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1.发明授权Polysiloxane stabilizers for flatting agents in radiation hardenable compositions 失效用于辐射可硬化组合物中的平滑剂的聚硅氧烷稳定剂
公开(公告)号：US4417023A
公开(公告)日：1983-11-22
申请号：US347512
申请日：1982-02-10
IPC分类号： C08F2/48
CPC分类号： C08F2/48
摘要： Flatting agents, such as silica, talc and carbonates are present in radiation hardenable compositions in order to reduce gloss and obtain a flat appearance in cured coating. However, the flatting agent settles in the radiation-hardenable composition. To reduce settling of the flatting agent, one or more stabilizers are added to the composition. Useful stabilizers are alkylene oxide adducts of particular siloxane copolymers.
摘要翻译： 平滑剂如二氧化硅，滑石和碳酸盐存在于可辐射硬化的组合物中，以便降低光泽并获得固化涂层中的平坦外观。 然而，平坦化剂沉降在可辐射硬化组合物中。 为了减少平整剂的沉降，将一种或多种稳定剂加入到组合物中。 有用的稳定剂是特定硅氧烷共聚物的烯化氧加合物。
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公开(公告)号：US4382135A
公开(公告)日：1983-05-03
申请号：US250058
申请日：1981-04-01
IPC分类号： C07C69/54 , C07C43/11 , C08F20/00 , C08F20/10 , C08F222/10 , C09D4/00 , C09J133/08 , C08F226/00
CPC分类号： C08F222/1006 , C07C43/11 , C09D4/00
摘要： Radiation curable diluents have been developed which are acrylic acid esters of alkoxylated 1,6-hexanediol, neopentyl glycol and tripropylene glycol, each having a relatively low degree of alkoxylation. Examples are diacrylates of adducts of neopentyl glycol with two moles, four moles and six moles, respectively, of ethylene oxide and with two moles and four moles, respectively, of propylene oxide.
摘要翻译： 已经开发了可辐射固化的稀释剂，其是烷氧基化的1,6-己二醇，新戊二醇和三丙二醇的丙烯酸酯，它们各自具有较低的烷氧基化程度。 实例是分别具有2摩尔，4摩尔和6摩尔环氧乙烷和2摩尔和4摩尔环氧丙烷的新戊二醇的加合物的二丙烯酸酯。
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公开(公告)号：US4424074A
公开(公告)日：1984-01-03
申请号：US411033
申请日：1982-08-24
CPC分类号： C04B28/04
摘要： Additives for cementitious compositions which are mixtures of (1) salts such as the sodium salt of a condensation product of naphthalenesulfonic acid and formaldehyde and (2) zinc salts increase compressive strengths and reduce water contents of hardened cementitious compositions. Useful additives include mixtures of from 65% to about 75% by weight of a sodium salt of a condensation product of naphthalenesulfonic acid and formaldehyde and from about 25 to about 35% by weight of a zinc salt such as zinc sulfate, zinc chloride, zinc acetate or the like. Effective amounts of these additives are added to cementitious compositions to improve their properties. Addition of effective amounts of these mixtures in cementitious strengths from 25 to 30% greater over those obtained with a sodium salt of the condensation product.
摘要翻译： 作为（1）盐如萘磺酸和甲醛的缩合产物的钠盐和（2）锌盐的混合物的水泥组合物的添加剂增加了硬化水泥组合物的抗压强度并降低了其含水量。 有用的添加剂包括65重量％至约75重量％的萘磺酸和甲醛缩合产物的钠盐和约25至约35重量％的锌盐如硫酸锌，氯化锌，锌 乙酸酯等。 将这些添加剂的有效量加入到水泥组合物中以改善它们的性能。 将有效量的这些混合物在水泥强度中的添加量比通过缩合产物的钠盐获得的混合物的量高25至30％。
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公开(公告)号：US4514189A
公开(公告)日：1985-04-30
申请号：US469168
申请日：1983-02-24
申请人： John G. Papalos , Joseph V. Sinka
发明人： John G. Papalos , Joseph V. Sinka
IPC分类号： C10L1/32
CPC分类号： C10L1/326 , Y10S516/03
摘要： Particulate carbonaceous materials water mixtures are prepared by adding a condensate which is a condensation product of(a) an aldehyde having from about 1 to about 7 carbon atoms,(b) a benzene derivative such as benzene sulfonic acid, an alkyl benzene sulfonic acid having at least one alkyl group of from about 1 to about 20 carbon atoms and mixtures thereof, and optionally,(c) a naphthalene derivative such as naphthalene sulfonic acid, an alkyl naphthalene sulfonic acid having at least one alkyl group of from about 1 to about 12 carbon atoms and mixtures thereof.The condensate is added in an amount sufficient to reduce viscosity of the water mixture of carbonaceous materials, to stabilize carbonaceous materials in the water network and to improve pumpability. An acid form of the condensate or a salt may be added.
