公开(公告)号：US20110021680A1

公开(公告)日：2011-01-27

申请号：US12934294

申请日：2009-03-18

申请人： Karla S. Colle ,  Phillippe Louis Buess ,  Eddy Theophile Van Driessche ,  Allen D. Godwin ,  Ramzi Yanni Saleh ,  Jon E.R. Stanat ,  Raphael Frans Caers

发明人： Karla S. Colle ,  Phillippe Louis Buess ,  Eddy Theophile Van Driessche ,  Allen D. Godwin ,  Ramzi Yanni Saleh ,  Jon E.R. Stanat ,  Raphael Frans Caers

IPC分类号： C08L91/00 ,  C07C69/66 ,  C07C69/76 ,  C07C69/34

CPC分类号： C08K5/11 ,  C07B41/12 ,  C07C45/50 ,  C07C51/235 ,  C07C67/08 ,  C07C69/30 ,  C08K5/0016 ,  C08K5/103 ,  C08K5/12 ,  C07C69/78 ,  C08L27/06 ,  C07C47/02

摘要： Triglyceride and other polyol ester PVC plasticizers can be produced by recovery of branched C6 to C9 aldehydes from a hydroformylation product, optional hydrogenation to the alcohol, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, ethylene glycol, propylene glycol or mixtures thereof. The branched alkyl chains comprise at least 10% methyl branching. Special triglycerides are derived from branched aliphatic acids having alkyl chains with average carbon numbers from 6 to 9 and at least 10% methyl branching. These triglycerides are fast fusing plasticisers if before esterification with glycerol, an aryl acid is introduced together with the aliphatic acids.

摘要翻译： 甘油三酯和其它多元醇酯类PVC增塑剂可以通过从加氢甲酰化产物回收支链C6至C9醛，任选的氢化成醇，用氧气和/或空气氧化成酸，回收所得酸，并用甘油酯化 ，乙二醇，丙二醇或其混合物。 支链烷基链包含至少10％的甲基支链。 特别的甘油三酸酯衍生自具有平均碳数为6至9和至少10％甲基支链的烷基链的支链脂族酸。 如果在用甘油酯化之前，这些甘油三酯是快速熔化增塑剂，芳基酸与脂肪酸一起引入。

公开(公告)号：US20100305250A1

公开(公告)日：2010-12-02

申请号：US12742505

申请日：2008-10-23

申请人： Karla S. Colle ,  Jon E.R. Stanat ,  Juan J. Reinoso ,  Allen D. Godwin

发明人： Karla S. Colle ,  Jon E.R. Stanat ,  Juan J. Reinoso ,  Allen D. Godwin

IPC分类号： C08K5/1539 ,  C08K5/12

CPC分类号： C08K5/0016 ,  C08K5/12 ,  C08L15/02

摘要： C7-C12 secondary alcohol esters of cyclohexanecarboxylic acids are especially useful as plasticizers for PVC and other plasticizable polymers. In embodiments, these plasticizers are useful in plastisol formulations to help improved processability of flexiblePVC material. In other embodiments these same plasticizers can be used in blends with other plasticizers to improve processability. In preferred embodiments these same plasticizers can be used to prepare flexible PVC compounds with enhanced low temperature flexibility, low toxicity, and improved resistance to outdoor aging.

摘要翻译： 环己烷羧酸的C7-C12仲醇酯特别适用于PVC和其他可塑化聚合物的增塑剂。 在实施方案中，这些增塑剂可用于增塑溶胶配方以有助于改善柔性PVC材料的可加工性。 在其它实施方案中，这些相同的增塑剂可以与其它增塑剂混合使用以改善加工性能。 在优选实施方案中，这些相同的增塑剂可用于制备具有增强的低温柔韧性，低毒性和改善的耐室外老化性能的柔性PVC化合物。

公开(公告)号：US20100160506A1

公开(公告)日：2010-06-24

申请号：US12653742

申请日：2009-12-17

申请人： Margaret May-Som Wu ,  Karla Schall Colle ,  Ramzi Yanni Saleh ,  Allen D. Godwin ,  John Edmond Randolph Stanat

发明人： Margaret May-Som Wu ,  Karla Schall Colle ,  Ramzi Yanni Saleh ,  Allen D. Godwin ,  John Edmond Randolph Stanat

IPC分类号： C08K5/1515 ,  C08K5/109 ,  C07D301/03 ,  C07D317/24 ,  C07C1/207

CPC分类号： C07D317/36 ,  C08L21/00 ,  C10G3/44 ,  C10G3/48 ,  C10G29/205 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1092 ,  C10G2300/30 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/06 ,  C10G2400/10 ,  C10M107/10 ,  C10M2205/0285 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2270/00 ,  Y02P30/20

