公开(公告)号：US06914087B2

公开(公告)日：2005-07-05

申请号：US09926632

申请日：2001-03-29

申请人： Katsuhiko Okada ,  Tetsuro Agawa ,  Kouji Shinohara ,  Yoshitaka Konishi

发明人： Katsuhiko Okada ,  Tetsuro Agawa ,  Kouji Shinohara ,  Yoshitaka Konishi

IPC分类号： B05D7/24 ,  C09D5/03 ,  C09D7/12 ,  C09D201/02 ,  C09D201/06 ,  B05D1/36 ,  C08L63/00

CPC分类号： C09D5/03

摘要： A powder coating is provided which does not require a long complicated production process, can be produced easily and with no danger of gelling occurring during production, and which forms a paint film with superior smoothness and with no film defects such as bubbles or pinholes. A powder coating raw materials solution comprising as essential constituents a room temperature solid main constituent resin (A) with a curable reactive group, a room temperature solid curing agent (B) which reacts with the curable reactive group of the main constituent resin (A), and an organic solvent (C), is spray dried at a temperature at which the main constituent resin (A) and the curing agent (B) undergo no substantial curing reaction.

摘要翻译： 提供粉末涂料，其不需要长的复杂生产工艺，可以容易地制备，并且在生产过程中不会发生胶凝的危险，并且形成具有优异平滑度和没有膜缺陷如气泡或针孔的漆膜。 一种粉末涂料原料溶液，其包含具有可固化反应性基团的室温固体主要构成树脂（A）和与主要构成树脂（A）的可固化反应性基团反应的室温固体固化剂（B）作为必要组分） 和有机溶剂（C）在主要构成树脂（A）和固化剂（B）不发生实质固化反应的温度下进行喷雾干燥。

公开(公告)号：US06515046B2

公开(公告)日：2003-02-04

申请号：US09828472

申请日：2001-04-09

申请人： Katsuhiko Okada ,  Tetsuro Agawa

发明人： Katsuhiko Okada ,  Tetsuro Agawa

IPC分类号： C08K505

CPC分类号： C08J3/122 ,  C08J2333/06 ,  C09D133/068 ,  C09D133/10 ,  C08L2666/34

摘要： A method of manufacturing a powder coating is provided which does not require a long complicated process, which enables the paint to be manufactured easily and with good conservation of energy, and moreover is free of any danger of gelling during the manufacturing process. The powder coating is manufactured by spray drying a powder coating raw materials solution comprising, as essential constituents, an epoxy group containing acrylic resin (A), a polyvalent carboxylic acid (B), and an organic solvent (C) incorporating an alcohol (C-1) of 2 to 4 carbon atoms, at a temperature at which the epoxy group containing acrylic resin (A) and the polyvalent carboxylic acid (B) undergo no substantial curing reaction.

公开(公告)号：US06844397B2

公开(公告)日：2005-01-18

申请号：US10142879

申请日：2002-05-13

申请人： Naoyuki Seike ,  Koichi Yamaguchi ,  Katsuhiko Okada ,  Tetsuro Agawa

发明人： Naoyuki Seike ,  Koichi Yamaguchi ,  Katsuhiko Okada ,  Tetsuro Agawa

IPC分类号： C08L33/06 ,  C09D133/14 ,  B32B15/08 ,  B32B27/30 ,  C08L33/14

CPC分类号： C09D133/14 ,  C08L33/068 ,  Y10T428/31511 ,  Y10T428/31692 ,  Y10T428/31909 ,  C08L2666/04 ,  C08L2666/28

摘要： The present invention provides a powder coating composition, which can ensure excellent smoothness, scratch resistance, water resistance and humidity resistance, when formed into a thin film, and a coating film forming method. The powder coating composition contains an epoxy group-containing vinyl copolymer (A) having a glass transition temperature of 40° C. or higher and a number-average molecular weight of 1,000 to 2,500, an epoxy group-containing vinyl copolymer (B) having a glass transition temperature of 0° C. or lower, and a polycarboxylic acid (C). 30 to 90% by weight of a polymerization unit of the epoxy group-containing vinyl copolymer (B) originates in a methacrylic acid alkyl ester (b-1) which has an alkyl group having 8 or more carbon atoms.

