Abstract:
By forming a structure wherein an oxygen ionic conductor or a mixed ionic-electronic conductor (MIEC) on a cathode surface is not covered by a molten carbonate electrolyte using an oxygen ionic conductor or a mixed ionic-electronic conductor having poor wettability on the molten carbonate electrolyte, a new electrochemical reaction site may be provided in addition to that provided by the molten carbonate electrolyte. As a result, cell performance, particularly cathode performance, can be improved even at low operation temperatures (e.g., 500-600° C.).
Abstract:
Provided is poly(benzimidazole-co-benzoxazole) having polybenzimidazole to which benzoxazole units are introduced, as a polymer electrolyte material. The polymer electrolyte material has both high proton conductivity and excellent mechanical properties even when it is obtained by in-situ phosphoric acid doping. The polymer electrolyte material may substitute for the conventional phosphoric acid-doped polybenzimidazole in a polymer electrolyte membrane fuel cell, particularly in a high-temperature polymer electrolyte membrane fuel cell.
Abstract:
Disclosed are a method for preparing a pure isophthalaldehyde bisulfite adduct free from impurities through a specific purification process, and use thereof as a starting material for polymerizing polybenzimidazole under a mild condition. According to the present disclosure, it is possible to obtain a pure isophthalaldehyde bisulfite adduct free from impurities, such as unreacted materials or byproducts. In addition, it is possible to accomplish industrial mass production of a high-molecular weight polybenzimidazole by using the adduct as a starting material for polymerizing polybenzimidazole under a mild condition in an organic solvent.