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公开(公告)号：US5817880A
公开(公告)日：1998-10-06
申请号：US818747
申请日：1997-03-14
申请人： Tomonori Iwasaki , Kazunori Tsushima , Takashi Furukawa , Takao Ishiwatari , Toru Tsuchiya , Mikako Nakamachi
发明人： Tomonori Iwasaki , Kazunori Tsushima , Takashi Furukawa , Takao Ishiwatari , Toru Tsuchiya , Mikako Nakamachi
IPC分类号： A01N37/10 , A01N53/00 , C07C45/72 , C07C49/707 , C07C69/013 , C07C69/65 , C07C69/743 , C07C49/597 , C07C35/06
CPC分类号： C07C69/743 , A01N37/10 , A01N53/00 , C07C45/72 , C07C49/707 , C07C69/013 , C07C69/65
摘要： There is provided an intermediate alcohol ester compound represented by the formula VII: ##STR1## wherein R.sub.1 is a methyl group or a hydrogen atom; R.sub.2 is a C.sub.2-4 alkyl group; substituted with two or more fluorine atoms.
摘要翻译： 提供由式VII表示的中间体醇酯化合物：其中R 1是甲基或氢原子; R2是C2-4烷基; 被两个或多个氟原子取代。
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2.发明授权Ester compound, agent for controlling noxious organisms containing the same as active ingredient, and production intermediate thereof 失效酯化合物，用于控制含有与活性成分相同的有害生物的试剂及其制备中间体
公开(公告)号：US5653990A
公开(公告)日：1997-08-05
申请号：US492980
申请日：1995-06-21
申请人： Tomonori Iwasaki , Kazunori Tsushima , Takashi Furukawa , Takao Ishiwatari , Toru Tsuchiya , Mikako Nakamachi
发明人： Tomonori Iwasaki , Kazunori Tsushima , Takashi Furukawa , Takao Ishiwatari , Toru Tsuchiya , Mikako Nakamachi
IPC分类号： A01N37/10 , A01N53/00 , C07C45/72 , C07C49/707 , C07C69/013 , C07C69/65 , C07C69/743 , C07C69/76 , A01N25/00 , C07C69/74
CPC分类号： C07C69/743 , A01N37/10 , A01N53/00 , C07C45/72 , C07C49/707 , C07C69/013 , C07C69/65
摘要： There is provided an ester compound represented by the formula I: ##STR1## wherein R.sub.1 is a methyl group or a hydrogen atom; R.sub.2 is a C.sub.1-6 haloalkyl group; and R.sub.3 is a pyrethroid acid residue, an agent for controlling noxious organisms containing the same as active ingredient and an intermediate for producing the same.
摘要翻译： 提供由式I表示的酯化合物：其中R 1是甲基或氢原子; R2是C1-6卤代烷基; R3是拟除虫菊酯酸残基，用于控制含有与活性成分相同的有害生物的试剂和用于制备它的中间体。
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公开(公告)号：US5607963A
公开(公告)日：1997-03-04
申请号：US456309
申请日：1995-06-01
IPC分类号： A01N53/00 , A01N53/04 , C07D207/44 , C07D207/452 , A01N43/36
CPC分类号： C07D207/452 , A01N53/00
摘要： Maleimide pesticides having enhanced efficacy represented by the formula (I), ##STR1## wherein X represents a halogen atom or a hydrogen atom, and R represents an alkyl group a cycloalkyl or haloalkyl group, a pesticidal composition containing the same as an active ingredient, and a process for producing the same.
摘要翻译： 具有由式（I）表示的功效增强的马来酰亚胺农药，其中X表示卤素原子或氢原子，R表示烷基，环烷基或卤代烷基，农药组合物含有与 活性成分及其制造方法。
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4.发明授权Ester compound and a pesticidal agent containing the same as an active ingredient 失效酯化合物和含有与活性成分相同的杀虫剂
公开(公告)号：US5852048A
公开(公告)日：1998-12-22
申请号：US609624
申请日：1996-03-01
申请人： Takashi Furukawa , Kazunori Tsushima , Tomonori Iwasaki , Hirosi Kisida , Mikako Nakamachi , Yoji Takada
发明人： Takashi Furukawa , Kazunori Tsushima , Tomonori Iwasaki , Hirosi Kisida , Mikako Nakamachi , Yoji Takada
IPC分类号： A01N53/00 , C07D249/12 , A61K31/415
CPC分类号： A01N53/00 , C07D249/12
摘要： There is disclosed an ester compound of the formula (I), ##STR1## wherein R.sup.1 represents a methyl group or a hydrogen atom, R.sup.2 represents a proparqyl group or an allyl group, and R.sup.3 represents a (C.sub.1 -C.sub.5)alkyl group, a (C.sub.1 -C.sub.5)haloalkyl group or a (C.sub.3 -C.sub.5)cycloalkyl group and R.sup.4 represents a halogen atom or a hydrogen atom, and a pesticide containing the same as an active ingredient.
