公开(公告)号：US20190062246A1

公开(公告)日：2019-02-28

申请号：US16078288

申请日：2017-02-03

申请人： KYOTO UNIVERSITY

发明人： Toyoshi SHIMADA ,  Kazuki NAKANISHI

IPC分类号： C07C43/20 ,  C07C309/66 ,  C07C50/32

摘要： In a production method of the present disclosure, a 1,1′-binaphthyl precursor derivative, an organic acid, and an iodinating or brominating agent are mixed. The 1,1′-binaphthyl precursor derivative has a 1,1′-binaphthyl skeleton and has an electron-donating group at the 2-position of the 1,1′-binaphthyl skeleton and at the 2′-position of the 1,1′-binaphthyl skeleton, and the electron-donating group contains an oxygen atom directly bonded to the skeleton. With the production method of the present disclosure, a 1,1′-binaphthyl derivative having a substituent introduced at the 8-position and/or 8′-position of the 1,1′-binaphthyl skeleton can be obtained. The 1,1′-binaphthyl derivative obtained by the production method of the present disclosure can be a compound further having a substituent introduced at at least one position selected from the 4-position, 4′-position, 5-position, 5′-position, 6-position, and 6′-position of the 1,1′-binaphthyl skeleton.

公开(公告)号：US20170022223A1

公开(公告)日：2017-01-26

申请号：US15125017

申请日：2015-03-09

申请人： KYOTO UNIVERSITY

发明人： Kazuki NAKANISHI ,  Nirmalya MOITRA ,  Kazuyoshi KANAMORI ,  Toyoshi SHIMADA

IPC分类号： C07F7/08 ,  C04B35/628 ,  D21H25/02 ,  C03C17/30 ,  D21C9/00 ,  D06M13/513 ,  C09D5/16 ,  C08B15/06

CPC分类号： C09C1/3081 ,  B01J31/14 ,  C03C17/30 ,  C04B35/628 ,  C04B35/62805 ,  C04B35/62807 ,  C04B35/62813 ,  C04B35/62815 ,  C04B35/62821 ,  C04B35/62823 ,  C04B35/62886 ,  C04B2235/3218 ,  C04B2235/3232 ,  C04B2235/3244 ,  C04B2235/3286 ,  C04B2235/3418 ,  C04B2235/3445 ,  C04B2235/483 ,  C07F7/0838 ,  C07F7/0896 ,  C07F9/4012 ,  C07F9/5355 ,  C07F17/02 ,  C08B15/05 ,  C09C1/00 ,  C09C1/30 ,  C09C1/3063 ,  C09C1/3072 ,  C09D5/1681 ,  D06M13/513 ,  D06M2101/24 ,  D06M2101/32 ,  D06M2200/12 ,  D06M2400/01 ,  D21C9/005 ,  D21H25/02

摘要： The method for producing a surface-modified base material according to the present invention includes a step of bringing a base material having a polar group present on a surface thereof into contact with a hydrosilane compound having a molecular structure A and having a Si—H group composed of a silicon atom of the molecular structure A and a hydrogen atom bonded to the silicon atom in the presence of a borane catalyst so as to allow a dehydrocondensation reaction to take place between the base material and the compound, thereby forming the base material surface-modified with the molecular structure A. This production method is capable of surface-modifying a base material at a lower temperature in a shorter time than conventional methods and allows a wide variety of options for the form, type, and application of the base material, the mode of the modification reaction, and the type of the molecular structure with which the base material is surface-modified.

摘要翻译： 根据本发明的表面改性基材的制造方法包括使具有分子结构A的具有Si-H基的氢硅烷化合物与其表面上存在的具有极性基团的基材接触的工序 由分子结构A的硅原子和在硼烷催化剂的存在下与硅原子键合的氢原子以使得在基材和化合物之间发生脱水反应，从而形成基材表面 用分子结构A改性。该制备方法能够在比常规方法更短的时间内在较低温度下对基材进行表面改性，并且允许用于基材的形式，类型和应用的各种选择 ，改性反应的方式，以及基材表面改性的分子结构的类型。