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公开(公告)号:US08039682B2
公开(公告)日:2011-10-18
申请号:US12402078
申请日:2009-03-11
申请人: Michael J. McCall , Joseph A. Kocal , Alakananda Bhattacharyya , Tom N. Kalnes , Timothy A. Brandvold
发明人: Michael J. McCall , Joseph A. Kocal , Alakananda Bhattacharyya , Tom N. Kalnes , Timothy A. Brandvold
IPC分类号: C10G1/00
CPC分类号: C10G3/47 , C10G3/46 , C10G3/49 , C10G3/52 , C10G45/02 , C10G45/58 , C10G47/00 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/08 , Y02P30/20
摘要: A hydrocarbon product stream having hydrocarbons with boiling points in the aviation fuel range is produced from renewable feedstocks such as plant and animal oils. The process involves treating a renewable feedstock by hydrogenating, deoxygenating, isomerization, and selectively hydrocracking the feedstock to produce paraffinic hydrocarbons having from about 9 to about 16 carbon atoms and a high iso/normal ratio in a single reaction zone containing a multifunctional catalyst, or set of catalysts, having hydrogenation, deoxygenation, isomerization and selective hydrocracking functions.
摘要翻译: 在航空燃料范围内具有沸点的烃的烃产物流由可再生原料如植物油和动物油生产。 该方法包括通过氢化,脱氧,异构化和选择性加氢裂解原料来处理可再生原料,以在含有多官能催化剂的单个反应区中产生具有约9至约16个碳原子的链烷烃和高异/正常比例,或 具有氢化,脱氧,异构化和选择性加氢裂化功能的催化剂组。
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公开(公告)号:US20090283442A1
公开(公告)日:2009-11-19
申请号:US12402078
申请日:2009-03-11
申请人: Michael J. McCall , Joseph A. Kocal , Alakananda Bhattacharyya , Tom N. Kalnes , Timothy A. Brandvold
发明人: Michael J. McCall , Joseph A. Kocal , Alakananda Bhattacharyya , Tom N. Kalnes , Timothy A. Brandvold
CPC分类号: C10G3/47 , C10G3/46 , C10G3/49 , C10G3/52 , C10G45/02 , C10G45/58 , C10G47/00 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/08 , Y02P30/20
摘要: A hydrocarbon product stream having hydrocarbons with boiling points in the aviation fuel range is produced from renewable feedstocks such as plant and animal oils. The process involves treating a renewable feedstock by hydrogenating, deoxygenating, isomerization, and selectively hydrocracking the feedstock to produce paraffinic hydrocarbons having from about 9 to about 16 carbon atoms and a high iso/normal ratio in a single reaction zone containing a multifunctional catalyst, or set of catalysts, having hydrogenation, deoxygenation, isomerization and selective hydrocracking functions.
摘要翻译: 在航空燃料范围内具有沸点的烃的烃产物流由可再生原料如植物油和动物油生产。 该方法包括通过氢化,脱氧,异构化和选择性加氢裂解原料来处理可再生原料,以在含有多官能催化剂的单个反应区中产生具有约9至约16个碳原子的链烷烃和高异/正常比例,或 具有氢化,脱氧,异构化和选择性加氢裂化功能的催化剂组。
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公开(公告)号:US20090253947A1
公开(公告)日:2009-10-08
申请号:US12418986
申请日:2009-04-06
CPC分类号: C10L1/04 , C10B53/02 , C10G3/46 , C10G3/47 , C10G3/49 , C10G3/50 , C10G50/00 , C10G65/00 , C10G65/02 , C10G65/14 , C10G69/00 , C10G69/02 , C10G69/08 , C10G69/126 , C10G69/14 , C10G2300/1014 , C10G2300/1022 , C10G2300/1037 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10J3/00 , C10J2300/0916 , C10J2300/1659 , C10L1/08 , Y02E50/13 , Y02P30/42 , Y02T50/678
摘要: A process for producing a blended fuel from a paraffin rich component and a cyclic rich component, where each of the components are generated from a renewable feedstock, is presented. The paraffin rich component is generated from a first renewable feedstock comprising at least one component selected from the group consisting of glycerides, free fatty acids, biomass, lignocellulose, free sugars, and combinations thereof. The cyclic rich component is generated from a second renewable feedstock comprising at least one component selected from the group consisting of glycerides, free fatty acids, free fatty alkyl esters, biomass, lignocellulose, free sugars, and combinations thereof. The blended fuel may a gasoline boiling point range blended fuel, a diesel boiling point range blended fuel, an aviation boiling point range blended fuel, any combination thereof, or any mixture thereof.
