gas at least partially deoxygenates a residual portion of the oxygenated hydrocarbons. Additional hydrogen gas may also be produced by water-gas shift reactions to deoxygenate the residual portion of the oxygenated hydrocarbons in the pyrolysis gases. Deoxygenation may occur in the presence of a hydroprocessing catalyst. A condensable portion of the pyrolysis gases is condensed to form low oxygen biomass-derived pyrolysis oil.
摘要翻译： 提供用于从含碳生物质原料生产低氧生物质衍生的热解油的方法。 碳水生物质原料在蒸汽重整催化剂存在下热解生成焦炭和裂解气。 在热解过程中，热分解气体中的一部分氧化烃通过也可产生碳氧化物和氢气的蒸汽重整转化为烃。 氢气至少部分地使氧化烃的残留部分脱氧。 还可以通过水煤气变换反应产生另外的氢气，以使热解气体中的氧化烃的残余部分脱氧。 脱氧可能在加氢处理催化剂存在下进行。 热解气体的可冷凝部分被冷凝以形成低氧生物质衍生的热解油。
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2.发明申请公开(公告)号：US20110201854A1
公开(公告)日：2011-08-18
申请号：US12707408
申请日：2010-02-17
IPC分类号： C10G1/00
CPC分类号： C10G3/45 , C01B3/12 , C01B3/323 , C01B3/38 , C01B2203/0233 , C01B2203/0283 , C01B2203/1211 , C01B2203/1241 , C10B49/22 , C10B53/02 , C10B57/06 , C10C5/00 , C10G3/50 , C10G2300/1011 , Y02E50/14 , Y02P20/145 , Y02P30/20
摘要： Methods are provided for producing low oxygen biomass-derived pyrolysis oil from carbonaceous biomass feedstock. The carbonaceous biomass feedstock is pyrolyzed in the presence of a steam reforming catalyst to produce char and pyrolysis gases. During pyrolysis, a portion of the oxygenated hydrocarbons in the pyrolysis gases is converted into hydrocarbons by steam reforming also yielding carbon oxides and hydrogen gas. The hydrogen gas at least partially deoxygenates a residual portion of the oxygenated hydrocarbons. Additional hydrogen gas may also be produced by water-gas shift reactions to deoxygenate the residual portion of the oxygenated hydrocarbons in the pyrolysis gases. Deoxygenation may occur in the presence of a hydroprocessing catalyst. A condensable portion of the pyrolysis gases is condensed to form low oxygen biomass-derived pyrolysis oil.
摘要翻译： 提供用于从含碳生物质原料生产低氧生物质衍生的热解油的方法。 碳水生物质原料在蒸汽重整催化剂存在下热解生成焦炭和裂解气。 在热解过程中，热分解气体中的一部分氧化烃通过也可产生碳氧化物和氢气的蒸汽重整转化为烃。 氢气至少部分地使氧化烃的残留部分脱氧。 还可以通过水煤气变换反应产生另外的氢气，以使热解气体中的氧化烃的残余部分脱氧。 脱氧可能在加氢处理催化剂存在下进行。 热解气体的可冷凝部分被冷凝以形成低氧生物质衍生的热解油。
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3.发明授权公开(公告)号：US08519203B2
公开(公告)日：2013-08-27
申请号：US12707433
申请日：2010-02-17
IPC分类号： C01C1/00
摘要： Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.
摘要翻译： 提供了低氧生物质衍生的热解油及其从碳质生物质原料生产它们的方法。 在含有贱金属基催化剂，贵金属基催化剂，经处理的沸石催化剂或其组合的催化剂存在下，碳质生物质原料热解产生裂解气。 在热解期间，催化剂催化脱氧反应，由此将热解气体中的至少一部分氧化烃转化成烃。 作为碳氧化物和水除去氧气。 热解气体的可冷凝部分（蒸汽）被冷凝成低氧生物质衍生的裂解油。
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4.发明申请公开(公告)号：US20110201855A1
公开(公告)日：2011-08-18
申请号：US12707433
申请日：2010-02-17
IPC分类号： C10G1/00
摘要： Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.