摘要翻译： 本发明提供一种粉末涂料组合物，其可以在形成薄膜时确保优异的平滑性，耐刮擦性，耐水性和耐湿性，以及涂膜形成方法。 粉末涂料组合物含有玻璃化转变温度为40℃以上，数均分子量为1,000〜2,500的含环氧基的乙烯基共聚物（A），含有环氧基的乙烯基共聚物（B）具有 玻璃化转变温度为0℃以下，多元羧酸（C）。 30〜90重量％的含环氧基乙烯基共聚物（B）的聚合单元来源于具有碳原子数为8以上的烷基的甲基丙烯酸烷基酯（b-1）。

公开(公告)号：US06649267B2

公开(公告)日：2003-11-18

申请号：US10166358

申请日：2002-06-11

申请人： Tetsuro Agawa ,  Katsuhiko Okada ,  Hiroo Tanaka ,  Masaya Hashimoto ,  Takaaki Asakura

发明人： Tetsuro Agawa ,  Katsuhiko Okada ,  Hiroo Tanaka ,  Masaya Hashimoto ,  Takaaki Asakura

IPC分类号： B32B2738

CPC分类号： C09D133/14 ,  C08L33/068 ,  C08L2205/02 ,  Y10T428/26 ,  Y10T428/31511 ,  Y10T428/31938 ,  C08L2666/04 ,  C08L2666/28

摘要： A thermosetting powder coating composition has an average particle diameter of entire particles is within a range from 5 to 50 &mgr;m, an average circularity of the particles is 0.90 or more, and a circularity of particles having a maximum number frequency in circularity distribution is within a range from 0.98 to 1.00, prepared by spray-drying an organic solvent solution containing, as a coating film forming component, an epoxy group-containing vinyl copolymer (A) having a glass transition temperature of 40° C. or higher, an epoxy group-containing vinyl copolymer (B) having a glass transition temperature of 0° C. or lower and a polycarboxylic acid (C) as an essential component.

摘要翻译： 平均粒径为5〜50μm的热固性粉末涂料组合物，其平均圆形度为0.90以上，圆形分布中具有最大频率的粒子的圆形度为 通过喷雾干燥含有玻璃化转变温度为40℃以上的含环氧基的乙烯基共聚物（A）作为涂膜形成组分的有机溶剂溶液制备，范围为0.98至1.00，环氧基 （B），其玻璃化转变温度为0℃以下，多元羧酸（C）为必须成分。

公开(公告)号：US20070240613A1

公开(公告)日：2007-10-18

申请号：US10592115

申请日：2005-03-09

申请人： Naoyuki Seike ,  Koichi Yamaguchi ,  Yutaka Furuya ,  Tetsuro Agawa

发明人： Naoyuki Seike ,  Koichi Yamaguchi ,  Yutaka Furuya ,  Tetsuro Agawa

IPC分类号： C09K3/00

CPC分类号： C09D5/03 ,  C08L33/068 ,  C08L83/10 ,  C09D133/068 ,  C09D183/10 ,  Y10S525/934 ,  Y10T428/31692 ,  Y10T428/31909 ,  C08L2666/04

摘要： A powder coating composition of the present invention includes, as essential components, an epoxy group-containing vinyl copolymer (A) with a glass transition temperature of 40° C. or higher, an epoxy group-containing vinyl copolymer (B) that contains organosiloxane side chains and has a glass transition temperature of 0° C. or lower, and a polyvalent carboxylic acid (C), and is able to form a coating film with excellent external appearance and scratch resistance.