摘要翻译: 本发明提供了一种从富含链烷烃的组分和富含循环的组分制备混合燃料的方法,其中每种组分均由可再生原料生成。 富含链烷烃的组分由包含至少一种选自甘油酯,游离脂肪酸,生物质,木质纤维素,游离糖及其组合的组分的第一可再生原料产生。 循环富含组分由第二可再生原料生成,其包含至少一种选自甘油酯,游离脂肪酸,游离脂肪烷基酯,生物质,木质纤维素,游离糖及其组合的组分。 混合燃料可以是汽油沸点范围混合燃料,柴油沸点范围混合燃料,航空沸点范围混合燃料,其任何组合,或其任何混合物。
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4.
公开(公告)号:US20090287029A1
公开(公告)日:2009-11-19
申请号:US12402873
申请日:2009-03-12
IPC分类号: C10G3/00
CPC分类号: C10G45/58 , C01B2203/0233 , C01B2203/0244 , C01B2203/062 , C10G3/42 , C10G3/50 , C10G3/52 , C10G45/64 , C10G45/72 , C10G47/00 , C10G47/36 , C10G65/12 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/04 , C10G2400/08 , C10L1/08 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要: A process for controlling the concurrent production of both diesel range hydrocarbons and aviation range hydrocarbons from renewable feedstocks such as plant oils and animal oils. The process involves determining the required specification of the desired products and the desired relative yields of the product that still meet the required specifications. The necessary isomerization and selective hydrocracking zone conditions are determined in order to create a mixture of paraffins which meet the required product specifications and yields. The necessary fractionation zone conditions are determined to separate the desired products. A renewable feedstock is treated by hydrogenating and deoxygenating to provide an effluent comprising paraffins, isomerizing and selectively hydrogenating at least a portion of the paraffins at the predetermined conditions, and separating by fractionation at the predetermined fractionation conditions to generate a diesel range hydrocarbon product and an aviation range hydrocarbon product.
摘要翻译: 控制从可再生原料如植物油和动物油同时生产柴油范围碳氢化合物和航空范围烃的过程。 该过程包括确定所需产品的所需规格以及仍符合要求规格的产品所需的相对产量。 确定所需的异构化和选择性加氢裂化区条件以产生满足所需产物规格和产率的石蜡混合物。 确定所需的分馏区条件以分离所需的产物。 通过氢化和脱氧来处理可再生原料以提供包含链烷烃的流出物,在预定条件下异构化和选择性氢化至少一部分链烷烃,并通过在预定分馏条件下分级分离以产生柴油范围烃产物和 航空范围烃产品。
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5.
公开(公告)号:US08058492B2
公开(公告)日:2011-11-15
申请号:US12402873
申请日:2009-03-12
IPC分类号: C10M171/00 , C07C4/00 , C10G1/00
CPC分类号: C10G45/58 , C01B2203/0233 , C01B2203/0244 , C01B2203/062 , C10G3/42 , C10G3/50 , C10G3/52 , C10G45/64 , C10G45/72 , C10G47/00 , C10G47/36 , C10G65/12 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/04 , C10G2400/08 , C10L1/08 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要: A process for controlling the concurrent production of both diesel range hydrocarbons and aviation range hydrocarbons from renewable feedstocks such as plant oils and animal oils. The process involves determining the required specification of the desired products and the desired relative yields of the product that still meet the required specifications. The necessary isomerization and selective hydrocracking zone conditions are determined in order to create a mixture of paraffins which meet the required product specifications and yields. The necessary fractionation zone conditions are determined to separate the desired products. A renewable feedstock is treated by hydrogenating and deoxygenating to provide an effluent comprising paraffins, isomerizing and selectively hydrogenating at least a portion of the paraffins at the predetermined conditions, and separating by fractionation at the predetermined fractionation conditions to generate a diesel range hydrocarbon product and an aviation range hydrocarbon product.