摘要翻译： 提供了低氧生物质衍生的热解油及其从碳质生物质原料生产它们的方法。 在含有贱金属基催化剂，贵金属基催化剂，经处理的沸石催化剂或其组合的催化剂存在下，碳质生物质原料热解产生裂解气。 在热解期间，催化剂催化脱氧反应，由此将热解气体中的至少一部分氧化烃转化成烃。 作为碳氧化物和水除去氧气。 热解气体的可冷凝部分（蒸汽）被冷凝成低氧生物质衍生的裂解油。
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公开(公告)号：US08884055B2
公开(公告)日：2014-11-11
申请号：US13155553
申请日：2011-06-08
申请人： Alakananda Bhattacharyya , Joseph A. Kocal , Joel T. Walenga , Nikolay Y. Adonin , Nina I. Kuznetsova , Bair S. Bal'zhinimaev
发明人： Alakananda Bhattacharyya , Joseph A. Kocal , Joel T. Walenga , Nikolay Y. Adonin , Nina I. Kuznetsova , Bair S. Bal'zhinimaev
IPC分类号： C07C51/16 , C07C51/265
CPC分类号： C07C51/265 , C07C51/42 , Y02P20/52 , Y02P20/542 , C07C63/26
摘要： A solid terephthalic acid composition and a process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, and a catalyst; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an dialkyl imidazolium ionic liquid; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. The solid terephthalic acid composition comprises, less than about 4,000 ppm-wt 4-carboxybenzaldehyde content, and more than about 2,000 ppm-wt a para-toluic acid.
摘要翻译： 固体对苯二甲酸组合物和由对二甲苯生产对苯二甲酸的方法。 该方法包括形成包含对二甲苯，溶剂，溴源和催化剂的混合物; 并通过在氧化条件下将氧化剂与氧化剂接触来氧化对二甲苯以产生包含对苯二甲酸，对甲苯甲酸，4-羧基苯甲醛的固体氧化产物。 溶剂包括具有1至7个碳原子的羧酸和二烷基咪唑鎓离子液体; 催化剂包括钴，钛，锰，铬，铜，镍，钒，铁，钼，锡，铈和锆中的至少一种。 固体对苯二甲酸组合物包含小于约4,000ppm重量的4-羧基苯甲醛含量和大于约2,000ppm重量的对甲苯甲酸。
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公开(公告)号：US08222465B2
公开(公告)日：2012-07-17
申请号：US13193227
申请日：2011-07-28
申请人： Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
发明人： Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
CPC分类号： C07C29/132 , C10G3/44 , C10G3/46 , C10G3/48 , C10G3/52 , C10G3/56 , C10G2300/1014 , Y02P20/52 , Y02P30/20 , C07C31/202 , C07C31/205
摘要： A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
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公开(公告)号：US20120004449A1
公开(公告)日：2012-01-05
申请号：US13155519
申请日：2011-06-08
申请人： Alakananda Bhattacharyya , Joseph A. Kocal , Joel T. Walenga , Nikolay Y. Adonin , Nina L. Kuznetsova , Bair S. Bal'zhinimaev
发明人： Alakananda Bhattacharyya , Joseph A. Kocal , Joel T. Walenga , Nikolay Y. Adonin , Nina L. Kuznetsova , Bair S. Bal'zhinimaev
IPC分类号： C07C51/265 , C07C51/42 , C07C51/16
CPC分类号： C07C51/265 , C07C63/16 , C07C63/24 , C07C63/26 , C07C63/06
摘要： A process and a mixture for oxidizing an alkyl-aromatic compound comprises forming a mixture comprising the alkyl-aromatic compound, a solvent, a bromine source, and a catalyst; and contacting the mixture with an oxidizing agent at oxidizing conditions to produce an oxidation product comprising at least one of an aromatic aldehyde, an aromatic alcohol, an aromatic ketone, and an aromatic carboxylic acid. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an ionic liquid selected from the group consisting of an imidazolium ionic liquid, a pyridinium ionic liquid, a phosphonium ionic liquid, a tetra alkyl ammonium ionic liquid, and combinations thereof. The catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium.
