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1.发明授权Polyester composition and biaxially oriented polyester film containing the same 失效聚酯组合物和含有它的双轴取向聚酯薄膜
公开(公告)号：US5470637A
公开(公告)日：1995-11-28
申请号：US98306
申请日：1993-11-23
申请人： Jun Sakamoto , Minoru Yoshida , Masatoshi Aoyama , Masaru Suzuki , Yukari Nakamori , Iwao Okazaki , Koichi Abe
发明人： Jun Sakamoto , Minoru Yoshida , Masatoshi Aoyama , Masaru Suzuki , Yukari Nakamori , Iwao Okazaki , Koichi Abe
CPC分类号： G11B5/733 , C08J5/18 , C08K3/22 , C08J2367/02 , Y10S428/91 , Y10T428/24372 , Y10T428/31786
摘要： A thermoplastic polyester composition suited for preparing a film or fiber having excellent abrasion resistance, as well as a biaxially oriented polyester film consisting essentially of the polyester composition are disclosed. The thermoplastic polyester according to the present invention is characterized by comprising a thermoplastic polyester (A) and zirconium oxide particles (B) having monoclinic and/or tetragonal crystal structure.
摘要翻译： PCT No.PCT / JP92 / 01605 Sec。 371日期：1992年11月23日 102（e）日期1992年11月23日PCT 1992年12月9日PCT PCT。 出版物WO93 / 12177 日本6月24日，1993年。一种适用于制备具有优异耐磨性的薄膜或纤维的热塑性聚酯组合物以及基本上由聚酯组合物组成的双轴取向聚酯薄膜。 根据本发明的热塑性聚酯的特征在于包含具有单斜晶体和/或四方晶体结构的热塑性聚酯（A）和氧化锆颗粒（B）。
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公开(公告)号：US5458964A
公开(公告)日：1995-10-17
申请号：US104759
申请日：1993-08-12
申请人： Iwao Okazaki , Masahiro Kimura , Masatoshi Aoyama , Masaru Suzuki , Koichi Abe , Yukari Nakamori , Hidehito Minamizawa , Katsuya Okamoto , Hiroyuki Tanaka
发明人： Iwao Okazaki , Masahiro Kimura , Masatoshi Aoyama , Masaru Suzuki , Koichi Abe , Yukari Nakamori , Hidehito Minamizawa , Katsuya Okamoto , Hiroyuki Tanaka
CPC分类号： C08J5/18 , B32B27/20 , G11B5/7305 , G11B5/738 , C08J2367/02 , Y10S428/91 , Y10T428/25 , Y10T428/254 , Y10T428/257 , Y10T428/259 , Y10T428/31786
摘要： Disclosed is a biaxially oriented film and a laminated film containing specified organic particles at a content of 0.001 to 20% by weight. The strength when deformed by 10% (S.sub.10) of the organic particles is in the range of 3 to 30 kgf/mm.sup.2, the thermal decomposition temperature for causing 10% loss in weight thereof is not lower than 350.degree. C. The weight average diameter thereof is in the range of 0.005 to 5 .mu.m. Since the organic particles have a good affinity with the matrix resin of the film and a good thermal resistance and the hardness of the particles is appropriate, desired protrusions hardly chipped and having an appropriate hardness for hardly scratching a magnetic surface can be formed on a film surface easily and uniformly. Therefore, a film excellent in abrasion resistance and scratch resistance at a high running speed and excellent in running durability can be obtained, which is useful particularly as a base film of a magnetic tape.