摘要翻译： 作为必要成分，本发明的粉末涂料组合物含有玻璃化转变温度为40℃以上的含环氧基的乙烯基共聚物（A），含有有机硅氧烷的含环氧基的乙烯基共聚物（B） 侧链，玻璃化转变温度为0℃以下，多价羧酸（C），能够形成外观优异，耐擦伤性优异的涂膜。

公开(公告)号：US20070149755A1

公开(公告)日：2007-06-28

申请号：US10583910

申请日：2004-12-14

申请人： Yutaka Furuya ,  Koichi Yamaguchi ,  Tetsuro Agawa ,  Kazuo Yamamura

发明人： Yutaka Furuya ,  Koichi Yamaguchi ,  Tetsuro Agawa ,  Kazuo Yamamura

IPC分类号： C09D5/46 ,  C09D133/14

CPC分类号： C09D5/033 ,  C09D133/14 ,  C09D167/00

摘要： This thermosetting powder coating composition is a thermosetting powder coating composition which contains a coating forming component which can crosslink and harden by an ester exchange reaction between a carboxylic ester group and a hydroxyl group, and an ester exchange reaction catalyst, in which the ester exchange reaction catalyst is constituted from an organic sulfonate (X) derived from a carboxylic amide and an organic sulfonic acid having fluorine atoms.

摘要翻译： 这种热固性粉末涂料组合物是含有可通过羧酸酯基和羟基之间的酯交换反应而交联并硬化的涂料形成组分的热固性粉末涂料组合物和酯交换反应催化剂 催化剂由衍生自羧酸酰胺的有机磺酸酯（X）和具有氟原子的有机磺酸构成。

公开(公告)号：US6090890A

公开(公告)日：2000-07-18

申请号：US652595

申请日：1996-08-13

申请人： Ichiro Murakami ,  Shoji Akamatsu ,  Tetsuro Agawa

发明人： Ichiro Murakami ,  Shoji Akamatsu ,  Tetsuro Agawa

IPC分类号： C08L63/00 ,  C08G59/30 ,  C08G59/32 ,  C08L67/00 ,  C09D5/03 ,  C09D163/00 ,  C09D183/04 ,  C09D183/06 ,  C08G77/14

CPC分类号： C09D163/00 ,  C08G59/306 ,  C08G59/3254 ,  C09D183/06 ,  Y10S525/934

摘要： Resin composition for powder paints, that has an excellent curability and excellent electrostatic properties (wraparound) and that provides cured coatings having an excellent appearance, weathering resistance, and mechanical properties, comprising (A) epoxy-functional branched organopolysiloxane and (B) a compound bearing a functional group reactive with the epoxy group, wherein the component (A)/component (B) weight ratio is from 2/98 to 98/2, or comprising (A) epoxy-functional branched organopolysiloxane, (3) a compound bearing a functional group reactive with the epoxy group, and (C) a compound bearing a functional group reactive with the functional group in component (B), wherein the component (A)/(component (B)+component (C)) weight ratio is from 2/98 to 98/2.

摘要翻译： PCT No.PCT / JP95 / 02093 Sec。 371日期：1996年8月13日 102（e）日期1996年8月13日PCT提交1995年10月12日PCT公布。 WO96 / 11988 PCT公开 日期1996年04月25日具有优异的固化性和优异的静电性能（环绕）的粉末涂料用树脂组合物，提供具有优异外观，耐候性和机械性能的固化涂料，其包含（A）环氧官能的支链有机聚硅氧烷和 （B）具有与环氧基反应的官能团的化合物，其中组分（A）/组分（B）的重量比为2/98〜98/2，或包含（A）环氧官能的支链有机聚硅氧烷，（ 3）具有与环氧基反应的官能团的化合物，（C）具有与组分（B）中的官能团反应的官能团的化合物，其中组分（A）/（组分（B）+组分 C））重量比为2/98〜98/2。

公开(公告)号：US06710137B2

公开(公告)日：2004-03-23

申请号：US10060215

申请日：2002-02-01

申请人： Akira Matsumoto ,  Tetsuro Agawa

发明人： Akira Matsumoto ,  Tetsuro Agawa

IPC分类号： C08G1882

CPC分类号： C08G18/8074 ,  C08G18/341 ,  C08G18/345 ,  C08G18/4219 ,  C08G18/6659 ,  C08G18/798 ,  C08G2150/20 ,  C08L33/068 ,  C09D5/03 ,  Y10T428/31551

