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公开(公告)号：US5600044A
公开(公告)日：1997-02-04
申请号：US449151
申请日：1995-05-24
申请人： Karla S. Colle , Christine A. Costello , Russell H. Oelfke , Larry D. Talley , John M. Longo , Enoch Berluche
发明人： Karla S. Colle , Christine A. Costello , Russell H. Oelfke , Larry D. Talley , John M. Longo , Enoch Berluche
CPC分类号： C09K8/52 , C10L3/06 , C09K2208/22 , Y10S585/95 , Y10T137/0329 , Y10T137/0391
摘要： A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is disclosed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitors used for practicing the method are substantially water soluble polymers formed from a N-substituted acrylamide having two nitrogen substituent groups, R.sub.1 and R.sub.2, where R.sub.1 is a hydrocarbon group having from one to ten carbon atoms and zero to four heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur, and combinations thereof, and R.sub.2 is a hydrogen atom or a hydrocarbon group having from one to ten carbon atoms selected from the group consisting of carbon, nitrogen, oxygen, and sulfur; alternatively, R.sub.1 and R.sub.2 may be linked to produce a cyclic ring having ten atoms comprising a combination of between three and ten carbon atoms and zero to four heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur, and combinations thereof. Some examples of such inhibitors include, but are not limited to, poly(N-ethylacrylamide), poly(N,N-diethylacrylamide), poly(N-methyl, N-acrylamide), poly(iso-propylacrylamide), poly(n-propylacrylamide), poly(N-cyclopentylacrylamide), poly(N-cyclohexylacrylamide), poly(acryloylpiperdine), poly(acryloylpiperdine), poly(acryloylmorpholine) and various N-substituted acrylamide copolymers.
摘要翻译： 公开了一种抑制在具有水合物形成成分的流体中形成笼形水合物的方法。 更具体地说，该方法可用于处理在管道中输送的天然气等石油流体流，以抑制管道中的水合物限制。 用于实施该方法的水合物抑制剂基本上是由具有两个氮取代基的N-取代丙烯酰胺R 1和R 2形成的水溶性聚合物，其中R 1是具有1至10个碳原子的烃基和0至4个选自 由氮，氧，硫及其组合构成的组，R2为氢原子或碳原子数为1〜10的选自碳，氮，氧，硫的烃基; 或者，R1和R2可以连接以产生具有10个原子的环，所述原子包含3至10个碳原子和0至4个选自氮，氧，硫及其组合的杂原子的组合。 这些抑制剂的一些实例包括但不限于聚（N-乙基丙烯酰胺），聚（N，N-二乙基丙烯酰胺），聚（N-甲基，N-丙烯酰胺），聚（异丙基丙烯酰胺），聚（n - 丙基丙烯酰胺），聚（N-环戊基丙烯酰胺），聚（N-环己基丙烯酰胺），聚（丙烯酰基哌啶），聚（丙烯酰基哌啶），聚（丙烯酰基吗啉）和各种N-取代的丙烯酰胺共聚物。
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公开(公告)号：US6107531A
公开(公告)日：2000-08-22
申请号：US973110
申请日：1998-01-06
CPC分类号： C09K8/52 , C10L3/06 , C10L3/10 , F17D1/05 , C09K2208/22 , Y10S585/95
摘要： A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate-forming constituents involves treating the fluid with an inhibitor comprising a substantially water soluble polymer having a polymer backbone .with a pendant C.sub.1 --C.sub.3 alkyl group; the polymer having an average molecular weight between about 1,000 and about 6,000,000. Preferably, the pendant alkyl group is a methyl group. The rate of nucleation, growth, and/or agglomeration of gas hydrate crystals in a petroleum fluid stream Is reduced using the alkylated polymer backbone inhibitor, thereby inhibiting the formation of a hydrate blockage in the pipe conveying the petroleum fluid stream. Test results are disclosed which unexpectedly show that alkylating the polymer backbone with a methyl group will produce a subcooling for the alkylated polymer that is at least about 2.degree. F. (about 1.1.degree. C.) greater than its nonalkylated counterpart. The inhibitor can be used conveniently at low concentrations, for example in the range of from about 0.01% to about 5% by weight of the water present in the oil or gas stream, to effectively treat a petroleum fluid having a water phase.