摘要翻译： 公开了含有0.001〜20重量％的特定有机粒子的双轴取向膜和层叠膜。 当有机颗粒变形10％（S10）时的强度在3〜30kgf / mm 2的范围内，其重量减少10％的热分解温度不低于350℃。重量平均直径 为0.005〜5μm的范围。 由于有机颗粒与膜的基质树脂具有良好的亲和性，并且具有良好的耐热性，并且颗粒的硬度是合适的，因此可以在薄膜上形成难以切割并且具有难以刮擦磁性表面的适当硬度的所需突起 表面容易均匀。 因此，可以获得在高运行速度下具有优异的耐磨性和耐擦伤性的膜，并且可以获得特别用作磁带的基膜的运行耐久性优异的运行耐久性优异的膜。
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公开(公告)号：US6124031A
公开(公告)日：2000-09-26
申请号：US119075
申请日：1993-09-22
CPC分类号： C08J5/18 , C08K3/0008 , C08K3/22 , C08J2367/02 , C08K2003/2227 , C08K2201/014 , C08L2205/02 , C08L67/02 , Y10T428/254 , Y10T428/256 , Y10T428/257 , Y10T428/258 , Y10T428/259
摘要： Disclosed are a thermoplastic polyester composition comprising a thermoplastic polyester (A) prepared from an acid component mainly comprising an aromatic dicarboxylic acid and a glycol component mainly comprising an aliphatic glycol and .theta.-type aluminum oxide particles (B); a thermoplastic polyester composition comprising the thermoplastic polyester (A) and a mixture (C) of two or more kinds of aluminum oxide particles different from each other in crystal structure; and films made from these compositions. Particularly, the films formed from the compositions can have excellent slipping property, abrasion resistance, and scratch resistance in repeated high-speed running.
摘要翻译： PCT No.PCT / JP93 / 00073 Sec。 371日期：1993年9月22日 102（e）1993年9月22日PCT 1993年1月27日PCT公布。 公开号WO93 / 15145 日期1988年8月5日公开是一种热塑性聚酯组合物，其包含由主要包含芳族二羧酸的酸组分和主要包含脂族二醇和θ型氧化铝颗粒（B）的二醇组分制备的热塑性聚酯（A） 包含热塑性聚酯（A）的热塑性聚酯组合物和晶体结构彼此不同的两种或更多种氧化铝颗粒的混合物（C）; 和由这些组合物制成的薄膜。 特别地，由组合物形成的膜在重复的高速运行中可以具有优异的滑动性，耐磨性和耐擦伤性。
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公开(公告)号：US5912074A
公开(公告)日：1999-06-15
申请号：US682954
申请日：1996-07-18
申请人： Masatoshi Aoyama , Hiroji Kojima , Masaru Suzuki
发明人： Masatoshi Aoyama , Hiroji Kojima , Masaru Suzuki
CPC分类号： C08J5/18 , B32B27/36 , C08L67/02 , G11B5/733 , C08J2367/02 , Y10T428/254 , Y10T428/257 , Y10T428/258 , Y10T428/259 , Y10T428/268 , Y10T428/269 , Y10T428/31786
摘要： A polyester composition comprises a polyester component (a) and polymer particles (b). At least an outermost layer of the polymer particles (b) is of a polymer having hydroxyl groups. The composition can be made into a film especially suitable for use as a substrate in a magnetic recording medium.
摘要翻译： 聚酯组合物包含聚酯组分（a）和聚合物颗粒（b）。 至少聚合物颗粒（b）的最外层是具有羟基的聚合物。 组合物可以制成特别适合用作磁记录介质中的基材的膜。
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公开(公告)号：US6083617A
公开(公告)日：2000-07-04
申请号：US750576
申请日：1996-12-11
申请人： Masatoshi Aoyama , Hiroji Kojima , Masaru Suzuki
发明人： Masatoshi Aoyama , Hiroji Kojima , Masaru Suzuki
CPC分类号： C08J5/18 , C08K3/34 , C08J2367/02 , Y10S428/91 , Y10T428/254 , Y10T428/256 , Y10T428/257 , Y10T428/258 , Y10T428/259 , Y10T428/268 , Y10T428/269 , Y10T428/2993
摘要： A polyester composition comprising 0.005 to 10% by weight compound oxide particles having a volume average particle meter of 0.005 to 2 .mu.m, a relative standard deviation .sigma. of the particle diameter of not more than 0.3, and composed mainly of silicon (Si), aluminum (Al) and at least one alkali metal (M), wherein the contents of the silicon, aluminum and alkali metal satisfy the following requirements: 10 wt. %.ltoreq.Si.ltoreq.45 wt. %, 3 wt. %.ltoreq.Al.ltoreq.30 wt. % and 0.5 wt. %.ltoreq.M.ltoreq.20 wt. %, respectively. The polyester composition, particularly when formed into films, has excellent surface evenness, running ability and abrasion resistance, and such films are suitable particularly for magnetic recording media and other applications.
