Nonaqueous electrolyte cell
    1.
    发明申请
    Nonaqueous electrolyte cell 审中-公开
    非水电解质电池

    公开(公告)号:US20060257743A1

    公开(公告)日:2006-11-16

    申请号:US10558887

    申请日:2004-03-17

    摘要: An object of the present invention is to provide a nonaqueous electrolyte battery which restrains swelling of the battery during high-temperature storage and is excellent in battery performance after storage. The invention is characterized by a specific constitution of a nonaqueous electrolyte and a combination thereof with a positive active material having specific crystal structure and composition. Namely, it is characterized by a nonaqueous electrolyte battery containing a positive electrode, a negative electrode, and a nonaqueous electrolyte, wherein the above nonaqueous electrolyte contains at least a cyclic carbonate having a carbon-carbon π bond and the above positive electrode contains a positive active material comprising a composite oxide represented by a composite formula: LixMnaNibCOcO2 (wherein 0≦x≦1.1, a+b+c=1, |a-b|

    摘要翻译: 本发明的目的是提供一种非水电解质电池,其在高温保存期间抑制电池膨胀,并且在储存后具有优异的电池性能。 本发明的特征在于非水电解质的具体结构及其与具有特定晶体结构和组成的正极活性物质的组合。 也就是说,其特征在于包含正极,负极和非水电解质的非水电解质电池,其中上述非水电解质至少含有具有碳 - 碳p键的环状碳酸酯,上述正极含有正极 包含复合氧化物的活性材料,所述复合氧化物由以下复合式表示:Li x Mn x N a (其中0 <= x <= 1.1,a + b + c = 1,| ab | <0.05,0 型晶体结构。

    ELECTRODE MATERIAL AND LITHIUM ION SECONDARY BATTERY
    2.
    发明申请
    ELECTRODE MATERIAL AND LITHIUM ION SECONDARY BATTERY 审中-公开
    电极材料和锂离子二次电池

    公开(公告)号:US20110001084A1

    公开(公告)日:2011-01-06

    申请号:US12828619

    申请日:2010-07-01

    IPC分类号: H01M4/58

    摘要: The electrode material according to the present invention has a crystal phase in the form of a lattice containing lithium vanadium oxide, such as Li0.3V2O5 with a primary particle diameter of 10 nm or more and 200 nm or less, wherein lithium is arranged in the lattice. Accordingly, when the electrode material is used as the positive electrode material, especially in the crystallized state containing an amorphous glass composition such as phosphor, lithium, antimony (or iron), a high battery capacity can be obtained. Further, even if the charging and discharging are repeated, the crystal structure is difficult to be collapsed, whereby the cycle characteristic is enhanced.

    摘要翻译: 根据本发明的电极材料具有含有锂钒氧化物的晶格形状的结晶相,例如一次粒径为10nm以上且200nm以下的Li 0.3 V 2 O 5,其中,锂配置在 格子。 因此,当电极材料用作正极材料时,特别是在含有诸如磷,锂,锑(或铁)的无定形玻璃组合物的结晶状态下,可以获得高电池容量。 此外,即使重复充放电,晶体结构难以塌陷,从而提高了循环特性。

    ELECTRIC STORAGE DEVICE AND FABRICATING METHOD THEREFOR
    3.
    发明申请
    ELECTRIC STORAGE DEVICE AND FABRICATING METHOD THEREFOR 审中-公开
    电力储存装置及其制造方法

    公开(公告)号:US20100330431A1

    公开(公告)日:2010-12-30

    申请号:US12873934

    申请日:2010-09-01

    摘要: An electrode laminate unit 12 of an electric storage device 10 is composed of positive electrodes 14 and negative electrodes 15, which are alternately laminated, and a lithium electrode 16 is arranged at the outermost part of the electrode laminate unit 12 so as to oppose to the negative electrode 15. A charging/discharging unit 21 having first and second energization control units 21a and 21b is connected to a positive-electrode terminal 18, negative-electrode terminal 19, and a lithium-electrode terminal 20. Electrons are moved from the lithium electrode 16 to the positive electrode 14 through the first energization control unit 21a, and lithium ions are doped into the positive electrode 14 from the lithium electrode 16. Electrons are moved from the lithium electrode 16 to the negative electrode 15 through the second energization control unit 21b, and lithium ions are doped into the negative electrode 15 from the lithium electrode 16. The lithium ions are doped into both of the positive electrode 14 and the negative electrode 15 as described above, whereby the doping time can dramatically be shortened.

