摘要:
A polypropylene composition comprising 20 to 95% by weight of a stereoregular polypropylene characterized by the specified physical properties determined from .sup.13 C NMR spectra and 5 to 80% by weight of an .alpha.-olefin copolymer comprising 10 to 90% by weight of an .alpha.-olefin and 10 to 90% by weight of at least one of other .alpha.-olefins. The polypropylene composition demonstrates good balance of rigidity and impact resistance, high heat resistance and high toughness, when used as molding materials.
摘要翻译:一种聚丙烯组合物,其包含20至95重量%的立构规整聚丙烯,其特征在于由13 C NMR谱确定的特定物理性质和5至80重量%的包含10至90重量%的α-烯烃的α-烯烃共聚物 和10至90重量%的至少一种其它α-烯烃。 当用作成型材料时,聚丙烯组合物表现出良好的刚性和耐冲击性的平衡,高耐热性和高韧性。
摘要:
There are provided propylene-ethylene copolymers from which there are made molded articles having excellent heat resistance and films having both low temperature heat-sealing characteristics and stiffness, processes for the production thereof and molded articles. The propylene-ethylene copolymers contain 0.01-15 mol % of an ethylene unit and are characterized by that in the chain structure determined by NMR, triad (PEP), triad (EEE) and a ratio (N.sub..alpha..beta.) of all .alpha., .beta.-methylene carbons to all propylene units are in the specified range, a weight average molecular weight is 50,000-1,500,000 and a molecular weight distribution (Mw/Mn) is 1.2-3.8. The copolymers can be produced by copolymerizing ethylene and propylene in the presence of a catalyst in which the specified chiral transition metal compound (metallocene) and aluminoxane are combined.
摘要:
A process for the production of a high stereoregular polypropylene wherein(a) an isotactic pentad (m m m m) is 0.950 to 0.995,(b) a syndiotactic pentad (r r r r) is 0 to 0.01,(c) a different bond due to 2,1- and 1,3-insertions of propylene monomer is 0 to 0.3 mol %,(d) an absence of a terminal double bond is confirmed,(e) a weight average molecular weight (Mw) is 50,000 to 1,000,000 and(f) a ratio (Mw/Mn) of the weight average molecular weight (Mw) to a number average molecular weight (Mn) is 1.5 to 3.8, (a) to (d) being determined from .sup.13 C NMR spectra, comprising polymerizing propylene in the presence of hydrogen using a catalyst comprising a chiral transition metal compound and an aluminoxane, the transition metal compound being represented by the formula of Q(C.sub.5 H.sub.4-m R.sup.1.sub.m) (C.sub.5 H.sub.4-n R.sup.2.sub.n)MXY wherein (C.sub.5 H.sub.4-m R.sup.1.sub.m) and (C.sub.5 H.sub.4-n R.sup.2.sub.n) represent a substituted cyclopentadienyl group; m and n are an integer of 1 to 3; R.sup.1 and R.sup.2 may be the same or different and each represents an alkyl group of 1 to 20 carbons; Q is a group capable of crosslinking (C.sub.5 H.sub.4-m R.sup.1.sub.m) and (C.sub.5 H.sub.4-n R.sup.2.sub.n) and represents a divalent, hydrocarbyl radical, an unsubstituted silylene group or a hydrocarbyl-substituted silylene group; M represents a transition metal selected from the group consisting of titanium, zirconium, and hafnium; X and Y may be the same or different and each represents a hydrogen, a halogen or a hydrocarbyl radical, and wherein said polymerization is performed by a slurry polymerization using an aliphatic hydrocarbon as a solvent or by a bulk polymerization using propylene as a solvent.
摘要翻译:一种制备高立构规则聚丙烯的方法,其中(a)全同立构五单元组(mmmm)为0.950-0.995,(b)间同立构五单元组(rrrr)为0至0.01,(c)由于2,1 - 和丙烯单体的1,3-插入为0〜0.3摩尔%,(d)不存在末端双键,(e)重均分子量(Mw)为50,000〜1,000,000,(f)a 重均分子量(Mw)与数均分子量(Mn)之比(Mw / Mn)为1.5至3.8,(a)至(d)由13 C NMR谱确定,包括在存在下聚合丙烯 使用包含手性过渡金属化合物和铝氧烷的催化剂的氢,所述过渡金属化合物由下式Q(C5H4-mR1m)(C5H4-nR2n)MXY表示,其中(C5H4-mR1m)和(C5H4-nR2n)表示 取代的环戊二烯基; m和n为1〜3的整数, R 1和R 2可以相同或不同,各自表示1〜20个碳的烷基; Q是能够交联的基团(C5H4-mR1m)和(C5H4-nR2n),代表二价烃基,未取代的亚甲硅烷基或烃基取代的亚甲硅烷基; M表示选自钛,锆和铪的过渡金属; X和Y可以相同或不同,各自表示氢,卤素或烃基,并且其中所述聚合通过使用脂族烃作为溶剂的淤浆聚合或通过使用丙烯作为溶剂的本体聚合进行。
摘要:
The present invention provides propylene/ethylene random copolymers characterized in that: an ethylene content (Ew) is 0.1-10 wt %, a relationship between an isolated ethylene content (E1) and the ethylene content (Ew) is represented by the following equation E1>0.85−0.01 Ew 2,1- and 1,3-propylene units present in a polymer chain are 0-1 mol %, a weight average molecular weight (Mw) is in the range of 40,000-1,000,000, and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to a number average molecular weight(Mn) is in the range of 1.5-3.8. The copolymers are suitable for a base resin for a molding material for the production of a wide variety of molded articles which are high in randomness and excellent in stiffness, heat resistance and transparency.