摘要翻译： PCT No.PCT / JP96 / 00992 Sec。 371日期1996年12月11日第 102（e）日期1996年12月11日PCT PCT 1996年4月11日PCT公布。 公开号WO96 / 32443 日期：1996年10月17日一种聚酯组合物，其包含0.005〜10重量％的体积平均粒度计为0.005〜2μm的复合氧化物粒子，粒径的相对标准偏差σ为0.3以下，主要由 硅（Si），铝（Al）和至少一种碱金属（M），其中硅，铝和碱金属的含量满足以下要求：10wt。 ％
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6.发明授权Polyester resin compositions, catalyst for polyester production, polyester film, and magnetic recording medium 有权聚酯树脂组合物，聚酯生产催化剂，聚酯薄膜和磁记录介质公开(公告)号：US07709594B2
公开(公告)日：2010-05-04
申请号：US10529847
申请日：2003-10-03
CPC分类号： B32B27/36 , B32B27/08 , C08G63/85 , C08J5/18 , C08J2367/02 , C08K3/10 , C08K5/49 , C08L25/00 , C08L39/06 , C08L67/02 , C08L101/00 , C08L2201/00 , C08L2205/14 , C08L2205/22 , G11B5/7305 , G11B5/7325 , G11B5/733 , Y10T428/31786 , C08L2666/04 , C08L2666/06 , C08L2666/02
摘要： A polyester composition produced without using an antimony compound as a polycondensation catalyst and including (I) composition containing, on a weight basis, 30 ppm or less of antimony, 0.5 to 50 ppm of titanium, and 0.1 to 100 ppm of phosphorus, in which the number density of titanium-containing particles, the equivalent circular diameter of which is 1μm or more, is less than 100/0.02 mg; and (II) a composition containing, on a weight basis, antimony, titanium and phosphorous as defined above, in which organic polymer particles are contained in amount of 0.1 to 5 wt%, the organic polymer particles having an average particle diameter determined by dynamic light scattering of 0.05 to 3μm and containing 0.01% or less of coarse particles relative to the total number of the particles, the coarse particles having a diameter at least twice the average particle diameter.
摘要翻译： 在不使用锑化合物作为缩聚催化剂的情况下制造的聚酯组合物，其包含（I）以重量计含有30ppm以下的锑，0.5〜50ppm的钛和0.1〜100ppm的磷的组合物，其中 其等效圆直径为1μm以上的含钛粒子的数密度小于100 / 0.02mg; 和（II）以重量计含有如上定义的锑，钛和磷的组合物，其中有机聚合物颗粒的含量为0.1至5重量％，有机聚合物颗粒的平均粒径由动态 光散射为0.05〜3μm，相对于粒子总数，含有0.01％以下的粗粒子，粗粒子的直径为平均粒径的2倍以上。
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公开(公告)号：US20120034480A1
公开(公告)日：2012-02-09
申请号：US13137239
申请日：2011-07-29
申请人： Jun Sakamoto , Masatoshi Aoyama , Yoshihiro Honma
发明人： Jun Sakamoto , Masatoshi Aoyama , Yoshihiro Honma
IPC分类号： B32B27/36 , C08G63/127 , C07F7/28 , C08G63/85
CPC分类号： B32B27/36 , B32B27/08 , C08G63/85 , C08J5/18 , C08J2367/02 , C08K3/10 , C08K5/49 , C08L25/00 , C08L39/06 , C08L67/02 , C08L101/00 , C08L2201/00 , C08L2205/14 , C08L2205/22 , G11B5/7305 , G11B5/7325 , G11B5/733 , Y10T428/31786 , C08L2666/04 , C08L2666/06 , C08L2666/02
摘要： Polyester composition produced without antimony compound as a polycondensation catalyst including, 30 ppm or less antimony, 0.5-50 ppm titanium, and 0.1-100 ppm phosphorus, the number density of titanium-containing particles having an equivalent circular diameter of 1 μm or more being less than 100/0.02 mg; and a composition as above, containing 0.1-5 wt % organic polymer particles which have an average particle diameter of 0.05-3 μm and contain 0.01% or less of coarse particles which have a diameter at least twice the average particle diameter. Polyester catalyst including a reaction product between at least one of Ti(OR)4 and Ti(OH)m(OR)4-m, wherein Rs may be the same or different and each represents a C2-C10 organic group, and m represents an integer of 1-4, and a ligand including nitrogen, sulfur, and/or oxygen as a donor atom, and capable of coordinating with two or more sites.
摘要翻译： 不含锑化合物作为缩聚催化剂制备的聚酯组合物，包括30ppm或更少的锑，0.5-50ppm的钛和0.1-100ppm的磷，具有等于1μm或更大的等同圆直径的含钛颗粒的数密度为 小于100 / 0.02mg; 和如上所述的组合物，其含有0.1-5重量％的平均粒径为0.05-3μm的有机聚合物颗粒，并且含有0.01％或更少的直径至少为平均粒径的两倍的粗颗粒。 包括Ti（OR）4和Ti（OH）m（OR）4-m中的至少一种之间的反应产物的聚酯催化剂，其中Rs可以相同或不同，并且各自表示C2-C10有机基团，m表示 1-4的整数，以及包含氮，硫和/或氧作为供体原子的配体，并且能够与两个或更多个位点配位。
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8.发明申请Polyester resin compositions, catalyst for polyester production, polyester film, and magnetic recording medium 有权聚酯树脂组合物，聚酯生产催化剂，聚酯薄膜和磁记录介质公开(公告)号：US20050239929A1
公开(公告)日：2005-10-27
申请号：US10529847
申请日：2003-10-03
IPC分类号： B32B27/36 , C08G63/85 , C08J5/18 , C08K3/10 , C08K5/49 , C08L25/00 , C08L39/06 , C08L67/02 , C08L101/00 , G11B5/73 , G11B5/733
CPC分类号： B32B27/36 , B32B27/08 , C08G63/85 , C08J5/18 , C08J2367/02 , C08K3/10 , C08K5/49 , C08L25/00 , C08L39/06 , C08L67/02 , C08L101/00 , C08L2201/00 , C08L2205/14 , C08L2205/22 , G11B5/7305 , G11B5/7325 , G11B5/733 , Y10T428/31786 , C08L2666/04 , C08L2666/06 , C08L2666/02
摘要： The present invention aims to provide a practical polyester that can be produced substantially without using an antimony compound as a polycondensation catalyst. (I) The present invention provides a polyester resin composition containing, on a weight basis, 30 ppm or less of antimony, 0.5 to 50 ppm of titanium, and 0.1 to 100 ppm of phosphorus, in which the number density of titanium-containing particles, the equivalent circular diameter of which is 1 μm or more, is less than 100/0.02 mg; and (II) The present invention provides a polyester resin composition containing, on a weight basis, 30 ppm or less of antimony, 0.5 to 50 ppm of titanium, and 0.1 to 100 ppm of phosphorus, in which organic polymer particles are contained in amount of 0.1 to 5 wt %, the organic polymer particles having an average particle diameter determined by dynamic light scattering of 0.05 to 3 μm and containing 0.01% or less of coarse particles relative to the total number of the particles, the coarse particles having a diameter at least twice the average particle diameter.
