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公开(公告)号:US08895685B2
公开(公告)日:2014-11-25
申请号:US13696868
申请日:2011-01-21
申请人: Katja Klimke , Juha Yli-Peltola , Elke Pachner , Doris Machl , Hermann Braun , Susana Filipe , Anh Tuan Tran
发明人: Katja Klimke , Juha Yli-Peltola , Elke Pachner , Doris Machl , Hermann Braun , Susana Filipe , Anh Tuan Tran
IPC分类号: C08F210/06 , C08F110/06 , C08F255/02
CPC分类号: C09D123/26 , C08F10/06 , C08F110/06 , C08F210/06 , C08F255/02 , C08L2312/02 , C09J151/06 , C08F2500/11 , C08F2500/12 , C08F2500/17 , C08F2500/20 , C08F210/16 , C08F236/06
摘要: Polypropylene composition comprising a polypropylene base resin whereby the polypropylene base resin has a MFR (2.16 kg, 230° C., ISO 1133) of 8 to 24 g/10 min and a LAOS-NLF>2.8 whereby LAOS−NLF=|G′1/G′3| where G′1—first order Fourier Coefficient, G′3—third order Fourier Coefficient.
摘要翻译: 包含聚丙烯基础树脂的聚丙烯组合物,由此聚丙烯基础树脂具有8至24g / 10min的MFR(2.16kg,230℃,ISO 1133)和LAOS-NLF> 2.8,由此LAOS-NLF = | G' 1 / G'3 | 其中G'1一阶傅里叶系数,G'3-三阶傅里叶系数。
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公开(公告)号:US20130123416A1
公开(公告)日:2013-05-16
申请号:US13696868
申请日:2011-01-21
申请人: Katja Klimke , Juha Yli-Peltola , Elke Pachner , Doris Machl , Hermann Braun , Susana Filipe , Anh Tuan Tran
发明人: Katja Klimke , Juha Yli-Peltola , Elke Pachner , Doris Machl , Hermann Braun , Susana Filipe , Anh Tuan Tran
IPC分类号: C09D123/26
CPC分类号: C09D123/26 , C08F10/06 , C08F110/06 , C08F210/06 , C08F255/02 , C08L2312/02 , C09J151/06 , C08F2500/11 , C08F2500/12 , C08F2500/17 , C08F2500/20 , C08F210/16 , C08F236/06
摘要: Polypropylene composition comprising a polypropylene base resin whereby the polypropylene base resin has a MFR (2.16 kg, 230° C., ISO 1133) of 8 to 24 g/10 min and a LAOS-NLF>2.8 whereby LAOS−NLF=|/G′1/G′3| where G′1—first order Fourier Coefficient, G′3—third order Fourier Coefficient.
摘要翻译: 包含聚丙烯基础树脂的聚丙烯组合物,由此聚丙烯基础树脂的MFR(2.16kg,230℃,ISO 1133)为8至24g / 10min,LAOS-NLF> 2.8,由此LAOS-NLF = | / G '1 / G'3 | 其中G'1一阶傅里叶系数,G'3-三阶傅里叶系数。
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公开(公告)号:US20140163126A1
公开(公告)日:2014-06-12
申请号:US14112364
申请日:2012-04-26
申请人: Anh Tuan Tran , Katja Klimke , Hermann Braun , Susana Filipe
发明人: Anh Tuan Tran , Katja Klimke , Hermann Braun , Susana Filipe
CPC分类号: C08F10/06 , C08F4/34 , C08F4/65912 , C08F110/06 , C08F210/06 , C08F255/02 , C08L23/12 , C08L2203/14 , C08L2314/06 , C08F2500/11 , C08F2500/12 , C08F236/06 , C08L47/00
摘要: The present invention is concerned with a polypropylene composition comprising a polypropylene base resin, the polypropylene composition having —a XHU content of less than 1.25 wt.-%; —a F30 melt strength of at least 30 cN, determined in the Rheotens test at 200° C.; and —a melt extensibility v30 of at least 200 m/s, determined in the Rheotens test at 200° C. In another aspect the present invention is concerned with a polypropylene composition having an MFR (2.16 kg, 230° C., ISO 1133) of 1.0 to 5.0 g/10 min comprising a polypropylene base resin, the polypropylene base resin being obtainable by producing an intermediate polypropylene having an MFR (2.16 kg, 230° C., ISO 1133) of 0.5 to 2.5 g/10 min in the presence of an asymmetric catalyst; mixing the intermediate polypropylene with peroxide and at least one diene at a temperature of 20 to 90° C. for at least 2 minutes to form a pre-mixed material; melt mixing the pre-mixed material in a melt mixing device at a barrel temperature in the range of 180 to 300° C., whereby the melt mixing device is a melt mixing device includes a feed zone, a kneading zone and a die zone, whereby an initial barrel temperature T1 is maintained in the feed zone, a barrel temperature T2 is maintained in the kneading zone and a die barrel temperature T3 is maintained in the die zone, whereby the barrel temperatures T1, T2, and T3 satisfy the following relation: T1
