Process for producing monosilane
    3.
    发明授权
    Process for producing monosilane 失效
    生产甲硅烷的方法

    公开(公告)号:US4904460A

    公开(公告)日:1990-02-27

    申请号:US337657

    申请日:1989-04-13

    IPC分类号: C01B33/04 C07F7/04

    CPC分类号: C01B33/043 C07F7/045

    摘要: A process for producing monosilane, which comprises disproportionating an alkoxysilane of the formula:H.sub.n Si(OR).sub.4-n (I)wherein R is an alkyl group having from 1 to 6 carbon atoms or a cycloalkyl group and n is an integer of 1, 2 or 3, in the presence of a catalyst, wherein the catalyst comprises at least one compound selected from the group consisting of aromatic alkoxides of the formula:MOAr (II)wherein M is a metal of Group Ia of the Periodic Table and Ar is a substituted or unsubstituted aromatic hydrocarbon group, and quaternary ammonium and phosphonium compounds of the formula:R.sup.1 R.sup.2 R.sup.3 R.sup.4 ZX (III)wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 which may be the same or different, is a substituted or unsubstituted alkyl or aryl group, Z is a nitrogen atom or a phosphorus atom and X is an anion.