    摘要翻译: 蓄电装置10的电极层叠单元12由交替层叠的正极14和负极15构成,锂电极16配置在电极层叠单元12的最外侧,以与电极层叠单元12相对。 负极15.具有第一和第二通电控制单元21a和21b的充电/放电单元21连接到正极端子18,负极端子19和锂电极端子20.电子从锂 电极16通过第一通电控制单元21a连接到正极14,并且锂离子从锂电极16掺杂到正极14中。电子通过第二通电控制单元从锂电极16移动到负极15 21b,并且锂离子从锂电极16掺杂到负极15中。锂离子掺杂到两者中 如上所述,由此可以显着地缩短掺杂时间。

    Electric storage device and fabricating method therefor
    4.
    发明授权
    Electric storage device and fabricating method therefor 有权
    蓄电装置及其制造方法

    公开(公告)号:US07846219B2

    公开(公告)日:2010-12-07

    申请号:US12127989

    申请日:2008-05-28

    IPC分类号: H01M10/38 H01M10/44 H01M4/04

    摘要: An electrode laminate unit of an electric storage device is composed of positive electrodes and negative electrodes, which are alternately laminated, and a lithium electrode arranged at the outermost part of the electrode laminate unit so as to oppose the negative electrode. A charging/discharging unit having first and second energization control units connected to a positive-electrode terminal, negative-electrode terminal, and a lithium-electrode terminal. Electrons are moved from the lithium electrode to the positive electrode through the first energization control unit, and lithium ions are doped into the positive electrode from the lithium electrode. Electrons are moved from the lithium electrode to the negative electrode through the second energization control unit, and lithium ions are doped into the negative electrode from the lithium electrode. The lithium ions are doped into both of the positive and negative electrodes, whereby the doping time can be dramatically shortened.

    摘要翻译: 蓄电装置的电极层叠单元由交替层叠的正极和负极以及布置在电极层叠单元的最外部的锂电极与负极相对。 具有连接到正极端子,负极端子和锂电极端子的第一和第二通电控制单元的充电/放电单元。 电子通过第一通电控制单元从锂电极移动到正电极,并且从锂电极将锂离子掺杂到正极中。 电子通过第二通电控制单元从锂电极移动到负极,并且锂离子从锂电极掺杂到负极中。 锂离子被掺杂到正电极和负电极中,由此可以显着缩短掺杂时间。

    MANUFACTURING METHOD OF ELECTRODE MATERIAL, AND ELECTRIC STORAGE DEVICE
    5.
    发明申请
    MANUFACTURING METHOD OF ELECTRODE MATERIAL, AND ELECTRIC STORAGE DEVICE 审中-公开
    电极材料的制造方法和电储存装置

    公开(公告)号:US20090246633A1

    公开(公告)日:2009-10-01

    申请号:US12410631

    申请日:2009-03-25

    IPC分类号: H01M4/58 H01M4/88

    摘要: When a layered crystal material of vanadium pentoxide that can be used as a positive electrode active material is manufactured, a sulfur-containing organic material is not used as a raw material in the present invention. Therefore, uncertain adhesion of the sulfur-containing organic material to the layered crystal material is eliminated. The property of the suspension containing a vanadium compound and plural lithium compounds such as lithium sulfide and lithium hydroxide is adjusted by using these lithium compounds. By this adjustment, the pentavalence of the vanadium ions is controlled to be a desired ratio. Consequently, an active material having reproducibility can be manufactured. First discharge energy of a lithium ion secondary battery using the active material can be enhanced.