摘要： The present invention provides a resin composition for a powder coating, which can form a coating film having superior appearance, superior flexibility and superior weatherability while maintaining the storage stability of the coating, and to provide a powder coating and an article coated therewith. The resin composition comprises a polyester resin (A) having a hydroxyl group or having a hydroxyl group and an acid group, isophthalic acid accounting for 50 mol % or more of a polycarboxylic acid unit constituting the polyester resin; a crystalline polyurethane resin (B); and a curing agent (C-1) made of a compound having a functional group reactive with the hydroxyl group or a combination of a curing agent (C-1) made of a compound having a functional group reactive with the hydroxyl group and a curing agent (C-2) made of a compound having a functional group reactive with the acid group.

摘要翻译： 本发明提供一种粉末涂料用树脂组合物，其能够在保持涂料的保存稳定性的同时形成具有优异的外观，优异的柔软性和优异的耐候性的涂膜，并且提供粉末涂料和涂布的制品。 树脂组合物包含具有羟基或羟基和酸基的聚酯树脂（A），间苯二甲酸占构成聚酯树脂的多元羧酸单元的50摩尔％以上; 结晶聚氨酯树脂（B）; 和由具有与羟基反应的官能团的化合物制成的固化剂（C-1）或由具有与羟基反应的官能团的化合物制成的固化剂（C-1）和固化剂 试剂（C-2）由具有与酸基反应的官能团的化合物制成。

公开(公告)号：US06613840B2

公开(公告)日：2003-09-02

申请号：US10013709

申请日：2001-12-13

申请人： Hiroyuki Itou ,  Tetsuro Agawa

发明人： Hiroyuki Itou ,  Tetsuro Agawa

IPC分类号： C09D16702

CPC分类号： C09D167/00 ,  Y10S525/934 ,  Y10T428/31511 ,  Y10T428/31551 ,  C08L75/04

摘要： A resin composition for a powder coating, which comprises a non-crystalline polyester resin (A) having a carboxyl group, a crystalline polyester polyurethane resin (B) and a curing agent (C) made of a compound having a functional group reactable with the carboxyl group as an essential component, yields a powder coating which is highly suitable for practical use, the powder coating having superior storage stability (blocking resistance) and forming a coating film having superior smoothness under low temperature curing conditions.

公开(公告)号：US07960475B2

公开(公告)日：2011-06-14

申请号：US10592115

申请日：2005-03-09

申请人： Naoyuki Seike ,  Koichi Yamaguchi ,  Yutaka Furuya ,  Tetsuro Agawa

发明人： Naoyuki Seike ,  Koichi Yamaguchi ,  Yutaka Furuya ,  Tetsuro Agawa

IPC分类号： C08F8/00

CPC分类号： C09D5/03 ,  C08L33/068 ,  C08L83/10 ,  C09D133/068 ,  C09D183/10 ,  Y10S525/934 ,  Y10T428/31692 ,  Y10T428/31909 ,  C08L2666/04

摘要： A powder coating composition of the present invention includes, as essential components, an epoxy group-containing vinyl copolymer (A) with a glass transition temperature of 40° C. or higher, an epoxy group-containing vinyl copolymer (B) that contains organosiloxane side chains and has a glass transition temperature of 0° C. or lower, and a polyvalent carboxylic acid (C), and is able to form a coating film with excellent external appearance and scratch resistance.

摘要翻译： 作为必要成分，本发明的粉末涂料组合物含有玻璃化转变温度为40℃以上的含环氧基的乙烯基共聚物（A），含有有机硅氧烷的含环氧基的乙烯基共聚物（B） 侧链，玻璃化转变温度为0℃以下，多价羧酸（C），能够形成外观优异，耐擦伤性优异的涂膜。