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    Supported olefin polymerization catalyst, its preparation and use
    1.
    发明授权
    Supported olefin polymerization catalyst, its preparation and use 失效
    负载型烯烃聚合催化剂，其制备与应用

    公开(公告)号：US06291611B1

    公开(公告)日：2001-09-18

    申请号：US08481336

    申请日：1995-08-02

    申请人： Kalle Kallio ,  Ove Andell ,  Hilkka Knuuttila ,  Ulf Palmqvist

    发明人： Kalle Kallio ,  Ove Andell ,  Hilkka Knuuttila ,  Ulf Palmqvist

    IPC分类号： C08F4642

    CPC分类号： C08F10/00 ,  C08F4/63912 ,  C08F4/63916 ,  C08F4/6392 ,  C08F110/02 ,  Y10S526/943 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

    摘要： Olefin polymerization comprising catalysts based on a metallocene, an alumoxane and a support are disclosed. The process for the preparation of a supported olefin ploymerization catalyst comprises: a) a metallocene/activator reaction product, a solvent capable of dissolving it, and a porous support are brought into mutual contact, and b) the solvent is removed, and wherein step a) is carried out so that the porous support is impregnated with a volume of the metallocene/activator reaction product and solvent, which does not exceed the total pore volume of the support.

    摘要翻译： 公开了包含基于茂金属，铝氧烷和载体的催化剂的烯烃聚合。 负载型烯烃聚合催化剂的制备方法包括：a）茂金属/活化剂反应产物，能够溶解的溶剂和多孔载体相互接触，b）除去溶剂，其中步骤a ），使得多孔载体用一定体积的金属茂/活化剂反应产物和溶剂浸渍，其不超过载体的总孔体积。

    Activator system for metallocene compounds
    2.
    发明授权
    Activator system for metallocene compounds 失效
    金属茂化合物的活化剂体系

    公开(公告)号：US06380332B1

    公开(公告)日：2002-04-30

    申请号：US09355309

    申请日：1999-09-23

    申请人： Kalle Kallio ,  Hilkka Knuuttila ,  Kaisa Suominen

    发明人： Kalle Kallio ,  Hilkka Knuuttila ,  Kaisa Suominen

    IPC分类号： C08F416

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65916 ,  C08F210/08

    摘要： Aluminoxanes having C2-C10 alkyl groups can conveniently be used in supported olefin polymerization catalyst compositions prepared by contacting a support comprising a solid compound which is one of pure aluminium oxide, a mixed aluminium oxide, an aluminium salt, a magnesium halide, or a C1-C8 alkoxy magnesium halide, in any order with at least a) an organometallic compound, b) a metallocene, and c) an aluminoxane, and recovering said supported olefin polymerization catalyst composition.

    摘要翻译： 具有C2-C10烷基的氧化铝可以方便地用于通过使包含纯氧化铝，混合氧化铝，铝盐，卤化镁或C1的固体化合物的载体接触而制备的负载型烯烃聚合催化剂组合物 -C8烷氧基卤化镁，以至少为a的任何顺序）有机金属化合物，b）茂金属和c）铝氧烷，并回收所述负载型烯烃聚合催化剂组合物。

    Substituted metallocene compounds for olefin polymerization catalyst systems, their intermediates and methods for preparing them
    4.
    发明授权
    Substituted metallocene compounds for olefin polymerization catalyst systems, their intermediates and methods for preparing them 失效

    公开(公告)号：US06355819B1

    公开(公告)日：2002-03-12

    申请号：US09402934

    申请日：1999-12-20

    申请人： Reko Leino ,  Hendrik Luttikhedde ,  Carl-Eric Wilen ,  Jan Näsman ,  Kalle Kallio ,  Hilkka Knuuttila ,  Jyrki Kauhanen

    发明人： Reko Leino ,  Hendrik Luttikhedde ,  Carl-Eric Wilen ,  Jan Näsman ,  Kalle Kallio ,  Hilkka Knuuttila ,  Jyrki Kauhanen