摘要： This disclosure is directed to an integrated method for making synthetic hydrocarbon fluids, plasticizers and polar synthetic lubricant base stocks from a renewable feedstock. More particularly, the disclosure is directed to a metathesis reaction of natural oil or its derivative ester and ethylene in the presence of an effective amount of a metathesis catalyst to form linear alpha-olefins, internal olefins and reduced chain length triglycerides. The linear alpha-olefins and/or internal olefins are polymerized to produce synthetic hydrocarbon fluids in the presence of a suitable catalyst. The reduced chain length triglycerides are converted into polar synthetic lubricant base stocks or plasticizers by hydrogenation, isomerization, followed by hydrogenations, or by hydroisomerization processes. Alternatively, the reduced chain length triglycerides can also be epoxidized to form epoxidized triglyceride plasticizers, optionally followed by carbonation, to form carbonated triglyceride plasticizers.

摘要翻译： 本发明涉及从可再生原料制备合成烃流体，增塑剂和极性合成润滑剂基础油的综合方法。 更具体地，本公开涉及天然油或其衍生物酯和乙烯在有效量的复分解催化剂存在下的复分解反应，以形成线性α-烯烃，内烯烃和还原链长度甘油三酯。 在合适的催化剂存在下，将线性α-烯烃和/或内烯烃聚合以产生合成烃流体。 还原的链长度甘油三酯通过氢化，异构化，随后氢化或通过加氢异构化方法转化为极性合成润滑剂基础油料或增塑剂。 或者，还原链长度甘油三酯也可以被环氧化以形成环氧化甘油三酯增塑剂，任选地随后碳酸化形成碳酸化甘油三酯增塑剂。

公开(公告)号：US08389625B2

公开(公告)日：2013-03-05

申请号：US12653742

申请日：2009-12-17

申请人： Margaret May-Som Wu ,  Karla Schall Colle ,  Ramzi Yanni Saleh ,  Allen D. Godwin ,  Jon Edmond Randolph Stanat

发明人： Margaret May-Som Wu ,  Karla Schall Colle ,  Ramzi Yanni Saleh ,  Allen D. Godwin ,  Jon Edmond Randolph Stanat

IPC分类号： C08K5/09

CPC分类号： C07D317/36 ,  C08L21/00 ,  C10G3/44 ,  C10G3/48 ,  C10G29/205 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1092 ,  C10G2300/30 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/06 ,  C10G2400/10 ,  C10M107/10 ,  C10M2205/0285 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2270/00 ,  Y02P30/20

摘要： This disclosure is directed to an integrated method for making synthetic hydrocarbon fluids, plasticizers and polar synthetic lubricant base stocks from a renewable feedstock. More particularly, the disclosure is directed to a metathesis reaction of natural oil or its derivative ester and ethylene in the presence of an effective amount of a metathesis catalyst to form linear alpha-olefins, internal olefins and reduced chain length triglycerides. The linear alpha-olefins and/or internal olefins are polymerized to produce synthetic hydrocarbon fluids in the presence of a suitable catalyst. The reduced chain length triglycerides are converted into polar synthetic lubricant base stocks or plasticizers by hydrogenation, isomerization, followed by hydrogenations, or by hydroisomerization processes. Alternatively, the reduced chain length triglycerides can also be epoxidized to form epoxidized triglyceride plasticizers, optionally followed by carbonation, to form carbonated triglyceride plasticizers.

摘要翻译： 本发明涉及从可再生原料制备合成烃流体，增塑剂和极性合成润滑剂基础油的综合方法。 更具体地，本公开涉及天然油或其衍生物酯和乙烯在有效量的复分解催化剂存在下的复分解反应，以形成线性α-烯烃，内烯烃和还原链长度甘油三酯。 在合适的催化剂存在下，将线性α-烯烃和/或内烯烃聚合以产生合成烃流体。 还原的链长度甘油三酯通过氢化，异构化，随后氢化或通过加氢异构化方法转化为极性合成润滑剂基础油料或增塑剂。 或者，还原链长度甘油三酯也可以被环氧化以形成环氧化甘油三酯增塑剂，任选地随后碳酸化形成碳酸化甘油三酯增塑剂。

公开(公告)号：US08283411B2

公开(公告)日：2012-10-09

申请号：US13301375

申请日：2011-11-21

申请人： Claudius Gosse ,  Thomas Marshall Larson ,  Pierre Jean Paul Legrand ,  Raphael Frans Caers ,  Paul H Daniels ,  Allen D. Godwin ,  Didier Naert

发明人： Claudius Gosse ,  Thomas Marshall Larson ,  Pierre Jean Paul Legrand ,  Raphael Frans Caers ,  Paul H Daniels ,  Allen D. Godwin ,  Didier Naert

IPC分类号： C08L27/06

CPC分类号： C08K5/12 ,  C08K5/0016 ,  Y10T428/2933 ,  Y10T428/31797 ,  Y10T428/3192 ,  C08L27/06

摘要： Esters of cyclohexane polycarboxylic acids are used as plasticizers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticizers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticizers may also be included. The formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials such as blood bags and tubing.