摘要翻译： 颗粒状碳质材料水混合物通过加入作为（a）具有约1至约7个碳原子的醛的缩合产物的缩合物，（b）苯衍生物如苯磺酸，烷基苯磺酸具有 至少一个约1至约20个碳原子的烷基及其混合物，和任选的（c）萘衍生物如萘磺酸，具有至少一个烷基的烷基萘磺酸约1至约 12个碳原子及其混合物。 加入的冷凝物的量足以降低碳质材料的水混合物的粘度，以稳定水网中的碳质材料并提高泵送性。 可以加入酸形式的缩合物或盐。
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公开(公告)号：USH1712H
公开(公告)日：1998-02-03
申请号：US255493
申请日：1994-06-08
申请人： John G. Papalos , Joseph V. Sinka
发明人： John G. Papalos , Joseph V. Sinka
CPC分类号： C07C69/54
摘要： Radiation-curable compositions containing monoalkyl or mono-aralkyl ether di-acrylates or di-methacrylates of particular ethoxylated and/or propoxylated polyols of formulae I and II have been developed. These polyol derivatives substituted with hydrophobic ether functionalities constitute UV-curable diluents that can be isolated in excellent yields with minimal losses during the manufacturing process.
摘要翻译： 已经开发了包含式I和II的特定乙氧基化和/或丙氧基化多元醇的单烷基或单芳烷基醚二丙烯酸酯或二 - 甲基丙烯酸酯的可辐射固化组合物。 用疏水醚官能团取代的这些多元醇衍生物构成了紫外线固化的稀释剂，可以在制造过程中以最小的损失以优异的产率分离。
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公开(公告)号：US4290817A
公开(公告)日：1981-09-22
申请号：US112564
申请日：1980-01-16
摘要： Byproduct ammonium ions remaining in an aqueous solution of a water soluble glucoheptonate salt after its synthesis are reacted with the free acid form of a naphthalenesulfonic acid-formaldehyde condensation product to obtain an aqueous composition which does not produce an ammonia odor when introduced into aqueous media having a pH above 9. The aqueous composition can be dried to obtain a flowable powder. Both the aqueous composition and flowable powder are useful as additives in industrial products. They may be used to prolong the time of hydration of cement.
摘要翻译： 在其合成后残留在水溶性葡庚糖酸盐的水溶液中的副产物铵离子与游离酸形式的萘磺酸 - 甲醛缩合产物反应，以获得当引入含水介质中时不产生氨气味的含水组合物， pH高于9.水性组合物可以干燥以获得可流动的粉末。 水性组合物和可流动粉末都可用作工业产品中的添加剂。 它们可用于延长水泥的水化时间。
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公开(公告)号：US4164426A
公开(公告)日：1979-08-14
申请号：US925031
申请日：1978-07-17
申请人： Joseph V. Sinka , Jose L. Villa
发明人： Joseph V. Sinka , Jose L. Villa
CPC分类号： C04B24/22
摘要： Addition of zinc naphthaleneformaldehyde sulfonate to concrete mix improves compressive strength. This sulfonate is effective in concrete mixes prepared with Type I, II and III cements.