摘要翻译： 本发明的目的在于提供一种基本上不使用锑化合物作为缩聚催化剂的实际的聚酯。 （I）本发明提供一种聚酯树脂组合物，其含有30ppm以下的锑，0.5〜50ppm的钛和0.1〜100ppm的磷，其中含钛粒子的数密度 其等效圆直径为1um或更大，小于100 / 0.02mg; 和（II）本发明提供一种聚酯树脂组合物，其含有量为30ppm以下的锑，0.5〜50ppm的钛和0.1〜100ppm的磷，其中含有有机聚合物粒子的量 为0.1〜5重量％，通过动态光散射为0.05〜3μm，平均粒径为0.01〜以下的有机聚合物粒子相对于粒子总数为0.01％以下，粗粒子的直径为 至少是平均粒径的两倍。
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公开(公告)号：US5474854A
公开(公告)日：1995-12-12
申请号：US256303
申请日：1994-08-09
CPC分类号： C08J5/18 , C08L67/02 , C08J2367/02 , Y10T428/24355 , Y10T428/24372 , Y10T428/2913 , Y10T428/31786 , Y10T428/31794
摘要： The invention is a polyester composition containing crosslinked polymer particles with ester bonds at the main chain. The particles are excellent in affinity to polyesters, and so the films formed from the polyester compositions do not have the particles falling off during high speed running, and do not have flaws in the film surfaces. The invention can prevent the generation of white powder and the flaws of magnetic faces caused by falling-off particles, and prevent the contamination in the production of films, even though these are problems caused when various conventional particles are added, and is especially suitable for use as products such as magnetic films.
摘要翻译： PCT No.PCT / JP93 / 01631 Sec。 371日期1994年8月9日 102（e）日期1994年8月9日PCT提交1993年11月10日PCT公布。 出版物WO94 / 11438 日期：1994年5月26日。本发明是含有在主链上具有酯键的交联聚合物颗粒的聚酯组合物。 该颗粒对聚酯的亲和性优异，因此由聚酯组合物形成的膜不会在高速运行期间脱落，并且在膜表面没有缺陷。 本发明可以防止白色粉末的产生和由脱落颗粒引起的磁性面的缺陷，并且防止了膜的生成中的污染，即使这些是在添加各种常规颗粒时引起的问题，并且特别适用于 用作磁性膜等产品。
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10.发明授权公开(公告)号：US09290616B2
公开(公告)日：2016-03-22
申请号：US14122275
申请日：2012-05-28
申请人： Yong He , Pujing Zuo , Zinong Ye , Masatoshi Aoyama , Xin Zeng , Xiangqun Fan , Xiaji Dai , Jing Lu
发明人： Yong He , Pujing Zuo , Zinong Ye , Masatoshi Aoyama , Xin Zeng , Xiangqun Fan , Xiaji Dai , Jing Lu
CPC分类号： C08G63/87 , C08G63/08 , C08G63/80 , C08G63/823
摘要： A solid-phase polymerization method of high-molecular-weight aliphatic polyester conducts the solid-phase polymerization of aliphatic polyester prepolymer under a gas stream containing sulfonic acid catalyst. The method features preparing metal free aliphatic polyester with high molecular weight, good color and luster and perfect thermal stability efficiently. The non-metal-ion aliphatic polyester is not only applicable to common use, but is also suitable as high value-added medical material and packing material which contacts with food directly than other metal-containing polyester.
摘要翻译： 高分子量脂肪族聚酯的固相聚合方法在含有磺酸催化剂的气流下进行脂族聚酯预聚物的固相聚合。 该方法具有制备高分子量，良好的色泽和光泽的无机脂肪族聚酯，并有效地提供了完美的热稳定性。 非金属离子脂肪族聚酯不仅适用于常用，而且也适用于与其他含金属聚酯直接接触的高附加值医疗材料和包装材料。
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