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公开(公告)号:US09200095B2
公开(公告)日:2015-12-01
申请号:US14112364
申请日:2012-04-26
申请人: Anh Tuan Tran , Katja Klimke , Hermann Braun , Susana Filipe
发明人: Anh Tuan Tran , Katja Klimke , Hermann Braun , Susana Filipe
IPC分类号: C08F10/06 , C08L23/12 , C08F4/34 , C08F4/659 , C08F110/06 , C08F210/06
CPC分类号: C08F10/06 , C08F4/34 , C08F4/65912 , C08F110/06 , C08F210/06 , C08F255/02 , C08L23/12 , C08L2203/14 , C08L2314/06 , C08F2500/11 , C08F2500/12 , C08F236/06 , C08L47/00
摘要: The present invention is concerned with a polypropylene composition comprising a polypropylene base resin, the polypropylene composition having—a XHU content of less than 1.25 wt. %;—a F30 melt strength of at least 30 cN, determined in the Rheotens test at 200° C.; and—a melt extensibility v30 of at least 200 m/s, determined in the Rheotens test at 200° C. In another aspect the present invention is concerned with a polypropylene composition having an MFR (2.16 kg, 230° C., ISO 1133) of 1.0 to 5.0 g/10 min comprising a polypropylene base resin, the polypropylene base resin being obtainable by producing an intermediate polypropylene having an MFR (2.16 kg, 230° C., ISO 1133) of 0.5 to 2.5 g/10 min in the presence of an asymmetric catalyst; mixing the intermediate polypropylene with peroxide and at least one diene at a temperature of 20 to 90° C. for at least 2 minutes to form a pre-mixed material; melt mixing the pre-mixed material in a melt mixing device at a barrel temperature in the range of 180 to 300° C., whereby the melt mixing device is a melt mixing device includes a feed zone, a kneading zone and a die zone, whereby an initial barrel temperature T1 is maintained in the feed zone, a barrel temperature T2 is maintained in the kneading zone and a die barrel temperature T3 is maintained in the die zone, whereby the barrel temperatures T1, T2, and T3 satisfy the following relation: T1
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公开(公告)号:US08686093B2
公开(公告)日:2014-04-01
申请号:US13504900
申请日:2010-10-28
申请人: Katja Klimke , Petar Doshev , Susana Filipe , Anh Tuan Tran
发明人: Katja Klimke , Petar Doshev , Susana Filipe , Anh Tuan Tran
CPC分类号: C08L23/10 , C08L23/142 , C08L23/16 , C08L2205/02 , C08L2207/02 , C08L2207/07 , C08L2308/00 , C08L2314/06 , C08L2666/06
摘要: Heterophasic polypropylene resin having a MFR (2.16 kg, 230° C.) of at least 1.0 g/10 min, determined according to ISO 1133, comprising a propylene random copolymer matrix phase (A), and an ethylene-propylene copolymer rubber phase (B) dispersed within the matrix phase, wherein the heterophasic polypropylene resin has a fraction soluble in p-xylene at 25° C. (XCS fraction) being present in the resin in an amount of 15 to 45 wt % whereby the XCS fraction has an ethylene content of 25 wt % or lower, and a fraction insoluble in p-xylene at 25° C. (XCU fraction), said heterophasic polypropylene resin being characterized by a strain hardening factor (SHF) of 1.7 to 4.0 when measured at a strain rate of 3.0 s−1 and a Hencky strain of 3.0.
摘要翻译: 根据ISO 1133测定的具有至少1.0g / 10min的MFR(2.16kg,230℃)的多相聚丙烯树脂包含丙烯无规共聚物基体相(A)和乙烯 - 丙烯共聚物橡胶相( B)分散在基质相中,其中异相聚丙烯树脂在25℃下具有可溶于对二甲苯的馏分(XCS馏分),其量为15至45重量%,由此XCS馏分具有 乙烯含量为25重量%以下,在25℃下不溶于对二甲苯的馏分(XCU馏分),所述多相聚丙烯树脂的特征在于在应变时测定的应变硬化系数(SHF)为1.7〜4.0 速率为3.0s-1,Hencky菌株为3.0。
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公开(公告)号:US20120220727A1
公开(公告)日:2012-08-30
申请号:US13504900
申请日:2010-10-28
申请人: Katja Klimke , Petar Doshev , Susana Filipe , Anh Tuan Tran
发明人: Katja Klimke , Petar Doshev , Susana Filipe , Anh Tuan Tran
IPC分类号: C08L23/16
CPC分类号: C08L23/10 , C08L23/142 , C08L23/16 , C08L2205/02 , C08L2207/02 , C08L2207/07 , C08L2308/00 , C08L2314/06 , C08L2666/06
摘要: Heterophasic polypropylene resin having a MFR (2.16 kg, 230° C.) of at least 1.0 g/1 Omin, determined according to ISO 1133, comprising a propylene random copolymer matrix phase (A), and an ethylene-propylene copolymer rubber phase (B) dispersed within the matrix phase, wherein the heterophasic polypropylene resin has a fraction soluble in p-xylene at 25° C. (XCS fraction) being present in the resin in an amount of 15 to 45 wt % whereby the XCS fraction has an ethylene content of 25 wt % or lower, and a fraction insoluble in p-xylene at 25 0C (XCU fraction), said heterophasic polypropylene resin being characterised by a strain hardening factor (SHF) of 1.7 to 4.0 when measured at a strain rate of 3.0 s−1 and a Hencky strain of 3.0.
摘要翻译: 根据ISO 1133测定的具有至少1.0g / lOmin的MFR(2.16kg,230℃)的多相聚丙烯树脂包含丙烯无规共聚物基质相(A)和乙烯 - 丙烯共聚物橡胶相( B)分散在基质相中,其中异相聚丙烯树脂在25℃下具有可溶于对二甲苯的馏分(XCS馏分),其量为15至45重量%,由此XCS馏分具有 乙烯含量为25重量%以下,在25℃下不溶于对二甲苯的馏分(XCU馏分),所述多相聚丙烯树脂的特征在于应变率为1.7〜4.0的应变硬化系数(SHF) 3.0 s-1和Hencky菌株3.0。
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公开(公告)号:US20130123431A1
公开(公告)日:2013-05-16
申请号:US13696909
申请日:2010-11-29
申请人: Susana Filipe , Katja Klimke , Anh Tuan Tran , Petar Doshev , Antti Tynys , Martin Obadal , Cornelia Kock , David Friel
发明人: Susana Filipe , Katja Klimke , Anh Tuan Tran , Petar Doshev , Antti Tynys , Martin Obadal , Cornelia Kock , David Friel
IPC分类号: C08L23/12
CPC分类号: C08L23/12 , C08L23/10 , C08L2308/00 , C08L2666/06
摘要: The present invention relates to a polypropylene composition showing a high melt flow rate and high melt strength while maintaining high impact strength. The composition of the present invention is obtainable by using a low molecular weight linear isotactic polypropylene as melt flow enhancer for a high molecular weight polypropylene having a high melt strength and impact strength. The inventive composition could be used for the production of different articles.
摘要翻译: 本发明涉及一种在保持高冲击强度的同时显示高熔体流动速率和高熔体强度的聚丙烯组合物。 通过使用低分子线性全同立构聚丙烯作为具有高熔体强度和冲击强度的高分子量聚丙烯的熔体流动增强剂,可以获得本发明的组合物。 本发明的组合物可用于生产不同的制品。
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公开(公告)号:US08722805B2
公开(公告)日:2014-05-13
申请号:US13696909
申请日:2010-11-29
申请人: Susana Filipe , Katja Klimke , Anh Tuan Tran , Petar Doshev , Antti Tynys , Martin Obadal , Cornelia Kock , David Friel
发明人: Susana Filipe , Katja Klimke , Anh Tuan Tran , Petar Doshev , Antti Tynys , Martin Obadal , Cornelia Kock , David Friel
CPC分类号: C08L23/12 , C08L23/10 , C08L2308/00 , C08L2666/06
摘要: The present invention relates to a polypropylene composition showing a high melt flow rate and high melt strength while maintaining high impact strength. The composition of the present invention is obtainable by using a low molecular weight linear isotactic polypropylene as melt flow enhancer for a high molecular weight polypropylene having a high melt strength and impact strength. The inventive composition could be used for the production of different articles.
