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公开(公告)号：US07214740B2
公开(公告)日：2007-05-08
申请号：US11120822
申请日：2005-05-03
CPC分类号： C08F214/18 , C08F8/20 , C08F214/262 , C08J5/225 , C08J2327/12 , C08F2216/1475
摘要： The present invention is a fluoropolymer comprising a plurality of pendent groups terminating in —CF2SO3X, —CF2SO2F, or combinations thereof, where X is selected from a group consisting of H+ and a monovalent cation, and at least one —CF2Y end group, where Y is selected from a group consisting of a chlorine atom, a bromine atom, an iodine atom, a nitrile group, and an —SO3X group.
摘要翻译： 本发明是含有多个终止于-CF 2 SO 3 X，-CF 2 SO 2的侧基的含氟聚合物 F或其组合，其中X选自H +和/或一价阳离子和至少一个-CF 2 Y Y端基 其中Y选自氯原子，溴原子，碘原子，腈基和-SO 3 X基。
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2.发明授权Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam 有权通过电子束交联的溴，氯或碘官能聚合物电解质公开(公告)号：US07265162B2
公开(公告)日：2007-09-04
申请号：US10712590
申请日：2003-11-13
申请人： Michael A. Yandrasits , Steven J. Hamrock , Klaus Hintzer , Arne Thaler , Tatsuo Fukushi , Naiyong Jing , Kai Helmut Lochhaas
发明人： Michael A. Yandrasits , Steven J. Hamrock , Klaus Hintzer , Arne Thaler , Tatsuo Fukushi , Naiyong Jing , Kai Helmut Lochhaas
IPC分类号： C08F2/46
CPC分类号： C08J5/225 , B01D67/009 , B01D71/32 , B01D71/82 , C08F114/26 , C08J3/28 , C08J2327/18 , H01M8/1023 , H01M8/1039 , H01M8/1072 , H01M8/1088 , H01M2300/0082 , Y02P70/56
摘要： A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, as well as the polymer so made, the method comprising application of electron beam radiation to a highly fluorinated fluoropolymer comprising: a backbone derived in part from tetrafluoro-ethylene monomer, first pendent groups which include a group according to the formula —SO2X, where X is F, Cl, Br, OH or —O−M+, where M+ is a monovalent cation, and second pendent groups which include Br, Cl or I. Typically, the membrane has a thickness of 90 microns or less, more typically 60 or less, and most typically 30 microns or less.
摘要翻译： 提供了一种用于制造交联聚合物电解质的方法，该电解质通常是在诸如燃料电池的电解槽中用作聚合物电解质膜的膜形式，以及如此制备的聚合物，该方法包括施加电子束 辐射到高度氟化的含氟聚合物，其包含：部分由四氟乙烯单体衍生的主链，第一侧基，其包括根据式-SO 2 X的基团，其中X是F，Cl，Br ，OH或-O - ，其中M +是单价阳离子，第二侧基包括Br，Cl或I. 通常，膜具有90微米或更小，更通常为60或更小，最通常为30微米或更小的厚度。
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公开(公告)号：US08802793B2
公开(公告)日：2014-08-12
申请号：US12915601
申请日：2010-10-29
IPC分类号： C08G75/00
CPC分类号： B01D67/0093 , B01D69/141 , B01D71/32 , B01D2323/30 , C08F214/18 , C08F214/26 , C08J5/2237 , C08J2327/18 , H01M8/1023 , H01M8/1039 , H01M8/106 , H01M8/1081 , H01M8/1088 , Y02P70/56
摘要： A method is provided for obtaining crosslinked polymers having pendent sulfonic acid groups by crosslinking through the sulfonic acid groups or their precursors with aromatic crosslinkers or aromatic pendent crosslinking groups to form aromatic sulfones. Such crosslinked polymers may be used to make polymer electrolyte membranes (PEM's) that may be used in electrolytic cells such as fuel cells.