摘要翻译： {PG，1将萘甲醛磺酸锌加入到混凝土混合物中可提高抗压强度。 该磺酸盐在用I，II和III型水泥制备的混凝土混合物中是有效的。
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公开(公告)号：US4780500A
公开(公告)日：1988-10-25
申请号：US39223
申请日：1987-04-17
申请人： Joseph V. Sinka , Dinshaw F. Bardoliwalla , Jose L. Villa , Edwin L. Kelley , Albert L. Resnick
发明人： Joseph V. Sinka , Dinshaw F. Bardoliwalla , Jose L. Villa , Edwin L. Kelley , Albert L. Resnick
IPC分类号： C08F220/06 , D21H19/58 , C08F222/02 , C08K13/02 , C08L31/06
CPC分类号： D21H19/58 , C08F220/06
摘要： Copolymers of (1) from about 80% to about 98% by weight of acrylic acid and (2) from about 2% to about 20% by weight of itaconic acid and having a weight average molecular weight of between about 100,000 to about 800,000 and which are at least water dispersible are useful as retention aids for paper coating compositions.
摘要翻译： （1）约80％至约98％重量的丙烯酸和（2）约2％至约20％重量的衣康酸的共聚物，其重均分子量为约100,000至约800,000，和 其至少是水分散的可用作纸涂料组合物的保留助剂。
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公开(公告)号：US4478602A
公开(公告)日：1984-10-23
申请号：US348238
申请日：1982-02-12
IPC分类号： C10L1/32
CPC分类号： C10L1/322 , Y10S516/07
摘要： Binary surfactant mixtures are added to particulate carbonaceous materials in oil slurries such as coal oil (COM) or coke oil mixtures in an amount sufficient to stabilize slurries during storage and dispersing at various temperatures. These stabilizer mixtures are added to either the oil or slurry and are effective with or without addition of water. Coal/coke oil slurries may contain from about 30 to about 90 parts by weight of oil, about 10 to about 70 parts by weight of powdered coal or coke, about 0.01 to about 6.0 parts by weight of the stabilizer mixture and about 0 to about 10 parts by weight of water. A useful stabilizer mixture contains from about 0.25 to about 0.75 parts by weight of an imidazoline quaternary salt and from about 0.75 to about 0.25 parts by weight of a nonionic surfactant which is ethylene diamine condensed first with about 80 moles of propylene oxide and then with about 20 moles of ethylene oxide.
摘要翻译： 将二元表面活性剂混合物加入到油浆（例如煤油（COM））或焦炭混合物中的颗粒状碳质材料中，其量足以在各种温度下储存和分散期间稳定浆料。 将这些稳定剂混合物加入到油或浆料中，并且在添加或不添加水的情况下是有效的。 煤/焦炭油浆可以含有约30至约90重量份的油，约10至约70重量份的粉煤或焦炭，约0.01至约6.0重量份的稳定剂混合物和约0至约 10重量份水。 有用的稳定剂混合物包含约0.25至约0.75重量份的咪唑啉季盐和约0.75至约0.25重量份的非离子表面活性剂，其是首先用约80摩尔环氧丙烷缩合的乙二胺，然后与约 20摩尔环氧乙烷。
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公开(公告)号：US4021365A
公开(公告)日：1977-05-03
申请号：US597149
申请日：1975-07-18
申请人： Joseph V. Sinka , Irwin A. Lichtman
发明人： Joseph V. Sinka , Irwin A. Lichtman
CPC分类号： C09D7/1233 , B01D19/0404 , C08K5/20
摘要： Defoamer compositions having improved stability are prepared from hydrophobic silica, quick-chilled amides, and hydrocarbon oil, with oil soluble organic polymers and surface-active additives as optional ingredients. These compositions are useful in defoaming aqueous systems including paper pulp black liquors, water-base paints, and adhesives.
摘要翻译： 具有改善的稳定性的消泡剂组合物由疏水性二氧化硅，快速冷却的酰胺和烃油，油溶性有机聚合物和表面活性添加剂作为任选成分制备。 这些组合物可用于消泡水系统，包括纸浆黑液，水基涂料和粘合剂。
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