    IPC分类号： C07F1700

    CPC分类号： C08F10/00 ,  Y10S526/943 ,  C08F4/65927 ,  C08F4/65912

    摘要： The invention relates to metallocene compounds having the formula (I): (CpYq)mMRnBo  (I) wherein: Cp or each same or different Cp is a non-substituted or substituted, fused or non-fused, homo(iso)cyclic or heterocyclic cyclopentadienyl ligand, indenyl ligand, tetrahydroindenyl ligand, fluorenyl ligand or octahydrofluorenyl ligand, Y or each same or different Y is a substituent at the cyclopentadienyl ring of said ligand Cp having the following structure (II): wherein: D is an element of Group 14 of the Periodic Table (IUPAC), R1, R2 and R3 are the same or different and are each one of a hydrogen, a halogen, a substituted or unsubstituted C1-C10 hydrocarbyl group, a substituted or unsubstituted C1-C10 hydrocarbyloxy group, a C1-C12 organosilicon group, or at least two of R1, R2 and R3 form together with D a C4-C20 ring structure; M is a transition metal of Group 4 of the Periodic Table (IUPAC) and is bound to the ligand Cp or ligands Cp in an &eegr;5 bonding mode; R or each same or different R is bound to M and is one of a hydrogen, a halogen, a substituted or unsubstituted C1-C10 hydrocarbyl group, a substituted or unsubstituted C1-C10 hydrocarbyloxy group, a C1-C12 organosilicon group, or two R form together with M a C4-C20 metallocyclic ring structure; B is a bridge atom or group between two Cp ligands or between one Cp ligand and M; q is, when Cp is non-bridged, 0-5 for the cyclopentadienyl ligand, 0-3 for the indenyl or tetrahydroindenyl ligand and 0-1 for the fluorenyl or octahydrofluorenyl ligand, q is, when Cp is bridged, 0-4 for the cyclopentadienyl ligand, 0-2 for the indenyl or tetrahydroindenyl ligand and 0 for the fluorenyl or octahydrofluorenyl ligand; m is 1 or 2; m·q≧1; o is 0 or 1; and n is 4-m-o, except when there is one bridge B between two Cp ligands, in which case n is 4-m, their intermediates, preparation and use.

    Supported olefin polymerization catalyst composition
    5.
    发明授权
    Supported olefin polymerization catalyst composition 失效
    负载型烯烃聚合催化剂组合物

    公开(公告)号：US06720394B1

    公开(公告)日：2004-04-13

    申请号：US09700996

    申请日：2001-01-22

    申请人： Kalle Kallio ,  Marja Mustonen ,  Hilkka Knuuttila

    发明人： Kalle Kallio ,  Marja Mustonen ,  Hilkka Knuuttila

    IPC分类号： C08F4642

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/02 ,  Y10S526/943 ,  C08F4/65916

    摘要： Alumoxanes having C2-C12 alkyl groups can conveniently be used in supported olefin polymerization catalyst compositions prepared by contacting, either previous to or immediately before the beginning of the olefin polymerization, a support comprising a porous carrier with (a) an organometallic compound of the general formula R1MXv−1, (b) a metallocene of the general formula (CpY)mM′X′nZo and an alumoxane of the following general formula in any order.

    摘要翻译： 具有C 2 -C 12烷基的异氰酸酯可以方便地用于通过在烯烃聚合之前或之前或之前使包含多孔载体的载体与（a）一般的有机金属化合物接触而制备的负载型烯烃聚合催化剂组合物 式（R 1 MXv-1），（b）通式（CpY）mM'X'nZo的茂金属和下列通式的铝氧烷任意有序。

    Polymer composition, a process for the production thereof and films prepared thereof
    6.
    发明授权
    Polymer composition, a process for the production thereof and films prepared thereof 有权
    聚合物组合物，其制备方法和其制备的膜

    公开(公告)号：US06632884B1

    公开(公告)日：2003-10-14

    申请号：US09857901

    申请日：2001-10-01

    申请人： Merete Skar ,  Ole Jan Myhre ,  Arja Lehtinen ,  Harri Hokkanen ,  Hilkka Knuuttila ,  Kalle Kallio ,  Esa Kinnunen ,  Eija Lappi

    发明人： Merete Skar ,  Ole Jan Myhre ,  Arja Lehtinen ,  Harri Hokkanen ,  Hilkka Knuuttila ,  Kalle Kallio ,  Esa Kinnunen ,  Eija Lappi

    IPC分类号： C08F2002

    CPC分类号： C08F10/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F110/02 ,  C08F210/16 ,  C08F4/65925 ,  C08F2/001 ,  C08F4/65927 ,  C08F2500/12 ,  C08F2500/07 ,  C08F2500/26 ,  C08F210/08

    摘要： This invention concerns process for producing polyethylene compositions, films prepared thereof and process for the preparation of the films. The process comprises subjecting ethylene, optionally hydrogen and comonomers to polymerization or copolymerization reactions in a multistage polymerization. At least one polymerization stage is conducted essentially in the absence of hydrogen. The polymerization reactions are carried out in the presence of a single-site catalyst capable of forming a composition comprising a low molecular weight component with MFR2 of at least 10 g/10 min and a density higher than the density of the composition and a high molecular weight component. The melt flow rate of the composition is in the range MFR2=0.1-5.0 g/10 min and the density of the composition is 915-960 kg/m3. The invention makes it possible to produce polyethylene compositions for manufacturing films with a good balance between optical and mechanical properties.