摘要翻译： 提供了一种通过使用芳族交联剂或芳族侧链交联基团通过磺酸基团或其前体进行交联以形成芳族砜来获得具有侧链磺酸基团的交联聚合物的方法。 这种交联聚合物可用于制备可用于诸如燃料电池的电解池中的聚合物电解质膜（PEM's）。
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公开(公告)号：US08206874B2
公开(公告)日：2012-06-26
申请号：US12266932
申请日：2008-11-07
申请人： Steven J. Hamrock , Matthew H. Frey , Michael A. Yandrasits , Gregory M. Haugen , Andrew M. Herring , James L. Horan , Niccolo V. Aieta
发明人： Steven J. Hamrock , Matthew H. Frey , Michael A. Yandrasits , Gregory M. Haugen , Andrew M. Herring , James L. Horan , Niccolo V. Aieta
IPC分类号： H01M8/10
CPC分类号： H01M8/1032 , C08J5/2231 , C08J2333/02 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/1039 , H01M8/1048
摘要： This disclosure provides polymer electrolytes, polymer electrolyte membranes (PEM's) and membrane electrode assemblies (MEA's) such as may be useful in fuel cells which contain or comprise polyoxometalates (POM's) or heteropolyacids (HPA's). In some embodiments the polyoxometalate, it's counterions or both may comprise Mn and/or Ce. In some embodiments the polymer electrolyte is fluorinated. In some embodiments the polymer electrolyte comprises a second acidic functional group other than a polyoxometalate. In another aspect, the present disclosure provides methods of making polymer electrolytes including methods which comprising a step of copolymerizing monomers comprising a covalently bound polyoxometalates and methods which comprise a step of covalently attaching a polyoxometalate to the polymer.
摘要翻译： 本公开提供了聚合物电解质，聚合物电解质膜（PEM）和膜电极组件（MEA's），例如可用于含有或包含多金属氧酸盐（POM）或杂多酸（HPA））的燃料电池。 在一些实施方案中，多金属氧酸盐，其抗衡离子或两者可以包含Mn和/或Ce。 在一些实施方案中，聚合物电解质是氟化的。 在一些实施方案中，聚合物电解质包含除多金属氧酸盐以外的第二酸性官能团。 在另一方面，本公开提供了制备聚合物电解质的方法，包括使包含共价结合的多金属氧酸盐的单体共聚的步骤的方法和包括将多金属氧酸盐共价连接到聚合物上的步骤的方法。
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公开(公告)号：US08637205B2
公开(公告)日：2014-01-28
申请号：US12972959
申请日：2010-12-20
申请人： Eric J. Iverson , Daniel M. Pierpont , Michael A. Yandrasits , Steven J. Hamrock , Stephan J. Obradovich , Donald G. Peterson
发明人： Eric J. Iverson , Daniel M. Pierpont , Michael A. Yandrasits , Steven J. Hamrock , Stephan J. Obradovich , Donald G. Peterson
CPC分类号： H01M8/2418 , H01M8/0273 , H01M8/0276 , H01M8/0286 , H01M8/1004 , H01M8/1016 , H01M8/242 , H01M2008/1095 , Y02E60/521 , Y02P70/56
摘要： A fuel cell roll good subassembly is described that includes a plurality of individual electrolyte membranes. One or more first subgaskets are attached to the individual electrolyte membranes. Each of the first subgaskets has at least one aperture and the first subgaskets are arranged so the center regions of the individual electrolyte membranes are exposed through the apertures of the first subgaskets. A second subgasket comprises a web having a plurality of apertures. The second subgasket web is attached to the one or more first subgaskets so the center regions of the individual electrolyte membranes are exposed through the apertures of the second subgasket web. The second subgasket web may have little or no adhesive on the subgasket surface facing the electrolyte membrane.
摘要翻译： 描述了包括多个单独的电解质膜的燃料电池辊良好的子组件。 一个或多个第一子垫连接到单独的电解质膜。 每个第一子垫具有至少一个孔，并且第一子垫被布置成使得各个电解质膜的中心区域通过第一子垫的孔露出。 第二子垫包括具有多个孔的腹板。 第二子网腹板附接到一个或多个第一子垫，使得各个电解质膜的中心区域通过第二子网幅的孔露出。 第二子网网在面向电解质膜的子垫表面上可能具有很少或没有粘合剂。
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公开(公告)号：US20130101918A1
公开(公告)日：2013-04-25
申请号：US13699210
申请日：2011-05-18
申请人： Michael A. Yandrasits , Ji-Hwa Lee , Youngdon Yi , Daniel M. Pierpont , Steven J. Hamrock , Mark A. Schonewill
发明人： Michael A. Yandrasits , Ji-Hwa Lee , Youngdon Yi , Daniel M. Pierpont , Steven J. Hamrock , Mark A. Schonewill
IPC分类号： H01M8/10
CPC分类号： H01M8/1053 , C08J5/2206 , C08J2327/16 , H01M8/1023 , H01M8/1039 , H01M8/1051 , H01M8/106 , H01M8/1062 , H01M8/1067 , H01M8/1069 , H01M8/1081 , H01M2300/0082 , H01M2300/0094 , Y02P70/56
摘要： An electrolyte membrane having a proton conducting polymer reinforced with a nanofiber mat made from a nanofiber comprising a fiber material selected from polymers and polymer blends; wherein the fiber material has a fiber material proton conductivity; wherein the proton conducting polymer has a proton conducting polymer conductivity; and wherein the fiber material proton conductivity is less than the proton conducting polymer conductivity, and methods of making. In some embodiments, the nanofiber further comprises a proton conducting polymer.
摘要翻译： 一种具有由纳米纤维制成的纳米纤维毡增强的质子传导性聚合物的电解质膜，其包含选自聚合物和聚合物共混物的纤维材料; 其中所述纤维材料具有纤维材料质子传导性; 其中所述质子传导聚合物具有导电聚合物的导电性; 并且其中所述纤维材料的质子传导性小于质子传导性聚合物的导电性，以及制造方法。 在一些实施方案中，纳米纤维还包含质子传导性聚合物。
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公开(公告)号：US07847035B2
公开(公告)日：2010-12-07
申请号：US11278459
申请日：2006-04-03
IPC分类号： C08G75/00
CPC分类号： B01D67/0093 , B01D69/141 , B01D71/32 , B01D2323/30 , C08F214/18 , C08F214/26 , C08J5/2237 , C08J2327/18 , H01M8/1023 , H01M8/1039 , H01M8/106 , H01M8/1081 , H01M8/1088 , Y02P70/56
摘要： A method is provided for obtaining crosslinked polymers having pendent sulfonic acid groups by crosslinking through the sulfonic acid groups or their precursors with aromatic crosslinkers or aromatic pendent crosslinking groups to form aromatic sulfones. Such crosslinked polymers may be used to make polymer electrolyte membranes (PEM's) that may be used in electrolytic cells such as fuel cells.
摘要翻译： 提供了一种通过使用芳族交联剂或芳族侧链交联基团通过磺酸基或其前体进行交联以形成芳族砜来获得具有侧链磺酸基团的交联聚合物的方法。 这种交联聚合物可用于制备可用于诸如燃料电池的电解池中的聚合物电解质膜（PEM's）。
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公开(公告)号：US07338692B2
公开(公告)日：2008-03-04
申请号：US10661908
申请日：2003-09-12
申请人： Samantha D. Smith , Gene H. Shipman , Robert M. Floyd , Harold Todd Freemyer , Steven J. Hamrock , Michael A. Yandrasits , David G. S. Walton
发明人： Samantha D. Smith , Gene H. Shipman , Robert M. Floyd , Harold Todd Freemyer , Steven J. Hamrock , Michael A. Yandrasits , David G. S. Walton
CPC分类号： H01M8/1044 , B01D67/0009 , B01D67/0011 , B01D67/0016 , B01D67/0027 , B01D69/141 , B01D71/34 , B01D2323/46 , B01D2325/022 , B01D2325/20 , B01D2325/24 , C08J5/2281 , C08J2327/16 , H01M8/1023 , H01M8/1039 , H01M8/1048 , H01M8/106 , H01M8/1079 , H01M8/1083 , Y02E60/521 , Y02P70/56 , Y10T428/1352 , Y10T428/139 , Y10T428/249953 , Y10T428/249958 , Y10T428/249959 , Y10T428/249978 , Y10T428/249987 , Y10T428/3154
摘要： Shaped microporous articles are produced from polyvinylidene fluoride (PVDF) and nucleating agents using thermally induced phase separation (TIPS) processes. The shaped microporous article is oriented in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0. The shaped article may also comprise a diluent, glyceryl triacetate. The shaped microporous article may also have the micropores filled with a sufficient quantity of ion conducting electrolyte to allow the membrane to function as an ion conductive membrane. The method of making a microporous article comprises the steps of melt blending polyvinylidene fluoride, nucleating agent and glyceryl triacetate; forming a shaped article of the mixture; cooling the shaped article to cause crystallization of the polyvinylidene fluoride and phase separation of the polyvinylidene fluoride and glyceryl triacetate; and stretching the shaped article in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0.
摘要翻译： 成型微孔制品由聚偏氟乙烯（PVDF）和使用热诱导相分离（TIPS）工艺的成核剂制备。 成形的微孔制品以至少约1.1至1.0的拉伸比在至少一个方向上取向。 成型制品还可以包含稀释剂，三乙酸甘油酯。 成形的微孔制品也可以具有填充足量的离子导电电解质的微孔，以允许膜用作离子导电膜。 制造微孔制品的方法包括熔融共混聚偏二氟乙烯，成核剂和三乙酸甘油酯的步骤; 形成混合物的成型制品; 冷却成型制品以引起聚偏二氟乙烯的结晶和聚偏二氟乙烯和甘油三乙酸酯的相分离; 并且以至少约1.1至1.0的拉伸比在至少一个方向上拉伸成形制品。
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公开(公告)号：US06780472B2
公开(公告)日：2004-08-24
申请号：US10027933
申请日：2001-12-19
IPC分类号： C08F246
CPC分类号： C08G18/672 , C07D251/34 , C08G18/2875 , C08G18/792 , Y10S524/914 , Y10T428/31547
摘要： A monomer useful in the formulation of a radiation curable coatable composition comprises (a) polyfunctional isocyanurate having at least three terminal reactive groups reacted with (b) hydroxyalkyl acrylate and (c) tertiary amine alcohol in a molar ratio of a:b:c of about 1:1-2.5:0.5-2, wherein b+c is at least 3 and no greater than the total number of terminal reactive groups of (a). The monomer is included in a radiation curable coatable composition suitable for use as a floor finish and in a floor finishing system comprising the foregoing coatable composition with a primer. A method for the treatment of a substrate using the floor finish and the floor finishing system is also described.
摘要翻译： 可用于制备可辐射固化涂层组合物的单体包含（a）具有至少三个末端反应性基团与（b）丙烯酸羟烷基酯和（c）叔胺醇的摩尔比a:b:c的至少三个末端反应性基团反应的多官能异氰脲酸酯 约1：1-2.5：0.5-2，其中b + c为至少3且不大于（a）的末端反应性基团的总数。 该单体包括在适合用作地板表面的可辐射固化的可涂覆组合物中，以及包含前述可涂覆组合物与底漆的地板整理系统中。 还描述了使用地板漆和地板整理系统处理基板的方法。
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公开(公告)号：US07179847B2
公开(公告)日：2007-02-20
申请号：US10712361
申请日：2003-11-13
IPC分类号： C08F2/46
CPC分类号： C08J5/2293 , C08J2327/18 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1072 , Y02P70/56
摘要： A method of making a crosslinked polymer is provided as well as the polymer so made, the method comprising the steps of: providing a highly fluorinated fluoropolymer, typically a perfluorinated fluoropolymer, comprising pendent groups which include a group according to the formula —SO2X, where X is F, Cl, Br, OH, or —O−M+, where M+ is a monovalent cation, and exposing said fluoropolymer to electron beam radiation so as to result in the formation of crosslinks. Typically, the method according to the present invention additionally comprises the step of: forming said fluoropolymer into a membrane, typically having a thickness of 90 microns or less, more typically 60 microns or less, and most typically 30 microns or less.
摘要翻译： 提供制备交联聚合物的方法以及如此制备的聚合物，该方法包括以下步骤：提供高度氟化的含氟聚合物，通常为全氟化含氟聚合物，其包含侧基，其包括根据式-SO 2 X，其中X是F，Cl，Br，OH或-O - ，其中M + 是单价阳离子，并将所述含氟聚合物暴露于电子束辐射，从而导致交联的形成。 通常，根据本发明的方法另外包括以下步骤：将所述含氟聚合物形成膜，通常具有90微米或更小，更典型地为60微米或更小，最通常为30微米或更小的厚度。
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