摘要:
An object of the present invention is to provide a nonaqueous electrolyte battery which restrains swelling of the battery during high-temperature storage and is excellent in battery performance after storage. The invention is characterized by a specific constitution of a nonaqueous electrolyte and a combination thereof with a positive active material having specific crystal structure and composition. Namely, it is characterized by a nonaqueous electrolyte battery containing a positive electrode, a negative electrode, and a nonaqueous electrolyte, wherein the above nonaqueous electrolyte contains at least a cyclic carbonate having a carbon-carbon π bond and the above positive electrode contains a positive active material comprising a composite oxide represented by a composite formula: LixMnaNibCOcO2 (wherein 0≦x≦1.1, a+b+c=1, |a-b|
摘要翻译:本发明的目的是提供一种非水电解质电池,其在高温保存期间抑制电池膨胀,并且在储存后具有优异的电池性能。 本发明的特征在于非水电解质的具体结构及其与具有特定晶体结构和组成的正极活性物质的组合。 也就是说,其特征在于包含正极,负极和非水电解质的非水电解质电池,其中上述非水电解质至少含有具有碳 - 碳p键的环状碳酸酯,上述正极含有正极 包含复合氧化物的活性材料,所述复合氧化物由以下复合式表示:Li x Mn x N a (其中0 <= x <= 1.1,a + b + c = 1,| ab | <0.05,0 型晶体结构。
摘要:
The electrode material according to the present invention has a crystal phase in the form of a lattice containing lithium vanadium oxide, such as Li0.3V2O5 with a primary particle diameter of 10 nm or more and 200 nm or less, wherein lithium is arranged in the lattice. Accordingly, when the electrode material is used as the positive electrode material, especially in the crystallized state containing an amorphous glass composition such as phosphor, lithium, antimony (or iron), a high battery capacity can be obtained. Further, even if the charging and discharging are repeated, the crystal structure is difficult to be collapsed, whereby the cycle characteristic is enhanced.
摘要翻译:根据本发明的电极材料具有含有锂钒氧化物的晶格形状的结晶相,例如一次粒径为10nm以上且200nm以下的Li 0.3 V 2 O 5,其中,锂配置在 格子。 因此,当电极材料用作正极材料时,特别是在含有诸如磷,锂,锑(或铁)的无定形玻璃组合物的结晶状态下,可以获得高电池容量。 此外,即使重复充放电,晶体结构难以塌陷,从而提高了循环特性。
摘要:
An electrode laminate unit 12 of an electric storage device 10 is composed of positive electrodes 14 and negative electrodes 15, which are alternately laminated, and a lithium electrode 16 is arranged at the outermost part of the electrode laminate unit 12 so as to oppose to the negative electrode 15. A charging/discharging unit 21 having first and second energization control units 21a and 21b is connected to a positive-electrode terminal 18, negative-electrode terminal 19, and a lithium-electrode terminal 20. Electrons are moved from the lithium electrode 16 to the positive electrode 14 through the first energization control unit 21a, and lithium ions are doped into the positive electrode 14 from the lithium electrode 16. Electrons are moved from the lithium electrode 16 to the negative electrode 15 through the second energization control unit 21b, and lithium ions are doped into the negative electrode 15 from the lithium electrode 16. The lithium ions are doped into both of the positive electrode 14 and the negative electrode 15 as described above, whereby the doping time can dramatically be shortened.
摘要:
An electrode laminate unit of an electric storage device is composed of positive electrodes and negative electrodes, which are alternately laminated, and a lithium electrode arranged at the outermost part of the electrode laminate unit so as to oppose the negative electrode. A charging/discharging unit having first and second energization control units connected to a positive-electrode terminal, negative-electrode terminal, and a lithium-electrode terminal. Electrons are moved from the lithium electrode to the positive electrode through the first energization control unit, and lithium ions are doped into the positive electrode from the lithium electrode. Electrons are moved from the lithium electrode to the negative electrode through the second energization control unit, and lithium ions are doped into the negative electrode from the lithium electrode. The lithium ions are doped into both of the positive and negative electrodes, whereby the doping time can be dramatically shortened.
摘要:
When a layered crystal material of vanadium pentoxide that can be used as a positive electrode active material is manufactured, a sulfur-containing organic material is not used as a raw material in the present invention. Therefore, uncertain adhesion of the sulfur-containing organic material to the layered crystal material is eliminated. The property of the suspension containing a vanadium compound and plural lithium compounds such as lithium sulfide and lithium hydroxide is adjusted by using these lithium compounds. By this adjustment, the pentavalence of the vanadium ions is controlled to be a desired ratio. Consequently, an active material having reproducibility can be manufactured. First discharge energy of a lithium ion secondary battery using the active material can be enhanced.
摘要:
A crystal structure is provided to improve a characteristic of an electrode material, such as vanadium oxide. In the crystal structure, an amorphous state and a layered crystal state coexist at a predetermined ratio in a layered crystalline material such as vanadium oxide. In the layered crystalline material having such a layered crystal structure, layered crystal particles having a layer length L1 of 30 nm or shorter are formed. Ions are easily intercalated to and deintercalated from between the layers. When such a material is used for the positive electrode active material, a nonaqueous lithium secondary battery of which the discharge capacity and the cycle characteristic are good is manufactured.
摘要:
There is provided a positive electrode active material production method, a positive electrode, and a storage device. A production method of a positive electrode active material having a LiVPO4F-type crystal structure and containing carbon, includes: a step of synthesizing a precursor that has VPO4 containing carbon, from a starting material in the form of vanadium pentoxide and a phosphate compound, and from a carbon material as an additive; and a step of synthesizing LiVPO4F containing carbon, from the precursor and LiF. The carbon material as an additive is conductive carbon black having a specific surface area of 700 to 1500 m2/g, and in the step of synthesizing the precursor, an addition amount of the conductive carbon black is less than 2 moles per mole of vanadium pentoxide.
摘要:
An ammonium metavanadate is heat-treated to 500° C. or less at a predetermined rate of temperature rise, whereby a microcrystal particle of a vanadium pentoxide can be formed. According to the production method described above, a crystal of a nano-vanadium having a layer length of 100 nm or less can be formed. The nano-vanadium formed by the production method described above can effectively be used for an electrode of an electric storage device such as a battery. The production method according to the present invention can be linked to a conventional production method in which an ammonium metavanadate can be formed in the course of the method, whereby the present invention can smoothly be embodied.
摘要:
The ions other than a lithium ion and having a greater ion radius is interposed, before the lithium ion is doped, as an interlayer securing member in a vanadium oxide having a layered crystal into which the lithium ion can be doped. Since the interlayer securing member is interposed, the dope or dedope of the lithium ion into or from the vanadium oxide afterward can smoothly be performed. A sodium ion or the like can be employed as the interlayer securing member.