摘要:
A compound suitable for use as an internal electron donor having a structure: wherein R1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; R2 is independently at each occurrence, a hydrogen atom or aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; and R3 is an aliphatic hydrocarbyl group having 1 to 3 carbon atoms.
摘要:
A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: [R1—O—C(O)—O—]xR2 wherein R1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; x is 2-4; and R2 is an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms, provided that there are 2 atoms in the shortest chain connecting a first R1—O—C(O)—O— group and a second R1—O—C(O)—O— group.
摘要翻译:用于聚合烯烃的固体,不溶于烃的催化剂组分,所述催化剂组分含有镁,钛和卤素,并且还含有具有以下结构的内部电子给体:[R 1 -O-C(O)-O-] x R 2 其中R1在每次出现时独立地为含有1至20个碳原子的脂族或芳族烃或取代的烃基; x为2-4; 并且R2是含有1至20个碳原子的脂族或芳族烃或取代的烃基,条件是在连接第一个R1-O-C(O)-O-基团和第二个R1的最短链中有2个原子 -O-C(O)-O-基。
摘要:
A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: [R1—O—C(O)—O—]xR2 wherein R1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; x is 2-4; and R2 is an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms, provided that there are from 3 to 4 atoms in the shortest chain connecting a first R1—O—C(O)—O— group and a second R1—O—C(O)—O— group.
摘要翻译:用于聚合烯烃的固体,不溶于烃的催化剂组分,所述催化剂组分含有镁,钛和卤素,并且还含有具有以下结构的内部电子给体:[R 1 -O-C(O)-O-] x R 2 其中R1在每次出现时独立地为含有1至20个碳原子的脂族或芳族烃或取代的烃基; x为2-4; 并且R 2是含有1至20个碳原子的脂族或芳族烃或取代的烃基,条件是在连接第一个R1-O-C(O)-O-基团和最短链中有3至4个原子 第二个R1-O-C(O)-O-基团。
摘要:
A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: [R1—O—C(O)—O—]xR2 wherein R1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; x is 2-4; and R2 is an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms, provided that there are 2 atoms in the shortest chain connecting a first R1—O—C(O)—O— group and a second R1—O—C(O)—O— group.
摘要翻译:用于聚合烯烃的固体,不溶于烃的催化剂组分,所述催化剂组分含有镁,钛和卤素,并且还含有具有以下结构的内部电子给体:[R 1 -O-C(O)-O-] x R 2 其中R1在每次出现时独立地为含有1至20个碳原子的脂族或芳族烃或取代的烃基; x为2-4; 并且R2是含有1至20个碳原子的脂族或芳族烃或取代的烃基,条件是在连接第一个R1-O-C(O)-O-基团和第二个R1的最短链中有2个原子 -O-C(O)-O-基。
摘要:
A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: [R1—O—C(O)—O—]xR2 wherein R1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; x is 2-4; and R2 is an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms, provided that there are from 3 to 4 atoms in the shortest chain connecting a first R1—O—C(O)—O— group and a second R1—O—C(O)—O— group.
摘要翻译:用于聚合烯烃的固体,不溶于烃的催化剂组分,所述催化剂组分含有镁,钛和卤素,并且还含有具有以下结构的内部电子给体:[R 1 -OC(O)-O-] x R 2,其中R 1 在每次出现时独立地为脂族或芳族烃,或含有1至20个碳原子的取代烃基; x为2-4; 并且R2是含有1至20个碳原子的脂族或芳族烃或取代的烃基,条件是在连接第一个R1-OC(O)-O-基团和第二个 R1-OC(O)-O-基。
摘要:
The present disclosure provides processes for the production of substituted phenylene aromatic diesters and the resultant compositions. The processes include reacting an aromatic diol with an aromatic carboxylic acid or a derivative thereof. The aromatic diol and/or the aromatic carboxylic acid (or derivative thereof) is/are substituted. The reaction forms a substituted phenylene aromatic diester with the structure (II): wherein R1-R14 are the same or different. At least one of R1-R14 is selected from a substituted hydrocarbyl group having 1 to 20 carbon atoms, an unsubstituted hydrocarbyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a heteroatom, and combinations thereof.
摘要:
Synthesis pathways for a precursor to 5-tert-butyl-3-methyl-1, 2-phenylene dibenzoate are provided. The precursor is methylcatechol and/or 5-tert-butyl-3-methylcatechol.
摘要:
Disclosed is a process for producing a procatalyst composition having an amide ester internal electron donor. The process includes pre-halogenating a procatalyst precursor before reaction with the amide ester and forming the procatalyst composition. Ziegler-Natta catalyst compositions containing the present procatalyst composition exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution.
摘要:
Disclosed are catalyst compositions having an internal electron donor which includes a 3,6-di-substituted-1,2-phenylene aromatic diester. Ziegler-Natta catalyst compositions containing the present catalyst compositions exhibit very high hydrogen response, high activity, high selectivity and produce propylene-based olefins with high melt flow rate.
摘要:
Disclosed are procatalyst compositions having an internal electron donor which includes a substituted amide ester and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution.