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1.发明申请Selective Manufacture of N,N'-BIS(Cyanoethyl)-1,2-Ethylenediamine and N, N'-BIS(3-aminopropyl)-1,2-Ethylenediamine 审中-公开选择性制造N，N'-BIS（氰乙基）-1,2-乙二胺和N，N'-BIS（3-氨基丙基）-1,2-乙二胺公开(公告)号：US20080194857A1
公开(公告)日：2008-08-14
申请号：US11673697
申请日：2007-02-12
IPC分类号： C07C255/24 , C07C211/02
CPC分类号： C07C253/30 , C07C209/48 , C07C211/09 , C07C211/10 , C07C255/24
摘要： A method for making N,N′-bis(3-aminopropyl)-1,2-ethylenediamine which comprises reacting acrylonitrile and ethylenediamine in about a 2:1 molar ratio to make a N,N′-bis(cyanoethyl)-1,2-ethylenediamine reaction product and hydrogenating the reaction product, the improvement for improving the selectivity of the reactions to N,N′-bis(2-cyanoethyl)-ethylenediamine and to N,N′-bis(3-aminopropyl)-1,2-ethylenediamine which comprises reacting acrylonitrile and ethylenediamine in the presence of 2-30 wt % water, based on total reactants.
摘要翻译： 一种制备N，N'-双（3-氨基丙基）-1,2-乙二胺的方法，其包括以约2:1的摩尔比使丙烯腈和乙二胺反应以制备N，N'-双（氰基乙基） 2-乙二胺反应产物和氢化反应产物，改进了对N，N'-双（2-氰基乙基） - 乙二胺和N，N'-双（3-氨基丙基）-1的反应的选择性的改进， 2-乙二胺，其包括在2-30重量％水的存在下，基于总反应物使丙烯腈和乙二胺反应。
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公开(公告)号：US5932769A
公开(公告)日：1999-08-03
申请号：US13624
申请日：1998-01-26
IPC分类号： B01J23/89 , C07C209/16 , C07C211/05 , C07C211/06 , C07C211/07 , C07C209/38
CPC分类号： C07C209/16 , B01J23/8913 , B01J23/892
摘要： A process for the production of aliphatic amines by reacting aliphatic alcohols with an amino compound in the presence of a catalyst containing at least two inter-dispersed metals, in a multi-metallic structure, in which at least one of the metals is nickel or cobalt, and at least one other metal is palladium, platinum, rhodium, ruthenium, or copper.
摘要翻译： 在多金属结构中，在至少一种金属是镍或钴的多金属结构中，在含有至少两种相互分散的金属的催化剂的存在下，使脂族醇与氨基化合物反应生产脂族胺的方法 ，并且至少一种其它金属是钯，铂，铑，钌或铜。
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3.发明授权
公开(公告)号：US5886227A
公开(公告)日：1999-03-23
申请号：US958894
申请日：1997-10-28
IPC分类号： C07C213/02 , C07C217/28 , C07C209/48
CPC分类号： C07C213/02
摘要： Disclosed is an improved process for the catalytic hydrogenation of cyanopropionaldehyde alkyl acetals (CPAA) to form the aminobutyraldehyde alkyl acetals. The basic process comprises hydrogenating the cyanopropionaldehyde alkyl acetals by contacting said cyanopropionaldehyde alkyl acetals with hydrogen in the presence of a nickel or cobalt catalyst under conditions for reducing the nitrile group to the primary amine. The improvement resides in effecting the hydrogenation of a cyanopropionitrile dialkyl acetal feedstock containing contaminating levels of cyanopropionaldehyde in the presence of a secondary alkanol or water.
摘要翻译： 公开了用于氰基丙醛烷基缩醛（CPAA）的催化氢化以形成氨基丁醛烷基缩醛的改进方法。 基本方法包括通过在镍或钴催化剂存在下使所述氰基丙醛烷基缩醛与氢接触，在将腈基还原成伯胺的条件下使氰基丙醛烷基缩醛氢化。 改进在于在仲烷醇或水的存在下实现含有污染水平的氰基丙醛的氰基丙腈二烷基缩醛原料的氢化。
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公开(公告)号：US06060624A
公开(公告)日：2000-05-09
申请号：US327656
申请日：1999-06-08
IPC分类号： C07C213/08 , C07C217/08 , C07C205/00
CPC分类号： C07C213/08 , C07B2200/07
摘要： A method for racemizing an enantiomer of an alkoxyamine represented by formula I ##STR1## in which R.sub.1 and R.sub.2 are the same or different C.sub.1 to C.sub.20 alkyl group. A feed containing an enantiomer of the alkoxyamine is passed over a nickel or cobalt catalyst in the presence of hydrogen and ammonia. The racemic mixture formed by this method contains substantially no by-products.
摘要翻译： 由式I表示的烷氧基胺的对映异构体外消旋化的方法，其中R 1和R 2是相同或不同的C 1至C 20烷基。 含有烷氧基胺的对映体的进料在氢和氨的存在下通过镍或钴催化剂。 通过该方法形成的外消旋混合物基本上不含副产物。
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公开(公告)号：US06455744B1
公开(公告)日：2002-09-24
申请号：US09985786
申请日：2001-11-06
IPC分类号： C07C2522
CPC分类号： C07C49/697 , C07B39/00 , C07C17/18 , C07C17/23 , C07C25/22 , C07C45/512 , C07C23/18
摘要： A method of preparing vicinal difluoro aromatic compounds in high yield from hydroxy aromatic compounds and a method of preparing intermediates thereof. The hydroxy aromatic compound can be a mono-, bi- or tricyclic aromatic in which the rings are separate or fused. One or more of the rings can contain heteroatoms, such as oxygen, nitrogen, or sulfur, and can contain one or more substitutions, in addition to the hydroxy substitution.
摘要翻译： 由羟基芳香族化合物高产率制备邻位二氟芳族化合物的方法及其制备中间体的方法。 羟基芳族化合物可以是单环，双环或三环芳族，其中环是分开的或稠合的。 除了羟基取代之外，一个或多个环可以含有杂原子，例如氧，氮或硫，并且可以包含一个或多个取代。
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公开(公告)号：US07030283B2
公开(公告)日：2006-04-18
申请号：US10763366
申请日：2004-01-23
摘要： This invention relates to a process for the preparation of 1,1-difluoroolefins, e.g., difluorovinyl cycloaliphatic compounds such as difluorovinylcyclohexane and derivatives by the dehydrofluorination of a trifluoromethyl-substituted cycloaliphatic compound and the resulting compositions. This method utilizes a “sterically hindered super-base” system represented by the formula M+−NRR−; where M is Na or K and R is a secondary, or tertiary alkyl or cycloalkyl group of amines for effecting dehydrofluorination of the trifluoromethyl group leading to the difluorovinyl based cycloaliphatic compounds. The sterically hindered super base can be formed by the, in situ, reaction of a sodium or potassium alkoxide, e.g., KtBuO with a lithium dialkylamide where the lithium is bonded to nitrogen atom of an amine bearing secondary or tertiary aliphatic groups.
摘要翻译： 本发明涉及一种制备1,1-二氟烯烃的方法，例如二氟乙烯基脂环族化合物如二氟乙烯基环己烷和通过三氟甲基取代的脂环族化合物的脱氟化氢的衍生物和所得组合物。 该方法利用由式M + - NRR - SUP表示的“空间位阻超基”系统。 其中M是Na或K，R是仲烷基或烷基或环烷基的胺，用于实现导致二氟乙烯基的脂环族化合物的三氟甲基的脱氟化氢。 空间位阻的超级碱可以通过钾或钾醇钾例如KtBuO与二烷基氨基锂的原位反应形成，其中锂与带有仲或叔脂族基团的胺的氮原子键合。
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公开(公告)号：US06515191B2
公开(公告)日：2003-02-04
申请号：US10197969
申请日：2002-07-17
IPC分类号： C07C2522
CPC分类号： C07C49/697 , C07B39/00 , C07C17/18 , C07C17/23 , C07C25/22 , C07C45/512 , C07C23/18
摘要： A method of preparing vicinal difluoro aromatic compounds in high yield from hydroxy aromatic compounds and a method of preparing intermediates thereof. The hydroxy aromatic compound can be a mono-, bi- or tricyclic aromatic in which the rings are separate or fused. One or more of the rings can contain heteroatoms, such as oxygen, nitrogen, or sulfur, and can contain one or more substitutions, in addition to the hydroxy substitution.