    摘要翻译： 本发明涉及生产聚乙烯组合物的方法，其制备的薄膜及其制备方法。 该方法包括使乙烯，任选的氢和共聚单体在多级聚合中进行聚合或共聚反应。 基本上在不存在氢的情况下进行至少一个聚合阶段。 聚合反应在能够形成包含至少10g / 10分钟的MFR低于2分子量组分的组合物的单中心催化剂的存在下进行 并且密度高于组合物的密度和高分子量组分。 组合物的熔体流动速率在MFR 2 = 0.1-5.0g / 10min的范围内，组合物的密度为915-960kg / m 2 <3 。 本发明使得可以生产用于制造具有光学和机械性能之间良好平衡的膜的聚乙烯组合物

    Homogeneous olefin polymerization catalyst composition
    7.
    发明授权
    Homogeneous olefin polymerization catalyst composition 有权
    均相烯烃聚合催化剂组合物

    公开(公告)号：US06316556B1

    公开(公告)日：2001-11-13

    申请号：US09355308

    申请日：1999-07-28

    申请人： Kalle Kallio ,  Hilkka Knuuttila ,  Jyrki Kauhanen

    发明人： Kalle Kallio ,  Hilkka Knuuttila ,  Jyrki Kauhanen

    IPC分类号： C08F458

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/02 ,  Y10S526/943 ,  C08F4/65916

    摘要： The present invention relates to an olefin polymerization catalyst composition comprising a metallocene and an aluminoxane containing alkyl groups with at least two (2) carbon atoms which provides more uniformity than methylaluminoxane, offers greater control and reproducibility of olefin polymerization and greater storage stability. The present invention also provides a method for the preparation of the olefin polymerization catalyst composition.

    摘要翻译： 本发明涉及包含茂金属和含有至少两个（2）碳原子的烷基的铝氧烷的烯烃聚合催化剂组合物，其提供比甲基铝氧烷更均匀的烯烃聚合催化剂组合物，提供了更好的烯烃聚合的控制和再现性以及更高的储存稳定性。 本发明还提供了制备烯烃聚合催化剂组合物的方法。

    Heat sealable polyethylene film and method for its preparation
    10.
    发明授权
    Heat sealable polyethylene film and method for its preparation 有权
    可热封聚乙烯薄膜及其制备方法

    公开(公告)号：US07018710B2

    公开(公告)日：2006-03-28

    申请号：US10312713

    申请日：2001-06-29

    申请人： Kalle Kallio ,  Jari Äärilä ,  Merete Skar ,  Arja Lehtinen

    发明人： Kalle Kallio ,  Jari Äärilä ,  Merete Skar ,  Arja Lehtinen

    IPC分类号： B32B27/08 ,  B32B27/32

    CPC分类号： B32B27/08 ,  B32B27/32 ,  B32B27/327 ,  B32B2250/242 ,  B32B2307/31 ,  B32B2307/412 ,  B32B2307/558 ,  B32B2307/72 ,  B32B2439/70 ,  B32B2439/80 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2314/06 ,  Y10T428/2817 ,  Y10T428/2878 ,  Y10T428/31855 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08L2666/06

    摘要： A process for the preparation of a heat sealable film comprising a core layer and a sealing layer, said process comprising attaching said core layer to said sealing layer, said sealing layer comprising an ethylene copolymer composition in which: (1) there are two distinct maxima in the TREF fractogram of the ethylene copolymer composition; (2) at lest 10%, of the ethylene copolymer composition elutes in TREF at a temperature of less than 50° C.; (3) at least 25%, of the ethylene copolymer composition elutes in TREF at a temperature of higher than 75° C.; (4) none of the ethylene copolymer composition elutes in TREF at a temperature of higher than 100° C.; (5) the ethylene copolymer composition comprises two components, one of which is of relatively high comonomer content and high molecular weight, the other of which is of relatively low comonomer content and low molecular weight, both components being prepared by polymerisation of ethylene with a C3-20 alpha-olefin in the present of a single site catalyst; (6) the ethylene copolymer composition has a density of between 905 and 930 kg/m3, and an MFR2 between 0.3 and 4.0 g/10 min.

    摘要翻译： 一种制备可热封膜的方法，包括芯层和密封层，所述方法包括将所述芯层附着到所述密封层，所述密封层包含乙烯共聚物组合物，其中：（1）存在两个不同的最大值 在乙烯共聚物组成的TREF分解图中; （2）至少10％的乙烯共聚物组合物在低于50℃的温度下在TREF中洗脱; （3）至少25％的乙烯共聚物组合物在高于75℃的温度下在TREF中洗脱; （4）乙烯共聚物组合物中没有一种在高于100℃的温度下在TREF中洗脱。 （5）乙烯共聚物组合物包含两种组分，其中一种组分具有相对高的共聚单体含量和高分子量，另一种组分的共聚单体含量相对较低，分子量低，两种组分均通过乙烯与 单一位点催化剂存在下的3-30-α-烯烃; （6）所述乙烯共聚物组合物的密度在905至930kg / m 3的范围内，MFR 2之间的密度在0.3至4.0g / 10min之间。