摘要翻译: 控制从可再生原料如植物油和动物油同时生产柴油范围碳氢化合物和航空范围烃的过程。 该过程包括确定所需产品的所需规格以及仍符合要求规格的产品所需的相对产量。 确定所需的异构化和选择性加氢裂化区条件以产生满足所需产物规格和产率的石蜡混合物。 确定所需的分馏区条件以分离所需的产物。 通过氢化和脱氧来处理可再生原料以提供包含链烷烃的流出物,在预定条件下异构化和选择性氢化至少一部分链烷烃,并通过在预定分馏条件下分级分离以产生柴油范围烃产物和 航空范围烃产品。
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公开(公告)号:US08222465B2
公开(公告)日:2012-07-17
申请号:US13193227
申请日:2011-07-28
申请人: Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
发明人: Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
CPC分类号: C07C29/132 , C10G3/44 , C10G3/46 , C10G3/48 , C10G3/52 , C10G3/56 , C10G2300/1014 , Y02P20/52 , Y02P30/20 , C07C31/202 , C07C31/205
摘要: A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
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公开(公告)号:US20110313210A1
公开(公告)日:2011-12-22
申请号:US13193227
申请日:2011-07-28
申请人: Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
发明人: Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
IPC分类号: C07C31/20
CPC分类号: C07C29/132 , C10G3/44 , C10G3/46 , C10G3/48 , C10G3/52 , C10G3/56 , C10G2300/1014 , Y02P20/52 , Y02P30/20 , C07C31/202 , C07C31/205
摘要: A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
摘要翻译: 以包含纤维素的原料生成至少一种多元醇的催化方法是以连续方式进行的。 该方法包括使含有纤维素的氢,水和原料与催化剂连续地接触,以产生包含至少一种多元醇,水,氢和至少一种共同产物的流出物流。 将水,氢和至少一种副产物与流出物流分离并再循环至反应区。 从流出物流中回收多元醇。
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公开(公告)号:US20110313209A1
公开(公告)日:2011-12-22
申请号:US13193200
申请日:2011-07-28
申请人: Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
发明人: Tom N. Kalnes , John Q. Chen , Joseph A. Kocal
IPC分类号: C07C29/74
CPC分类号: C07C29/132 , C07C31/20
摘要: A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
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9.
公开(公告)号:US20110313212A1
公开(公告)日:2011-12-22
申请号:US13192835
申请日:2011-07-28
申请人: Tom N. Kalnes , John Q. Chen , Joseph A. Kocal , Tao Zhang , Aiqin Wang , Mingyuan Zheng , Changzhi Li , Jifeng Pang
发明人: Tom N. Kalnes , John Q. Chen , Joseph A. Kocal , Tao Zhang , Aiqin Wang , Mingyuan Zheng , Changzhi Li , Jifeng Pang
IPC分类号: C07C29/74
CPC分类号: C07C29/132 , C07C31/20
摘要: A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.
摘要翻译: 以包含纤维素的原料生成至少一种多元醇的催化方法是以连续方式进行的。 该方法包括使含有纤维素的氢,水和原料与催化剂连续地接触,以产生包含至少一种多元醇,水,氢和至少一种共同产物的流出物流。 将水,氢和至少一种副产物与流出物流分离并再循环至反应区。 从流出物流中回收多元醇。
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10.
公开(公告)号:US20110312487A1
公开(公告)日:2011-12-22
申请号:US13192907
申请日:2011-07-28
申请人: John Q. Chen , Tom N. Kalnes , Joseph A. Kocal
发明人: John Q. Chen , Tom N. Kalnes , Joseph A. Kocal
IPC分类号: B01J23/46 , B01J23/44 , B01J23/755 , B01J21/18 , B01J21/04 , B01J21/06 , B01J21/08 , B01J21/10 , B01J27/224 , B01J21/12 , B01J29/04 , B01J21/16 , B01J27/24 , B01J23/652 , B01J23/883 , B01J23/888 , B01J23/42
CPC分类号: B01J23/30 , B01J21/18 , B01J23/40 , B01J23/755 , B01J27/188 , B01J35/0006 , B01J37/0201
摘要: A catalyst system for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. Generating the polyol involves, contacting, hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one unsupported component and at least one supported component.
摘要翻译: 以连续或间歇的方式进行从包含糖的原料产生至少一种多元醇的催化剂体系。 产生多元醇包括使氢,水和包含糖的原料与催化剂体系接触以产生包含至少一种多元醇的流出物流并从流出物流中回收多元醇。 催化剂体系包含至少一种未负载的组分和至少一种负载的组分。
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