摘要翻译： PCT No.PCT / US96 / 10003 Sec。 371日期：1998年1月6日 102（e）1998年1月6日PCT PCT 1996年6月7日PCT公布。 公开号WO96 / 41786 PCT。 日期：1996年12月27日一种用于抑制在具有水合物形成成分的流体中形成笼形水合物的方法包括用包含具有聚合物主链的基本上水溶性聚合物的抑制剂处理流体，其具有C1-C3烷基侧基; 该聚合物的平均分子量为约1,000至约6,000,000。 优选地，所述侧基烷基是甲基。 使用烷基化聚合物主链抑制剂减少石油流体流中气体水合物晶体的成核，生长和/或附聚的速率，由此抑制输送石油流体流的管道中的水合物阻塞的形成。 公开了测试结果，其意外地显示用甲基烷基化聚合物主链将产生比其非烷基化对应物大至少约2°F（约1.1℃）的烷基化聚合物的过冷却。 抑制剂可以以低浓度方便地使用，例如在油或气流中存在的水的约0.01重量％至约5重量％的范围内，以有效地处理具有水相的石油流体。
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公开(公告)号：US07585816B2
公开(公告)日：2009-09-08
申请号：US10555227
申请日：2004-06-15
申请人： Karla S. Colle , Larry D. Talley , John M. Longo
发明人： Karla S. Colle , Larry D. Talley , John M. Longo
CPC分类号： C09K8/52 , C09K2208/22 , C10L3/00 , C10L3/003 , C10L3/10 , Y10T137/206 , Y10T137/2082
摘要： A method for inhibiting the formation of gas hydrates in a petroleum fluid having hydrate-forming constituents is claimed. More specifically, the method can be used to treat a petroleum fluid, such as natural gas conveyed in a pipe, to inhibit the formation of a hydrate flow restriction in the pipe. The preferred hydrate inhibitors used for practicing the method comprise substantially water soluble homopolymers and copolymers of isopropylmethacrylamide derivatives which have a bimodal molecular weight distribution.
摘要翻译： 要求保护在具有水合物形成成分的石油液体中抑制气体水合物形成的方法。 更具体地，该方法可用于处理石油流体，例如在管道中输送的天然气，以抑制管道中的水合物流动限制的形成。 用于实施该方法的优选水合物抑制剂包含具有双峰分子量分布的基本上水溶性均聚物和异丙基甲基丙烯酰胺衍生物的共聚物。
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公开(公告)号：US07994374B2
公开(公告)日：2011-08-09
申请号：US11883776
申请日：2006-01-17
申请人： Larry D. Talley , Karla S. Colle
发明人： Larry D. Talley , Karla S. Colle
IPC分类号： C07C7/20
CPC分类号： C10L3/06 , C09K2208/22
摘要： A method for treating a fluid having hydrate-forming constituents is provided. In one or more embodiments, the method includes including a mixture (110) comprising glycol and one or more kinetic inhibitors to a fluid (105) that includes one or more hydrate-forming constituents and water to provide a treated fluid comprising the glycol, one or more kinetic inhibitors, one or more hydrate-forming constituents and water. The treated fluid (125) is then separated at conditions sufficient to provide an oil phase stream and an aqueous phase stream, wherein the aqueous phase stream includes one or more kinetic inhibitors, glycol and water.
摘要翻译： 提供了一种处理具有水合物形成成分的流体的方法。 在一个或多个实施方案中，所述方法包括将包含二醇的一种或多种动力学抑制剂的混合物（110）包含在流体（105）中，所述动力学抑制剂包括一种或多种水合物形成组分和水，以提供包含二醇的处理过的流体 或更多的动力学抑制剂，一种或多种水合物形成成分和水。 然后在足以提供油相流和水相流的条件下分离处理过的流体（125），其中水相流包括一种或多种动力学抑制剂，二醇和水。
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公开(公告)号：US20080312478A1
公开(公告)日：2008-12-18
申请号：US11883776
申请日：2006-01-17
申请人： Larry D. Talley , Karla S. Colle
发明人： Larry D. Talley , Karla S. Colle
IPC分类号： C07C9/00
CPC分类号： C10L3/06 , C09K2208/22
摘要： A method for treating a fluid having hydrate-forming constituents is provided. In one or more embodiments, the method includes including a mixture (110) comprising glycol and one or more kinetic inhibitors to a fluid (105) that includes one or more hydrate-forming constituents and water to provide a treated fluid comprising the glycol, one or more kinetic inhibitors, one or more hydrate-forming constituents and water. The treated fluid (125) is then separated at conditions sufficient to provide an oil phase stream and an aqueous phase stream, wherein the aqueous phase stream includes one or more kinetic inhibitors, glycol and water.
摘要翻译： 提供了一种处理具有水合物形成成分的流体的方法。 在一个或多个实施方案中，所述方法包括将包含二醇的一种或多种动力学抑制剂的混合物（110）包含在流体（105）中，所述动力学抑制剂包括一种或多种水合物形成组分和水，以提供包含二醇的处理过的流体 或更多的动力学抑制剂，一种或多种水合物形成成分和水。 然后在足以提供油相流和水相流的条件下分离处理过的流体（125），其中水相流包括一种或多种动力学抑制剂，二醇和水。
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公开(公告)号：US20180328541A1
公开(公告)日：2018-11-15
申请号：US15953893
申请日：2018-04-16
CPC分类号： F17D1/18 , B08B7/0071 , B08B9/027 , B08B2220/01 , C09K8/52 , C09K8/524 , C09K2208/22 , F17D1/088 , F17D3/12
摘要： A method of transporting a mixed phase fluid in a conduit. A hydrate and/or wax film is permitted to deposit on an inner wall of the conduit in a conversion zone, the conversion zone being less than a length of the conduit. A quantity of heat is applied to the conduit in the conversion zone until the hydrate and/or wax deposited on the inner wall in the conversion zone separates therefrom, thereby inhibiting the continual formation of hydrates and/or wax on the inner wall. The separated hydrates and/or wax are flowed in the mixed phase fluid.