摘要翻译： 公开了式（I）的酯化合物，其中R 1表示甲基或氢原子，R 2表示丙酰基或烯丙基，R 3表示（C 1 -C 5）烷基 （C1-C5）卤代烷基或（C3-C5）环烷基，R4表示卤素原子或氢原子，和含有该活性成分的农药。
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5.发明授权Ester compound, active agent for controlling noxious insect pests containing the same as active ingredient, intermediate for production of the ester compound, and process for producing the intermediate 失效酯化合物，用于控制含有与活性成分相同的有害害虫的活性剂，用于制备酯化合物的中间体，以及制备中间体的方法
公开(公告)号：US5550258A
公开(公告)日：1996-08-27
申请号：US294934
申请日：1994-08-23
申请人： Tomonori Iwasaki , Masaya Suzuki , Takashi Furukawa , Kazunori Tsushima , Takao Ishiwatari , Toru Tsuchiya
发明人： Tomonori Iwasaki , Masaya Suzuki , Takashi Furukawa , Kazunori Tsushima , Takao Ishiwatari , Toru Tsuchiya
IPC分类号： C07D333/32 , A01N37/10 , A01N53/00 , A01N53/02 , C07B61/00 , C07C29/32 , C07C35/06 , C07C35/48 , C07C43/188 , C07C69/013 , C07C69/74 , C07C69/743 , C07C69/747 , C07C69/757 , C07D303/48 , C07D307/58 , C07F7/18 , C07D209/82
CPC分类号： C07C35/48 , A01N37/10 , A01N53/00 , C07C35/06 , C07C69/013 , C07C69/74 , C07C69/743 , C07F7/1856 , Y02P20/55
摘要： The present invention provides an ester compound represented by a formula I: ##STR1## wherein R.sub.1 denotes a hydrogen atom or a methyl group; R.sub.2 represents a 1-methyl-2-propenyl group, a 1-methyl-2-propynyl group, a 3,3-dihalogeno-1-methyl-2-propenyl group, or a C.sub.1 -C.sub.1 6 alkyl group which may be substituted with at least one halogen atom; and R.sub.3 represents an acid residue of pyrethroids.The invention also relates to an active agent for controlling noxious insect pests containing the ester compound as an active ingredient, an intermediate for production of the ester compound and a process for producing the intermediate. The ester compound represented by the formula I has good activities for controlling noxious insect pests.
摘要翻译： 本发明提供由式I表示的酯化合物：其中R 1表示氢原子或甲基; R2代表1-甲基-2-丙烯基，1-甲基-2-丙炔基，3,3-二卤代-1-甲基-2-丙烯基或可被C 1-6烷基取代的C 1 -C 16烷基 至少一个卤素原子; R3表示拟除虫菊酯的酸残基。 本发明还涉及用于控制含有酯化合物作为活性成分的有害害虫的活性剂，用于生产酯化合物的中间体和中间体的制备方法。 由式I表示的酯化合物具有良好的防治有害害虫的活性。
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6.发明授权Ester compound, active agent for controlling noxious insect pests containing the same as active ingredient, intermediate for production of the ester compound and process for producing the intermediate 失效酯化合物，用于控制含有与活性成分相同的有害害虫的活性剂，用于制备酯化合物的中间体和用于制备中间体的方法
公开(公告)号：US5672779A
公开(公告)日：1997-09-30
申请号：US641431
申请日：1996-05-01
申请人： Tomonori Iwasaki , Masaya Suzuki , Takashi Furukawa , Kazunori Tsushima , Takao Ishiwatari , Toru Tsuchiya
发明人： Tomonori Iwasaki , Masaya Suzuki , Takashi Furukawa , Kazunori Tsushima , Takao Ishiwatari , Toru Tsuchiya
IPC分类号： C07D333/32 , A01N37/10 , A01N53/00 , A01N53/02 , C07B61/00 , C07C29/32 , C07C35/06 , C07C35/48 , C07C43/188 , C07C69/013 , C07C69/74 , C07C69/743 , C07C69/747 , C07C69/757 , C07D303/48 , C07D307/58 , C07F7/18 , C07C13/12
CPC分类号： C07C35/48 , A01N37/10 , A01N53/00 , C07C35/06 , C07C69/013 , C07C69/74 , C07C69/743 , C07F7/1856 , Y02P20/55
摘要： The present invention provides a compound represented by the formula: ##STR1## wherein R.sub.1 denotes a hydrogen atom or a methyl group; R.sub.2 represents a 1-methyl-2-propenyl group, a 1-methyl-2-propynyl group, a 3,3-dihalogeno-1-methyl-2-propenyl group or a C.sub.1 -C.sub.6 alkyl group which may be substituted with at least one halogen atom; and A' represents a hydrogen atom or a protecting group for a hydroxyl group. The compound is useful in the preparation of esters which can be used to control insect pests.