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公开(公告)号：US07041857B1
公开(公告)日：2006-05-09
申请号：US11221066
申请日：2005-09-07
IPC分类号： C07C29/145 , C07C29/136
CPC分类号： C07C29/145 , C12C11/02 , C07C31/10
摘要： This invention relates to an improvement in a liquid phase process for producing isopropanol by the hydrogenation of acetone in the presence of a hydrogenation catalyst; the improvement comprising; contacting acetone with hydrogen under continuous liquid phase conditions; and, employing a sponge metal catalyst promoted with an effective amount of chromium.
摘要翻译： 本发明涉及通过在氢化催化剂存在下氢化丙酮生产异丙醇的液相方法的改进; 改进包括： 在连续液相条件下使丙酮与氢气接触; 并且使用用有效量的铬促进的海绵金属催化剂。
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公开(公告)号：US06894200B2
公开(公告)日：2005-05-17
申请号：US10357897
申请日：2003-02-03
CPC分类号： C07C49/697 , C07B39/00 , C07C17/18 , C07C17/23 , C07C25/22 , C07C45/512 , C07C23/18
摘要： A method of preparing vicinal difluoro aromatic compounds in high yield from hydroxy aromatic compounds using various bases and a method of preparing intermediates thereof. A method for making a vicinal difluoro halogenated aromatic compound including providing a tetrafluoro derivative of a halogen substituted aromatic compound, wherein the tetrafluoro derivative has two fluorine atoms on each of two adjacent carbons and at least one additional halogen substituent; reacting the tetrafluoro derivative with a reducing agent in presence of a base for a reaction time sufficient to form the vicinal difluoro halogenated aromatic compound containing two vicinal fluorine substituents and the at least one additional halogen substituent, wherein the reducing agent is used in a reducing agent effective amount sufficient to retain the at least one additional halogen substituent.
摘要翻译： 使用各种碱由羟基芳族化合物高收率制备邻位二氟芳族化合物的方法及其制备中间体的方法。 一种制备邻二氟卤代芳族化合物的方法，包括提供卤素取代的芳族化合物的四氟衍生物，其中四氟衍生物在两个相邻碳原子上具有两个氟原子和至少一个另外的卤素取代基; 使四氟衍生物与还原剂在碱的存在下反应足以形成含有两个邻位氟取代基的连位二氟卤代芳族化合物和至少一个另外的卤素取代基的反应时间，其中还原剂用于还原剂 足以保留至少一个另外的卤素取代基的有效量。
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公开(公告)号：US06706933B2
公开(公告)日：2004-03-16
申请号：US10334183
申请日：2002-12-30
IPC分类号： C07C2522
CPC分类号： C07C49/697 , C07B39/00 , C07C17/18 , C07C17/23 , C07C25/22 , C07C45/512 , C07C23/18
摘要： A method of preparing vicinal difluoro aromatic compounds in high yield from hydroxy aromatic compounds and a method of preparing intermediates thereof. The hydroxy aromatic compound can be a mono-, bi- or tricyclic aromatic in which the rings are separate or fused. One or more of the rings can contain heteroatoms, such as oxygen, nitrogen, or sulfur, and can contain one or more substitutions, in addition to the hydroxy substitution.
摘要翻译： 由羟基芳香族化合物高产率制备邻位二氟芳族化合物的方法及其制备中间体的方法。 羟基芳族化合物可以是单环，双环或三环芳族，其中环是分开的或稠合的。 除了羟基取代之外，一个或多个环可以含有杂原子，例如氧，氮或硫，并且可以包含一个或多个取代。
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