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公开(公告)号：US20110308625A1
公开(公告)日：2011-12-22
申请号：US13187226
申请日：2011-07-20
IPC分类号： F15D1/00
CPC分类号： F17D1/14 , C09K8/52 , C09K2208/22 , E21B37/06 , E21B43/017 , E21B43/34 , E21B43/40 , F17D1/17 , F17D3/10 , F17D3/12 , F17D3/14 , Y10T137/0318 , Y10T137/8376 , Y10T137/87571
摘要： Methods and systems are provided for producing hydrocarbons from production fluids that have water as an external phase. A method for transporting a hydrocarbon through a pipeline includes injecting water into a production stream at a production center. The production stream includes a hydrocarbon, and the water injection forms a transportation stream that includes a water external phase. The transportation stream is flowed through a transportation line to a surface facility, wherein the transportation line comprises a plurality of static mixers spaced at intervals along the transportation line.
摘要翻译： 提供了从具有水作为外部相的生产流体生产烃的方法和系统。 通过管道输送碳氢化合物的方法包括将水注入生产中心的生产流中。 生产流包括烃，注水形成包含水外相的输送流。 输送流通过输送管线流到地面设施，其中运输线路包括沿输送线间隔开的多个静态混合器。
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8.发明申请公开(公告)号：US20150260348A1
公开(公告)日：2015-09-17
申请号：US14602987
申请日：2015-01-22
申请人： Larry D. Talley , Jason W. Lachance
发明人： Larry D. Talley , Jason W. Lachance
CPC分类号： F17D1/17 , B01F5/0451 , B01F5/0473 , B01F5/0602 , C10L3/107 , F16L58/00 , Y10T137/2499
摘要： Methods and systems are provided for inhibiting the formation and/or growth of clathrate hydrates in a mixed phase fluid at or near the walls of a tubular through use of a chemical or physical coating on the tubular wall. An exemplary embodiment provides a method for producing a flowable mixed phase fluid having the potential to create clathrate hydrates. The method includes inhibiting hydrate formation in a tubular by injecting an additive into a fluid stream in the tubular, and the additive adheres, at least in part, to the walls of the tubular and inhibits hydrate growth proximate to the wall. When sufficient additive is injected into the tubular system, the hydrate film growth on the tubular walls is inhibited, at least to some extent, and a continuous flow rate is maintained.
摘要翻译： 提供的方法和系统用于通过使用管状壁上的化学或物理涂层来抑制在管壁或其附近的混合相流体中的包合物水合物的形成和/或生长。 一个示例性实施方案提供了一种用于生产具有产生包合物水合物的潜力的可流动混合相流体的方法。 该方法包括通过将管道中的流体流注入添加剂来抑制管中的水合物形成，并且添加剂至少部分地粘附在管壁上并且抑制靠近壁的水合物生长。 当足够的添加剂注入到管状系统中时，管壁上的水合物膜的生长至少在一定程度上被抑制，并且保持连续的流速。
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9.发明授权Distillate fuels containing an amine salt of a sulfonic acid and a low volatility carrier fluid (PNE-554) 失效含有磺酸和低挥发性载体流体的胺盐的蒸馏燃料（PNE-554）
公开(公告)号：US5215548A
公开(公告)日：1993-06-01
申请号：US811409
申请日：1991-12-20
CPC分类号： C10L1/143 , C10L1/14 , C10L10/04 , C10L1/1608 , C10L1/1616 , C10L1/182 , C10L1/1824 , C10L1/1852 , C10L1/191 , C10L1/2222 , C10L1/2225 , C10L1/238 , C10L1/2437 , C10L1/2475 , C10L1/306
摘要： Distillate fuel compositions containing an amine salt of a sulfonic acid and a low volatility carrier fluid are effective in reducing the formation of intake valve deposits in internal combustion engines. Gasoline containing diamine salts in combination with a polyol ester carrier fluid is a particularly preferred distillate fuel composition.
摘要翻译： 包含磺酸的胺盐和低挥发性载体流体的馏出燃料组合物有效地减少内燃机中进气阀沉积物的形成。 含有二胺盐的汽油与多元醇酯载体流体组合是特别优选的馏出物燃料组合物。
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公开(公告)号：US10274381B2
公开(公告)日：2019-04-30
申请号：US14727541
申请日：2015-06-01
申请人： Mohan G. Kulkarni , Larry D. Talley
发明人： Mohan G. Kulkarni , Larry D. Talley
摘要： The present techniques are directed to a pipeline transporting a production fluid including hydrocarbon. An optical fiber is disposed along a length of the pipeline. A control system determines a predicted operating temperature based on pressure and flow rate of the production fluid in the pipeline. The control system determines a measured temperature along the pipeline using the optical fiber. The control system detects and locates a temperature anomaly by comparing the measured temperature of the pipeline to the predicted operating temperature.
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