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    Lithium ion-conductive solid electrolyte and method for producing the same
    1.
    发明授权
    Lithium ion-conductive solid electrolyte and method for producing the same 失效
    锂离子导电固体电解质及其制造方法

    公开(公告)号：US5958281A

    公开(公告)日：1999-09-28

    申请号：US833208

    申请日：1997-04-14

    申请人： Kazunori Takada ,  Kazuya Iwamoto ,  Shigeo Kondo ,  Nobuhiko Ikeda ,  Kazutomi Yamamoto ,  Toshikatsu Uematsu

    发明人： Kazunori Takada ,  Kazuya Iwamoto ,  Shigeo Kondo ,  Nobuhiko Ikeda ,  Kazutomi Yamamoto ,  Toshikatsu Uematsu

    IPC分类号： C01B17/22 ,  C01B33/00 ,  H01B1/06 ,  H01M6/18 ,  H01M10/0562 ,  H01M4/36

    CPC分类号： H01M6/18 ,  C01B17/22 ,  C01B33/00 ,  C01P2006/40 ,  H01M2300/0068

    摘要： A method for producing an electrochemically advantageous lithium ion-conductive solid electrolyte with high ionic conductivity, low electronic conduction and electrochemical stability is disclosed. The method comprises the steps of synthesizing lithium sulfide by reacting lithium hydroxide with a gaseous sulfur source at a temperature of not less than 130.degree. C. and not more than 445.degree. C., thermally melting plural compounds containing at least silicon sulfide and the synthesized lithium sulfide, and cooling the molten mixture. The silicon sulfide is synthesized by the steps of adding a silicon powder to molten sulfur while stirring to disperse the silicon powder in the molten sulfur and heating the silicon powder-dispersed sulfur in a reaction chamber under reduced pressure.

    摘要翻译： 公开了一种制备具有高离子导电性，低电子传导性和电化学稳定性的电化学有利的锂离子传导性固体电解质的方法。 该方法包括以下步骤：在不低于130℃且不高于445℃的温度下，使氢氧化锂与气态硫源反应合成硫化锂，将至少含有硫化硅的多种化合物热合并合成 硫化锂，并冷却熔融混合物。 硫化硅通过在搅拌下将硅粉加入熔融硫中以将硅粉分散在熔融硫中并在减压下加热反应室中的硅粉分散硫的步骤合成。

    Lithium secondary battery with a high charge-discharge efficiency and a low self-discharging tendency
    4.
    发明授权
    Lithium secondary battery with a high charge-discharge efficiency and a low self-discharging tendency 有权
    具有高充放电效率和低自放电倾向的锂二次电池

    公开(公告)号：US06322929B1

    公开(公告)日：2001-11-27

    申请号：US09240689

    申请日：1999-02-02

    申请人： Kazunori Takada ,  Makoto Fujino ,  Kazuya Iwamoto ,  Shigeo Kondo

    发明人： Kazunori Takada ,  Makoto Fujino ,  Kazuya Iwamoto ,  Shigeo Kondo

    IPC分类号： H01M618

    CPC分类号： H01M4/131 ,  H01M4/485 ,  H01M4/5825 ,  H01M6/18 ,  H01M10/0562 ,  H01M2300/0068

    摘要： A lithium secondary battery free from problems encountered with a positive electrode active material exhibiting an electrode potential of not lower than 4.5 volts versus Li—a deterioration in performances because of self-discharge with decomposition of the electrolyte. The lithium secondary battery uses a sulfide based lithium ion conductive solid electrolyte as the electrolyte. Thus, a lithium secondary battery with a very low self-discharge tendency, that is, with the decomposition of electrolyte highly controlled, can be obtained even using the positive electrode active material generating a high voltage.

    摘要翻译： 锂电池没有遇到电极电位不低于4.5伏特的正极活性物质所遇到的问题，相对于Li-由于电解质分解导致的自放电而导致的性能劣化。 锂二次电池使用基于硫化物的锂离子传导性固体电解质作为电解质。 因此，即使使用产生高电压的正极活性物质，也可以获得具有非常低的自放电倾向的锂二次电池，即电解质分解得到高度控制的锂二次电池。

    Lithium secondary battery
    5.
    发明授权
    Lithium secondary battery 有权
    锂二次电池