摘要翻译: 本发明涉及一种在保持高冲击强度的同时显示高熔体流动速率和高熔体强度的聚丙烯组合物。 通过使用低分子线性全同立构聚丙烯作为具有高熔体强度和冲击强度的高分子量聚丙烯的熔体流动增强剂,可以获得本发明的组合物。 本发明的组合物可用于生产不同的制品。
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公开(公告)号:US20050119462A1
公开(公告)日:2005-06-02
申请号:US10499264
申请日:2002-12-23
申请人: Andrew Kelly , Susana Filipe , Nicole Gnadt , Ana Barbas , Pedro Pissarra
发明人: Andrew Kelly , Susana Filipe , Nicole Gnadt , Ana Barbas , Pedro Pissarra
IPC分类号: C12N15/09 , C07K14/47 , C07K14/54 , C12N1/15 , C12N1/19 , C12N1/21 , C12N5/10 , C12N15/70 , C12P21/02 , C07K14/52 , C07H21/04 , C12N9/00
CPC分类号: C12N15/70 , C07K14/47 , C07K14/5406
摘要: The present invention relates to novel vectors and nucleic acid sequences, which comprise promoters which are induced by nucleotides. The invention further relates to expression vectors utilising elements of the xanthosine operon and methods for the production of heterologous proteins.
摘要翻译: 本发明涉及包含由核苷酸诱导的启动子的新载体和核酸序列。 本发明进一步涉及使用黄大分子操纵子元件的表达载体和用于产生异源蛋白质的方法。
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公开(公告)号:US20130030125A1
公开(公告)日:2013-01-31
申请号:US13575334
申请日:2011-01-27
申请人: Andrey Buryak , Albrecht Dix , Magnus Palmlof , Anneli Pakkanen , Christian Piel , Ayodele Olutayo Fiola , Tore Dreng , Janne Maaranen , Alexander Krajete , Susana Filipe
发明人: Andrey Buryak , Albrecht Dix , Magnus Palmlof , Anneli Pakkanen , Christian Piel , Ayodele Olutayo Fiola , Tore Dreng , Janne Maaranen , Alexander Krajete , Susana Filipe
CPC分类号: C08L23/04 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2308/00 , C08L2666/04
摘要: A polyethylene moulding composition having a multimodal molecular weight distribution, having a density according to ISO 1183 at 23° C. in the range of 920 to 960 kg/m3 and an MFR190/2 according to ISO 1133 in the range of 0.05 to 10 g/10 min, said polyethylene moulding composition comprising at least three ethylene polymer fractions having distinct molecular weights: A) 15 to 50 wt % of a low molecular weight ethylene homopolymer or copolymer fraction with a weight average molecular weight Mw in the range of 15 to 40 kg/mol; B) 15 to 50 wt % of a medium molecular weight ethylene homopolymer or copolymer fraction with a weight average molecular weight Mw in the range of 70 to 200 kg/mol; and C) 15 to 50 wt % of a high molecular weight ethylene homopolymer or copolymer fraction with a weight average molecular weight Mw in the range of 220 to 400 kg/mol, provided that one of A, B and C is an ethylene homopolymer and at least one other component is an ethylene copolymer with at least one C3-C10 comonomer; and wherein the composition has—a Shore D hardness measured according to ASTM D2240-05 (15 sec) of at least 56.0.
摘要翻译: 具有多峰分子量分布的聚乙烯模塑组合物,其在23℃下的密度在920至960kg / m 3范围内,根据ISO 1133的MFR190 / 2在0.05至10g的范围内 10分钟,所述聚乙烯模塑组合物包含至少三种具有不同分子量的乙烯聚合物级分:A)15至50重量%的低分子量乙烯均聚物或共聚物部分,其重均分子量Mw在15至 40公斤/摩尔; B)15至50重量%的中等分子量的乙烯均聚物或共聚物部分,其重均分子量Mw为70-200kg / mol; 和C)15至50重量%的重均分子量Mw在220至400kg / mol范围内的高分子量乙烯均聚物或共聚物部分,条件是A,B和C中的一个是乙烯均聚物, 至少一种其它组分是与至少一种C 3 -C 10共聚单体的乙烯共聚物; 并且其中所述组合物具有根据ASTM D2240-05(15秒)测量的至少56.0的肖氏D硬度。
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