摘要翻译： 用于氧化烷基 - 芳族化合物的方法和混合物包括形成包含烷基 - 芳族化合物，溶剂，溴源和催化剂的混合物; 以及在氧化条件下使所述混合物与氧化剂接触以产生包含芳族醛，芳族醇，芳族酮和芳族羧酸中的至少一种的氧化产物。 溶剂包括具有1至7个碳原子的羧酸和选自咪唑鎓离子液体，吡啶鎓离子液体，鏻离子液体，四烷基铵离子液体及其组合的离子液体。 催化剂包括钴，钛，锰，铬，铜，镍，钒，铁，钼，锡，铈和锆中的至少一种。
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公开(公告)号：US20110313210A1
公开(公告)日：2011-12-22
申请号：US13193227
申请日：2011-07-28
申请人： Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
发明人： Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
IPC分类号： C07C31/20
CPC分类号： C07C29/132 , C10G3/44 , C10G3/46 , C10G3/48 , C10G3/52 , C10G3/56 , C10G2300/1014 , Y02P20/52 , Y02P30/20 , C07C31/202 , C07C31/205
摘要： A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
摘要翻译： 以包含纤维素的原料生成至少一种多元醇的催化方法是以连续方式进行的。 该方法包括使含有纤维素的氢，水和原料与催化剂连续地接触，以产生包含至少一种多元醇，水，氢和至少一种共同产物的流出物流。 将水，氢和至少一种副产物与流出物流分离并再循环至反应区。 从流出物流中回收多元醇。
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公开(公告)号：US20110313209A1
公开(公告)日：2011-12-22
申请号：US13193200
申请日：2011-07-28
申请人： Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
发明人： Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
IPC分类号： C07C29/74
CPC分类号： C07C29/132 , C07C31/20
摘要： A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
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公开(公告)号：US08039682B2
公开(公告)日：2011-10-18
申请号：US12402078
申请日：2009-03-11
申请人： Michael J. McCall , Joseph A. Kocal , Alakananda Bhattacharyya , Tom N. Kalnes , Timothy A. Brandvold
发明人： Michael J. McCall , Joseph A. Kocal , Alakananda Bhattacharyya , Tom N. Kalnes , Timothy A. Brandvold
IPC分类号： C10G1/00
CPC分类号： C10G3/47 , C10G3/46 , C10G3/49 , C10G3/52 , C10G45/02 , C10G45/58 , C10G47/00 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/08 , Y02P30/20
摘要： A hydrocarbon product stream having hydrocarbons with boiling points in the aviation fuel range is produced from renewable feedstocks such as plant and animal oils. The process involves treating a renewable feedstock by hydrogenating, deoxygenating, isomerization, and selectively hydrocracking the feedstock to produce paraffinic hydrocarbons having from about 9 to about 16 carbon atoms and a high iso/normal ratio in a single reaction zone containing a multifunctional catalyst, or set of catalysts, having hydrogenation, deoxygenation, isomerization and selective hydrocracking functions.
摘要翻译： 在航空燃料范围内具有沸点的烃的烃产物流由可再生原料如植物油和动物油生产。 该方法包括通过氢化，脱氧，异构化和选择性加氢裂解原料来处理可再生原料，以在含有多官能催化剂的单个反应区中产生具有约9至约16个碳原子的链烷烃和高异/正常比例，或 具有氢化，脱氧，异构化和选择性加氢裂化功能的催化剂组。
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