Catalysts for polymerizing olefins
    5.
    发明授权
    Catalysts for polymerizing olefins 失效
    用于聚合烯烃的催化剂

    公开(公告)号:US3639368A

    公开(公告)日:1972-02-01

    申请号:US3639368D

    申请日:1968-06-20

    CPC classification number: C08F10/00 C08F4/6094

    Abstract: AN ACTIVATOR FOR CATALYTIC SYSTEMS WHICH COMPRISE AN ORGANO-METALIC COMPOUND OF A METAL BELONGING TO ANY OF GROUPS I TO III OF THE PERIODIC SYSTEM AND A COMPOUND OF A TRANSITION METAL AND WHICH ARE USED FOR THE POLYMERISATION OF OLEFINS, CONSISTS OF A HALOGENATED DERIVATIVE OF 5,8-DIOXO-$ 1,4-METHYLENE-HEXAHYDRONAPHTALENE, CONTAINING AT LEAST 4 HALOGEN ATOMS IN THE MOLECULE.

    Process for producing crystalline olefin polymers and catalyst compositions therefor
    9.
    发明授权
    Process for producing crystalline olefin polymers and catalyst compositions therefor 失效
    生产结晶烯烃聚合物及其催化剂组合物的方法

    公开(公告)号:US3622552A

    公开(公告)日:1971-11-23

    申请号:US3622552D

    申请日:1969-10-03

    CPC classification number: C08F10/00 C08F4/6094

    Abstract: Polymerization of olefins and catalyst therefor, said catalyst comprising polymerizing at least one member selected from the group consisting of ethylene, propylene, butene-1 and styrene in the presence of a catalyst composition comprising (1) an organoaluminum compound having the formula, AIR2X wherein R represents a hydrocarbon residue selected from the group consisting of alkyl, aryl, aralkyl, alkaryl and cycloalkyl groups and X represents a halogen atoms selected from the group consisting of chlorine, bromine and iodine, (2) a halide of a transition metal of Groups IV, V and VI of the Periodic Table of the Elements, and (3) an aliphatic carboxylic ester having a side chain on a carbon atom in a Alpha -position to the ester carbon atom, the molar proportion of said organoaluminum compound, said halide of transition metal and said aliphatic carboxylic ester being 10-0.5 : 1 : 0.01-1.

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