摘要:
An olefin (co)polymer composition comprising, as major components, (a) 0.01 to 5 parts by weight of an olefin (co)polymer having an intrinsic viscosity [.eta..sub.a ] as measured in 135.degree. C. tetralin of 15 to 100 dl/g and (b) 100 parts by weight of an olefin (co)polymer obtained by using a metallocene catalyst and having an intrinsic viscosity [.eta..sub.b ] as measured in 135.degree. C. tetralin of 0.2 to 10 dl/g. When polyethylene having a high degree of polymerization is produced before a so-called metallocene catalyst is used to polymerize, e.g., propylene in the presence of the polyethylene as a component of a catalyst composition, a polypropylene composition having a high melt tension and a high crystallization temperature is produced.
摘要:
An IGBT has an emitter region, a top body region that is formed below the emitter region, a floating region that is formed below the top body region, a bottom body region that is formed below the floating region, a trench, a gate insulating film that covers an inner face of the trench, and a gate electrode that is arranged inside the trench. When a distribution of a concentration of p-type impurities in the top body region and the floating region, which are located below the emitter region, is viewed along a thickness direction of a semiconductor substrate, the concentration of the p-type impurities decreases as a downward distance increases from an upper end of the top body region that is located below the emitter region, and assumes a local minimum value at a predetermined depth in the floating region.
摘要:
A liquid sealed vibration isolating device has an elastically movable diaphragm capable of preventing elastic deformation of a relief valve to realize high damping while preventing a cavitation phenomenon. The relief valve is provided in the elastic movable diaphragm arranged in a partition member in order to open and close a leak passage so as to prevent occurrence of the cavitation phenomenon. The relief valve is integrally formed with a fixing portion of the elastic movable diaphragm. There is provided an upwardly open concavity that the relief valve faces. The relief valve is made thicker and provided with an opening and closing adjustment groove at a basal portion of its inclined wall. The opening and closing adjustment groove is formed with a locally thin bending portion functioning as a starting point of bending in an opening and closing operation of the relief valve.
摘要:
A specific information input region (B) individually specifying information to be input and an input mode switching region (C) used for changing an information input mode are placed on an information input region (A) set on a substrate. Each of these regions is displayed to be visible. An optical sensor detects a touched position on the information input region. Then, the touch operation in the input mode switching region (C) is detected according to the output of the optical sensor to selectively switch the information input mode among keyboard input, pen tablet input and mouse input. The output of the optical sensor is analyzed according to the set input mode to find out the information input by the touch operation.
摘要:
In a reverse conducting semiconductor device, which forms a composition circuit, a positive voltage that is higher than a positive voltage of a collector electrode may be applied to an emitter electrode. In this case, in a region of the reverse conducting semiconductor device in which a return diode is formed, a body contact region functions as an anode, a drift contact region functions as a cathode, and current flows from the anode to the cathode. When a voltage having a lower electric potential than the collector electrode is applied to the trench gate electrode at that time, p-type carriers are generated within the cathode and a quantity of carriers increases within the return diode. As a result, a forward voltage drop of the return diode lowers, and constant loss of electric power can be reduced. Electric power loss can be reduced in a power supply device that uses such a composition circuit in which a switching element and the return diode are connected in reverse parallel.
摘要:
A protrusion (13a) and a protrusion (13b) are formed a predetermined distance apart in the direction of a shaft in the outer circumferential surface of the roller main body (11). The cross sections of the protrusion (13a) and the protrusion (13b) are shaped such that a center portion of the roller main body (11) in the direction of the shaft is a boundary (14), and that on the left side of the boundary (14), a vertex (131a) is displaced to the left side from the perpendicular bisector (133a) of an opposite side (132a) whereas on the right side of the boundary (14), a vertex (131b) is displaced to the right side from the perpendicular bisector (133b) of an opposite side (132b). In this way, in a metallic movement roller that moves a strung endless belt, the winding movement and the like of the belt can be prevented, and the belt can be intentionally moved in a specific direction.