    摘要翻译: 当制造可用作正极活性物质的五氧化二钒的层状结晶材料时,在本发明中不使用含硫有机材料作为原料。 因此,消除了含硫有机材料对层状结晶材料的粘附性的不确定性。 通过使用这些锂化合物调节含有钒化合物的悬浮液的性质和多种锂化合物如硫化锂和氢氧化锂。 通过这种调整,钒离子的五价态被控制为期望的比例。 因此,可以制造具有再现性的活性材料。 可以提高使用活性物质的锂离子二次电池的第一放电能量。

    POSITIVE ELECTRODE ACTIVE MATERIAL PRODUCTION METHOD, POSITIVE ELECTRODE, AND STORAGE DEVICE
    7.
    发明申请
    POSITIVE ELECTRODE ACTIVE MATERIAL PRODUCTION METHOD, POSITIVE ELECTRODE, AND STORAGE DEVICE 审中-公开
    正极电极活性材料生产方法,正电极和存储装置

    公开(公告)号:US20130071749A1

    公开(公告)日:2013-03-21

    申请号:US13613245

    申请日:2012-09-13

    IPC分类号: H01M4/58 H01M4/583

    摘要: There is provided a positive electrode active material production method, a positive electrode, and a storage device. A production method of a positive electrode active material having a LiVPO4F-type crystal structure and containing carbon, includes: a step of synthesizing a precursor that has VPO4 containing carbon, from a starting material in the form of vanadium pentoxide and a phosphate compound, and from a carbon material as an additive; and a step of synthesizing LiVPO4F containing carbon, from the precursor and LiF. The carbon material as an additive is conductive carbon black having a specific surface area of 700 to 1500 m2/g, and in the step of synthesizing the precursor, an addition amount of the conductive carbon black is less than 2 moles per mole of vanadium pentoxide.

    摘要翻译: 提供正极活性物质的制造方法,正极和存储装置。 具有LiVPO 4 F型结晶结构并含有碳的正极活性物质的制造方法包括:从五氧化二钒和磷酸盐化合物的原料合成含有含有VPO 4的前体的工序,以及 从碳材料作为添加剂; 以及从前体和LiF合成含有碳的LiVPO 4 F的工序。 作为添加剂的碳材料是比表面积为700〜1500m 2 / g的导电性炭黑,在合成前体的步骤中,每摩尔五氧化二钒的导电性炭黑的添加量少于2摩尔 。

    PRODUCTION METHOD OF LAYERED CRYSTAL MATERIAL
    9.
    发明申请
    PRODUCTION METHOD OF LAYERED CRYSTAL MATERIAL 审中-公开
    层状材料的生产方法

    公开(公告)号:US20090269274A1

    公开(公告)日:2009-10-29

    申请号:US12425516

    申请日:2009-04-17

    IPC分类号: C01G31/02

    摘要: An ammonium metavanadate is heat-treated to 500° C. or less at a predetermined rate of temperature rise, whereby a microcrystal particle of a vanadium pentoxide can be formed. According to the production method described above, a crystal of a nano-vanadium having a layer length of 100 nm or less can be formed. The nano-vanadium formed by the production method described above can effectively be used for an electrode of an electric storage device such as a battery. The production method according to the present invention can be linked to a conventional production method in which an ammonium metavanadate can be formed in the course of the method, whereby the present invention can smoothly be embodied.

    摘要翻译: 偏钒酸铵以预定的升温速率被热处理至500℃以下,由此可以形成五氧化二钒的微晶粒子。 根据上述制造方法,可以形成层长度为100nm以下的纳米钒的结晶。 通过上述制造方法形成的纳米钒可以有效地用于诸如电池的蓄电装置的电极。 根据本发明的制造方法可以与在该方法中可以形成偏钒酸铵的常规制造方法相关联,由此可以顺利地实现本发明。