    公开(公告)号：US06210836B1

    公开(公告)日：2001-04-03

    申请号：US09288318

    申请日：1999-04-08

    申请人： Kazunori Takada ,  Kazuya Iwamoto ,  Shigeo Kondo

    发明人： Kazunori Takada ,  Kazuya Iwamoto ,  Shigeo Kondo

    IPC分类号： H01M452

    CPC分类号： H01M4/581 ,  H01M4/485 ,  H01M4/52 ,  H01M4/5815 ,  H01M10/0562 ,  H01M2300/0068

    摘要： A lithium ion conductive inorganic solid electrolyte is used as an electrolyte in a lithium secondary battery which uses a transition metal chalcogenide or a lithium• transition metal chalcogenide as an active material for negative electrode. There is provided a lithium secondary battery improved in reversibility and in charge and discharge cycle characteristics as compared with lithium secondary batteries which use a liquid electrolyte or a molten salt electrolyte as the electrolyte.

    摘要翻译： 在使用过渡金属硫族化物或锂的锂二次电池中，使用锂离子传导性无机固体电解质作为电解质。 过渡金属硫族化物作为负极活性材料。 与使用液体电解质或熔融盐电解质作为电解质的锂二次电池相比，提供了可逆性和充放电循环特性提高的锂二次电池。

    Molded solid electrolyte, molded electrode and electrochemical element
    6.
    发明授权
    Molded solid electrolyte, molded electrode and electrochemical element 有权
    模制固体电解质，模制电极和电化学元素

    公开(公告)号：US06368746B1

    公开(公告)日：2002-04-09

    申请号：US09555888

    申请日：2000-06-08

    申请人： Kazunori Takada ,  Kazuya Iwamoto ,  Shigeo Kondo ,  Yasumasa Takeuchi ,  Naoshi Yasuda ,  Fusazumi Masaka

    发明人： Kazunori Takada ,  Kazuya Iwamoto ,  Shigeo Kondo ,  Yasumasa Takeuchi ,  Naoshi Yasuda ,  Fusazumi Masaka

    IPC分类号： H01M1036

    CPC分类号： H01M10/052 ,  H01M4/13 ,  H01M4/621 ,  H01M6/181 ,  H01M10/0562

    摘要： A molded solid electrolyte, a molded electrode and an electrochemical device which contain a polymer composition consisting of 50 to 100 wt % of 1,2-polybutadiene having a 1,2-vinyl content of 70% or more and a crystallinity of 5 to 50%, and 0 to 50 wt % of polar rubber. According to the present invention, it becomes possible to obtain a molded solid electrolyte provided with high ionic conductivity and high workability, or a molded electrode having high electrode activity, and it is also possible to obtain an electrochemical device showing excellent activating properties by using the molded solid electrolyte and the molded electrode.

    摘要翻译： 一种模塑固体电解质，模制电极和电化学装置，其含有由50-100重量％的1,2-乙烯基含量为70％以上且结晶度为5〜50的1,2-聚丁二烯组成的聚合物组合物 ％，0〜50重量％的极性橡胶。 根据本发明，可以获得具有高离子导电性和高加工性的成型固体电解质或具有高电极活性的模塑电极，并且还可以通过使用 模制固体电解质和模制电极。

    Solid-state lithium secondary battery
    8.
    发明授权
    Solid-state lithium secondary battery 失效
    固态锂二次电池

    公开(公告)号：US5677081A

    公开(公告)日：1997-10-14

    申请号：US752969

    申请日：1996-12-02

    申请人： Kazuya Iwamoto ,  Noboru Aotani ,  Kazunori Takada ,  Shigeo Kondo

    发明人： Kazuya Iwamoto ,  Noboru Aotani ,  Kazunori Takada ,  Shigeo Kondo

    IPC分类号： H01M6/18 ,  H01M10/36

    CPC分类号： H01M10/0562 ,  H01M6/18

    摘要： A solid-state lithium secondary battery having a high safety and being free from the formation and growth of lithium dendrites is disclosed. It comprises a cathode having as an active material at least one compound selected from the group consisting of oxides and sulfides of a transition metal, a lithium ion-conductive solid electrolyte of a glass comprising Li.sub.2 S, and an anode having as an active material a metal capable of forming an alloy with lithium, wherein at least one of the cathode active material and anode active material contains lithium.

    摘要翻译： 公开了一种具有高安全性且不含锂枝晶的形成和生长的固态锂二次电池。 它包括具有作为活性材料的至少一种选自过渡金属的氧化物和硫化物的化合物的阴极，包含Li 2 S的玻璃的锂离子传导性固体电解质和具有金属作为活性材料的阳极 能够与锂形成合金，其中至少一种正极活性物质和负极活性物质含有锂。