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    Method for Producing Tertiary Phosphines
    1.
    发明申请
    Method for Producing Tertiary Phosphines 审中-公开
    生产三膦的方法

    公开(公告)号：US20080146850A1

    公开(公告)日：2008-06-19

    申请号：US11815460

    申请日：2006-02-09

    申请人： Kathrin Wissel ,  Matthias Maase ,  Oliver Huttenloch ,  Toni Flajs ,  Melanie Kuhl

    发明人： Kathrin Wissel ,  Matthias Maase ,  Oliver Huttenloch ,  Toni Flajs ,  Melanie Kuhl

    IPC分类号： C07F9/50

    CPC分类号： C07F9/5081 ,  C07F9/5068

    摘要： Method for producing tertiary phosphines by reacting a compound of the general formula (I) in which A is R1 or L2, B is R2 or L3, the R1 and R2 radicals are each independently an organic radical having in each case from 1 to 30 carbon atoms, where the R1 and R2 radicals may also be joined together; and the leaving groups L1 to L3 are each independently halogen, alkyloxy having from 1 to 10 carbon atoms or aryloxy having from 6 to 10 carbon atoms (a) with an alkali metal in an organic aprotic solvent and (b) a compound of the general formula (II) L4-R3   (II) in which the R3 radical is an organic radical having in each case from 1 to 30 carbon atoms; and the leaving group L4 is halogen, alkyloxy having from 1 to 10 carbon atoms or aryloxy having from 6 to 10 carbon atoms, in which the resulting reaction mixture is hydrolyzed with an aqueous base which has a pH of ≧10 and the organic phase is removed from the aqueous phase.

    摘要翻译： 通过使其中A为R 1或L 2的通式（I）的化合物与B 2反应生成叔膦的方法，B为R 2 O / >或L 3，R 1和R 2基团各自独立地为在每种情况下具有1至30个碳原子的有机基团， 其中R 1和R 2基团也可以连接在一起; 和离去基团L 1至L 3各自独立地为卤素，具有1至10个碳原子的烷氧基或具有6至10个碳原子的芳氧基（a）与 有机质子惰性溶剂中的碱金属和（b）通式（II）的化合物<？in-line-formula description =“In-line Formulas”end =“lead”→> L 4 （II）<？in-line-formula description =“In-line formula”end =“tail”？>其中R 3是基团 在每种情况下具有1至30个碳原子的有机基团; 并且离去基团L 4是卤素，具有1至10个碳原子的烷氧基或具有6至10个碳原子的芳氧基，其中所得反应混合物用具有pH值的碱水溶液水解 > 10，并且从水相中除去有机相。

    Process for the preparation of acylphosphines
    2.
    发明申请
    Process for the preparation of acylphosphines 审中-公开
    制备酰基膦的方法

    公开(公告)号：US20060229469A1

    公开(公告)日：2006-10-12

    申请号：US10565542

    申请日：2004-07-29

    申请人： Oliver Huttenloch ,  Matthias Maase ,  Toni Flajs ,  Jurgen Werner

    发明人： Oliver Huttenloch ,  Matthias Maase ,  Toni Flajs ,  Jurgen Werner

    IPC分类号： C07F9/02

    CPC分类号： C07F9/5036 ,  C07F9/5337

    摘要： A process for the preparation of acylphosphines formula (1) wherein m is 1 or 2; R1, R2, and R3 are organic residues derived from aliphatic or aromatic hydrocarbons; by (1) reacting organic phosphorus halides of formula (II) wherein Y is Br or Cl,with an alkali metal in a solvent in the presence of an activator, wherein the alkali metal is present in the form of a dispersion of alkali metal particles having a mean particle size of ≦500 μm in the solvent, (2) subsequent reaction with acid halides of formula (III) which process is carried out without isolation of the intermediates. Preferably, R1, R2 and R3 are independently from each other phenyl, naphthyl and bi-phenyl, being unsubstituted or substituted by one to five halogen, C1-C8 alky and/or C1-C8 alkoxy. Most preferably, R1 and R3 are phenyl and R2 is 2,4,6-trimethylphenyl. The alkali metal is preferably sodium, the activator is preferably chlorobenzene and/or n-butanol.

    摘要翻译： 制备其中m为1或2的式（1）的酰基膦的方法; R 1，R 2，R 3和R 3是衍生自脂族或芳族烃的有机残基; 通过（1）使其中Y为Br或Cl的式（II）的有机磷卤化物与碱金属在溶剂中在活化剂存在下反应，其中碱金属以碱金属颗粒分散体的形式存在 在溶剂中具有<=500μm的平均粒度，（2）随后与式（III）的酰卤反应，该方法在不分离中间体的情况下进行。 优选地，R 1，R 2和R 3 3彼此独立地为苯基，萘基和双 - 苯基，未被取代或被一个 至5个卤素，C 1 -C 8烷基和/或C 1 -C 8烷氧基。 最优选地，R 1和R 3是苯基，R 2是2,4,6-三甲基苯基。 碱金属优选为钠，活化剂优选为氯苯和/或正丁醇。