摘要翻译： 环己烷多元羧酸的酯用作聚氯乙烯的增塑剂，以使得能够使用较少的聚氯乙烯获得具有相当机械性能的产品。 这些酯的使用还产生具有增加的紫外光稳定性，改进的低温性能，较低粘度和改进的加工性以及燃烧时减少的烟雾的配方。 当环己烷多羧酸的酯可以作为粘度降低剂时，环己烷多元羧酸的酯可以单独使用或与其它增塑剂混合使用。 还可以包括快速熔化增塑剂。 制剂特别可用于生产从半刚性到高度柔性材料的一系列商品，并且特别可用于生产诸如血袋和管材之类的医疗材料。

公开(公告)号：US07585571B2

公开(公告)日：2009-09-08

申请号：US12172513

申请日：2008-07-14

申请人： Claudius Gosse ,  Thomas Marshall Larson ,  Pierre Jean Paul Legrand ,  Raphael Frans Caers ,  Paul H Daniels ,  Allen D. Godwin ,  Didier Naert

发明人： Claudius Gosse ,  Thomas Marshall Larson ,  Pierre Jean Paul Legrand ,  Raphael Frans Caers ,  Paul H Daniels ,  Allen D. Godwin ,  Didier Naert

IPC分类号： B32B27/08 ,  C08K5/12

CPC分类号： C08K5/12 ,  C08K5/0016 ,  Y10T428/2933 ,  Y10T428/31797 ,  Y10T428/3192 ,  C08L27/06

摘要： Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials such as blood bags and tubing.

摘要翻译： 环己烷多元羧酸的酯用作聚氯乙烯的增塑剂，以使得能够使用较少聚氯乙烯获得具有相当机械性能的产品。 这些酯的使用还产生具有增加的紫外光稳定性，改进的低温性能，较低粘度和改进的加工性以及燃烧时减少的烟雾的配方。 当环己烷多元羧酸的酯可以作为粘度降低剂时，环己烷多羧酸的酯可以单独使用或与其它增塑剂混合使用。 还可以包括快速熔化增塑剂。 制剂特别可用于生产从半刚性到高度柔性材料的一系列商品，并且特别可用于生产诸如血袋和管材之类的医疗材料。

公开(公告)号：US20090291304A1

公开(公告)日：2009-11-26

申请号：US12511781

申请日：2009-07-29

申请人： Claudius Gosse ,  Thomas Marshall Larson ,  Pierre Jean Paul Legrand ,  Raphael Frans Caers ,  Paul H. Daniels ,  Allen D. Godwin ,  Didier Naert

发明人： Claudius Gosse ,  Thomas Marshall Larson ,  Pierre Jean Paul Legrand ,  Raphael Frans Caers ,  Paul H. Daniels ,  Allen D. Godwin ,  Didier Naert

IPC分类号： B32B1/00 ,  C08K5/12

CPC分类号： C08K5/12 ,  C08K5/0016 ,  Y10T428/2933 ,  Y10T428/31797 ,  Y10T428/3192 ,  C08L27/06

摘要： Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials such as blood bags and tubing.

摘要翻译： 环己烷多元羧酸的酯用作聚氯乙烯的增塑剂，以使得能够使用较少聚氯乙烯获得具有相当机械性能的产品。 这些酯的使用还产生具有增加的紫外光稳定性，改进的低温性能，较低粘度和改进的加工性以及燃烧时减少的烟雾的配方。 当环己烷多元羧酸的酯可以作为粘度降低剂时，环己烷多羧酸的酯可以单独使用或与其它增塑剂混合使用。 还可以包括快速熔化增塑剂。 制剂特别可用于生产从半刚性到高度柔性材料的一系列商品，并且特别可用于生产诸如血袋和管材之类的医疗材料。

公开(公告)号：US07413813B2

公开(公告)日：2008-08-19

申请号：US11846879

申请日：2007-08-29

申请人： Claudius Gosse ,  Thomas Marshall Larson ,  Pierre Jean Paul Legrand ,  Raphael Frans Caers ,  Paul H Daniels ,  Allen D. Godwin ,  Didier Naert

发明人： Claudius Gosse ,  Thomas Marshall Larson ,  Pierre Jean Paul Legrand ,  Raphael Frans Caers ,  Paul H Daniels ,  Allen D. Godwin ,  Didier Naert

IPC分类号： B32B27/06

CPC分类号： C08K5/12 ,  C08K5/0016 ,  Y10T428/2933 ,  Y10T428/31797 ,  Y10T428/3192 ,  C08L27/06

摘要： Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials such as blood bags and tubing.

