摘要:
A process for preparing a biodegradable resin composition, comprising: providing a reaction mixture comprising at least one hydroxycarboxylic acid and, as a polymerization catalyst, a monoorganotin derivative; heating and stirring the reaction mixture, wherein the heating and stirring step is carried out under a reduced pressure to cause condensation polymerization or carried out in an organic solvent to cause azeotropic dehydrating polymerization. Also disclosed in a biodegradable resin composition prepared by the process.
摘要:
A process for the preparation of a readily hydrolyzable and/or biodegradable polyhydroxycarboxylic acid resin which can be used in agricultural materials, gardening materials, fishery materials, caking materials, medical instruments and materials, etc. and, even when discarded after use, which undergoes hydrolysis and/or is biodegraded into carbon dioxide, water, etc. Also disclosed are a hydrolyzable and/or biodegradable polyhydroxycarboxylic acid resin composition having an increased resin strength and melt viscosity, and a process for the preparation thereof.
摘要:
There is provided a method for easily preparing a polyhydroxycarboxylic acid resin in a one pot reaction by adding 1,3-substituted-1,1,3,3-tetraorganodistanoxan as a polymerization catalyst to a hydroxycarboxylic acid, such as L-lactic acid containing 10 to 50% of water as a starting material, and stirring while heating under a reduced pressure condition or in an organic solvent.
摘要:
The present invention relates a biodegradable resin composition comprising an L-lactic acid unit-containing resin (1) and a D-lactic acid unit-containing resin (2). Also disclosed is a biodegradable resin molded article obtained from the biodegradable resin composition.
摘要:
An optical recording material comprising at least one kind of chalcone type compound represented by the following general formula (I) or a metal complex using the chalcone type compound as a ligand: wherein ring A represents a 5- or 6-membered heterocyclic ring or an aromatic ring; ring B represents a 5- or 6-membered heterocyclic ring, an aromatic ring, or a metallocene structure; the above-mentioned heterocyclic and aromatic ring may be condensed with other rings or may be substituted; n is 0 or 1.
摘要:
An optical recording material containing a compound of formula (I): wherein R1 and R2 each represent hydrogen, hydroxyl, halogen, nitro, cyano, a C1-C30 organic group, or a group of formulae (II), (II′) or (III); or R1 and R2 are connected to form a ring; X1 is —CR3R4— or —NH—; Y1 is a C1-C30 organic group or a substituent of formulae (II), (II′) or (III); R3 and R4 each represent hydrogen, a C1-C30 organic group, or a group of formulae (II), (II′) or (III), provided that, when Y1 is a group of formula (III), R3 is hydrogen, a C1-C30 organic group, or a group of formulae (II), (II′) or (III), and when Y1 is a C1-C30 organic group or a group of formulae (II) or (II′), R3 is a group of formulae (II), (II′) or (III); M is Fe, Co, Ni, Ti, Cu, Zn, Zr, Cr, Mo, Os, Mn, Ru, Sn, Pd, Rh, Pt, or Ir; Anq− is a q-valent anion, p is a number necessary to neutralize an electric charge; and q is 1 or 2.
摘要:
There are disclosed an improved method for production of a polarizing glass having a high extinction ratio by facilitating control of the diameter of silver halide particles in a mother glass with high Ag concentration, and a polarizing glass produced by the method. The glass is a polarizing glass having dispersed and oriented geometrically anisotropic metallic silver particles at least in its surface layer, which is characterized by not containing TiO2 exceeding 1.7 wt % but containing not less than 0.4 wt % Ag, and in that Ag and halogens contained therein satisfy the following relations: the molar ratio of Ag/(Cl+Br) is 0.2 to 1.0; the molar ratio of Cl/(Cl+Br+F) 0.5 to 0.95; and the molar ratio of Br/(Cl+Br+F) 0.05 to 0.4. The method for production comprises the steps of drawing a glass containing dispersed AgClxBr1-x crystals, and then reducing it under a reducing atmosphere.
摘要:
The indolium compounds of the present invention are represented by general formula (I) below and exhibit thermal decomposition behavior further suitable for optical recording materials used in an optical recording layer of an optical recording medium for high-speed recording. (In the formula, ring A represents a benzene or naphthalene ring; Z represents, for example, an optionally halogenated C1-8 alkyl group that is optionally interrupted by —O—, —CO—, —OCO—, or —COO—; at least one of R1 and R2 represents a group represented by general formula (II) or (III), and when only one of R1 and R2 is a group represented by general formula (II) or (III), the other represents a C1-30 organic group; R3 and R4 each represent a hydrogen atom, a C1-30 organic group, or others; X represents a C1-8 alkyl group, which is optionally substituted with a halogen atom or a hydroxyl group or optionally interrupted by an ether bond, or others; Y1 represents a hydrogen atom or a C1-30 organic group; n represents an integer of 0 to 4, q represents an integer of 0 to 4; Anm- represents an m-valent anion; m represents 1 or 2; and p represents a coefficient to keep the electric charge neutral.)
摘要:
The cyanine compound of the present invention is represented by general formula (I) below and suitable as an optical recording material used in a recording layer of optical recording media on which recording and play-back are conducted with laser beam. The cyanine compound of the present invention particularly exhibits appropriate thermal decomposition behavior to attain sensitivity compatible with high-speed recording. (In the formula, each of ring A and ring B represents an optionally substituted benzene or naphthalene ring; each of R1 and R2 independently represents a C1-4 alkyl group or an optionally substituted benzyl group; at least one of R1 and R2 is an optionally substituted benzyl group; X represents O, S, or NY; each of Y, Y1, and Y2 independently represents a hydrogen atom or a C1-30 organic group; Z represents a hydrogen atom, a halogen atom, or a cyano group; Anm- represents an m-valent anion; m represents an integer of 1 or 2; and p represents a coefficient to keep an electric charge neutral.)
摘要:
A cyanine compound represented by formula (I): wherein ring A and ring B each represent a substituted or unsubstituted benzene ring or a substituted or unsubstituted naphthalene ring; R1, R2, R3, and R4 each represent an alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted benzyl group, or R1 and R2 are taken together, or R3 and R4 are taken together, to form a 3- to 6-membered ring, provided that at least one of R1, R2, R3, and R4 is a substituted benzyl group; Y1 and Y2 each represent an organic group having 1 to 30 carbon atoms; Anm− represents an m-valent anion; m represents an integer 1 or 2; and p represents a coefficient for maintaining overall charge neutrality.