    METHOD FOR ISOLATING ACIDS FROM CHEMICAL REACTION MIXTURES BY USING 1-ALKYLIMIDAZOLES
    3.
    发明申请
    METHOD FOR ISOLATING ACIDS FROM CHEMICAL REACTION MIXTURES BY USING 1-ALKYLIMIDAZOLES 审中-公开
    通过使用1-烷基咪唑来分离化学反应混合物中的酸的方法

    公开(公告)号：US20090023933A1

    公开(公告)日：2009-01-22

    申请号：US10596548

    申请日：2004-12-17

    申请人： Matthias Maase ,  Oliver Huttenloch

    发明人： Matthias Maase ,  Oliver Huttenloch

    IPC分类号： C07D233/54

    CPC分类号： C07B63/04 ,  C07F9/025 ,  C07F9/4841

    摘要： Method of separating acids from reaction mixtures by means of an auxiliary base, where the auxiliary base b) reacts with the acid to form a salt which is liquid at temperatures at which the desired product is not significantly decomposed while the liquid salt is being separated off and c) the salt of the auxiliary base forms two immiscible liquid phases with the desired product or the solution of the desired product in a suitable solvent, in which the auxiliary base used is an alkylmidazole, which has a solubility in 30% strength by weight sodium chloride solution at 25° C. of 10% by weight or less and whose hydrochloride has a melting point below 55° C.

    摘要翻译： 通过辅助碱将酸与反应混合物分离的方法，其中辅助碱b）与酸反应以形成盐，其在所需产物在不明显分解的温度下为液体，同时液体盐被分离出 和c）辅助碱的盐与所需产物或所需产物的溶液在合适的溶剂中形成两个不混溶的液相，其中所用的辅助碱是烷基咪唑，其溶解度在30重量％ 25℃的氯化钠溶液为10重量％以下，其盐酸盐的熔点低于55℃。

    Method for extracting impurities using ionic liquids
    8.
    发明授权
    Method for extracting impurities using ionic liquids 失效
    使用离子液体提取杂质的方法

    公开(公告)号：US07605297B2

    公开(公告)日：2009-10-20

    申请号：US10565187

    申请日：2004-07-03

    申请人： Matthias Maase ,  Manuel Budich ,  Georg Groβmann ,  Laszlo Szarvas

    发明人： Matthias Maase ,  Manuel Budich ,  Georg Groβmann ,  Laszlo Szarvas

    IPC分类号： A62D3/36

    CPC分类号： C07B63/00 ,  Y02P20/542

    摘要： The invention relates to a process for the extractive removal of phenols, alcohols, amines, phoshines, hydroxylamines, hydrazines, oximes, imines, water, carboxylic acids, amino acids, hydroxamic acids, sulfinic acids, sulfonic acids, peroxycarboxylic acids, phosphonous acids, phosphinous acids, phosphonic acids, phosphinic acids or phosphoric acids from aprotic solvents by means of ionic liquids of the formula [K]n+[A]n−, where n, [K]+ and An− are defined as in the description.

    摘要翻译： 本发明涉及一种用于萃取去除酚，醇，胺，磷，羟胺，肼，肟，亚胺，水，羧酸，氨基酸，异羟肟酸，亚磺酸，磺酸，过氧羧酸，膦酸， 通过式[K] n + [A] n-，其中n，[K] +和An-的离子液体由非质子传递溶剂中的膦酸，次膦酸或次膦酸或磷酸定义如说明书中所定义。

    Method of preparing ionic liquids
    10.
    发明申请
    Method of preparing ionic liquids 失效
    离子液体的制备方法

    公开(公告)号：US20070142646A1

    公开(公告)日：2007-06-21

    申请号：US10587248

    申请日：2005-01-26

    申请人： Matthias Maase ,  Klemens Massone ,  Laszlo Szarvas

    发明人： Matthias Maase ,  Klemens Massone ,  Laszlo Szarvas

    IPC分类号： C07D233/02 ,  C07D213/06

    CPC分类号： C07D233/56

    摘要： In the process for preparing ionic liquids, an ionic liquid is firstly reacted with an alkoxide or with barium hydroxide and is subsequently neutralized with an acid. The ionic liquid contains a phosphonium and/or ammonium cation and an anion selected from the group consisting of halides, arylsulfonates, alkylsulfonates, sulfate, hydroxysulfate, alkylsulfates, hydrogencarbonate, carbonate. triflate and carboxylates. In this process, virtually any anions can be introduced into the ionic liquids.

    摘要翻译： 在制备离子液体的过程中，首先使离子液体与醇盐或氢氧化钡反应，随后用酸中和。 离子液体含有鏻和/或铵阳离子和选自卤化物，芳基磺酸盐，烷基磺酸盐，硫酸盐，羟基硫酸盐，烷基硫酸盐，碳酸氢盐，碳酸盐的阴离子。 三氟甲磺酸酯和羧酸盐。 在这个过程中，几乎可以将任何阴离子引入到离子液体中。