摘要翻译： 环己烷多元羧酸的酯用作聚氯乙烯的增塑剂，以使得能够使用较少聚氯乙烯获得具有相当机械性能的产品。 这些酯的使用还产生具有增加的紫外光稳定性，改进的低温性能，较低粘度和改进的加工性以及燃烧时减少的烟雾的配方。 当环己烷多元羧酸的酯可以作为粘度降低剂时，环己烷多羧酸的酯可以单独使用或与其它增塑剂混合使用。 还可以包括快速熔化增塑剂。 制剂特别可用于生产从半刚性到高度柔性材料的一系列商品，并且特别可用于生产诸如血袋和管材之类的医疗材料。

公开(公告)号：US07297738B2

公开(公告)日：2007-11-20

申请号：US10490760

申请日：2002-09-25

申请人： Claudius Gosse ,  Thomas Marshall Larson ,  Pierre Jean Paul Legrand ,  Raphael Frans Caers ,  Paul H Daniels ,  Allen D. Godwin ,  Didier Naert

发明人： Claudius Gosse ,  Thomas Marshall Larson ,  Pierre Jean Paul Legrand ,  Raphael Frans Caers ,  Paul H Daniels ,  Allen D. Godwin ,  Didier Naert

IPC分类号： C08K5/12

CPC分类号： C08K5/12 ,  C08K5/0016 ,  Y10T428/2933 ,  Y10T428/31797 ,  Y10T428/3192 ,  C08L27/06

摘要： Esters of cyclohexane polycarboxylic acids are used as plasticisers for polyvinyl chloride to enable products with comparable mechanical properties to be obtained using less polyvinyl chloride. Use of these esters also produces formulations with increased stability to ultra-violet light, improved low temperature properties, lower viscosity and improved processability as well as reduced smoke on burning. The esters of cyclohexane polycarboxylic acids may be used alone or in admixture with other plasticisers when the esters of cyclohexane polycarboxylic acids may act as viscosity depressants. Fast fusing plasticisers may also be included. The formulations are particularly useful in the production of a range of goods from semi-rigid to highly flexible materials and are particularly useful in the production of medical materials such as blood bags and tubing.

摘要翻译： 环己烷多元羧酸的酯用作聚氯乙烯的增塑剂，以使得能够使用较少聚氯乙烯获得具有相当机械性能的产品。 这些酯的使用还产生具有增加的紫外光稳定性，改进的低温性能，较低粘度和改进的加工性以及燃烧时减少的烟雾的配方。 当环己烷多元羧酸的酯可以作为粘度降低剂时，环己烷多羧酸的酯可以单独使用或与其它增塑剂混合使用。 还可以包括快速熔化增塑剂。 制剂特别可用于生产从半刚性到高度柔性材料的一系列商品，并且特别可用于生产诸如血袋和管材之类的医疗材料。

公开(公告)号：US07425662B2

公开(公告)日：2008-09-16

申请号：US10509356

申请日：2003-03-28

申请人： Jon E. Stanat ,  Georges M. K. Mathys ,  David Wayne Turner ,  Jane C. Cheng ,  Stephen W. Beadle ,  Cesar M. Cheng Guajardo ,  Roger Eijkhoudt ,  Allen D. Godwin ,  Ernest E. Green ,  Charles M. Yarbrough ,  Raphael Frans Caers ,  Carolyn B. Duncan ,  Ramzi Y. Saleh

发明人： Jon E. Stanat ,  Georges M. K. Mathys ,  David Wayne Turner ,  Jane C. Cheng ,  Stephen W. Beadle ,  Cesar M. Cheng Guajardo ,  Roger Eijkhoudt ,  Allen D. Godwin ,  Ernest E. Green ,  Charles M. Yarbrough ,  Raphael Frans Caers ,  Carolyn B. Duncan ,  Ramzi Y. Saleh

IPC分类号： C07C2/20

CPC分类号： C07C2/64 ,  C07C2/12 ,  C07C45/28 ,  C07C51/16 ,  C07C2529/70 ,  C08F10/00 ,  C08F210/10 ,  C10G50/00 ,  C10M129/68 ,  C10M129/95 ,  C10M2207/28 ,  C11D1/667 ,  C11D3/2093 ,  C07C15/107 ,  C08F4/12 ,  C08F4/18 ,  C08F2500/02

摘要： A selectivated molecular sieve, e.g., ZSM-22 or ZSM-23, is used as olefin oligomerization catalyst to provide product, e.g., octenes and dodecenes from butene, having a low degree of branching and hindered double bonds.

摘要翻译： 使用选择性分子筛，例如ZSM-22或ZSM-23作为烯烃低聚催化剂，以提供具有低支化度和受阻双键的产物，例如丁烯中的辛烯和十二碳烯。