摘要翻译： 本发明提供由下式表示的化合物：其中R 1表示氢原子或甲基; R2代表1-甲基-2-丙烯基，1-甲基-2-丙炔基，3,3-二卤代-1-甲基-2-丙烯基或可以被取代的C 1 -C 6烷基 至少一个卤素原子; A'表示氢原子或羟基的保护基。 该化合物可用于制备可用于防治害虫的酯类。
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公开(公告)号：US5554649A
公开(公告)日：1996-09-10
申请号：US359013
申请日：1994-12-19
CPC分类号： A01N53/00
摘要： A controlling agent for fabric pest insects characterized by containing, as an active ingredient, a carboxylic acid ester represented by the formula (I): ##STR1## wherein R represents an allyl or propargyl group, Y represents a hydrogen atom or a methyl group, and when Y is a hydrogen atom, X represents an isobutenyl, 2,2-difluorovinyl or 2-chloro-2-fluorovinyl group, and when Y is a methyl group, X represents a methyl group.
摘要翻译： 特征在于含有式（I）表示的羧酸酯作为活性成分的织物害虫控制剂：其中R表示烯丙基或炔丙基，Y表示氢原子或 甲基，当Y为氢原子时，X表示异丁烯基，2,2-二氟乙烯基或2-氯-2-氟乙烯基，Y为甲基时，X表示甲基。
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公开(公告)号：US5550260A
公开(公告)日：1996-08-27
申请号：US253065
申请日：1994-06-02
IPC分类号： C07B37/00 , C07C29/32 , C07C35/06 , C07C41/30 , C07C43/188 , C07D307/20 , C07D309/12 , C07F7/18 , C07D307/02 , C07F7/08
CPC分类号： C07F7/1892 , C07B37/00 , C07C29/32 , C07C35/06 , C07B2200/07 , C07C2101/10 , C07C2101/16 , Y02P20/55
摘要： A process for the production of a cyclopentenol compound represented by the formula I: ##STR1## wherein R.sub.1 represents a 2-propenyl group or a 2-propynyl group from a cyclopentenolone compound represented by the formula II: ##STR2## by protecting the hydroxyl group of the compound II, reacting the protected compound II with a reagent system obtained from TiCl.sub.4, Zn and CH.sub.2 Br.sub.2 or CH.sub.2 I.sub.2 and removing the protecting group from the resulting reaction product.
摘要翻译： 制备由式I表示的环戊烯醇化合物的方法：其中R 1表示由式II表示的环戊烯醇酮化合物的2-丙烯基或2-丙炔基：（II） ）保护化合物II的羟基，使保护的化合物II与由TiCl 4，Zn和CH 2 B 2或CH 2 I 2获得的试剂体系反应，并从所得反应产物中除去保护基团。
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9.发明授权Ester compounds pesticidal compositions containing the same and itermediates for synthesis thereof 失效酯化合物含有相同的农药组合物和用于合成的杀虫剂组合物
公开(公告)号：US5925676A
公开(公告)日：1999-07-20
申请号：US927821
申请日：1997-09-11
IPC分类号： C07C69/74 , A01N53/00 , A01N53/02 , C07C35/06 , C07C35/48 , C07C69/013 , C07C69/612 , C07C69/743
CPC分类号： C07C35/06 , A01N53/00 , C07C35/48 , C07C69/013 , C07C2101/10
摘要： An ester compound represented by the formula ##STR1## wherein R.sub.1 and R.sub.2 may be the same or different and each represent a C.sub.1 -C.sub.6 alkyl group, or other specified groups, which may be optionally substituted with one or more halogen atoms; and R.sub.3 represents a pyrethroid acid residue (a group resulting from elimination of the carboxyl group from pyrethroid acid), and a pesticidal composition containing the ester compound as an active ingredient.
摘要翻译： 由下式表示的酯化合物其中R 1和R 2可以相同或不同，并且各自表示C 1 -C 6烷基或其它指定基团，其可任选被一个或多个卤素原子取代; R3表示除虫菊酯酸残基（由除虫菊酯酸除去羧基而得到的基团），以及含有酯化合物作为有效成分的杀虫剂组合物。
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公开(公告)号：US07423062B2
公开(公告)日：2008-09-09
申请号：US10738079
申请日：2003-12-17
申请人： Kazunori Tsushima
发明人： Kazunori Tsushima
IPC分类号： A01N53/06
CPC分类号： A01N53/00 , Y10T442/2525 , A01N43/32 , A01N25/34 , A01N2300/00
摘要： An insecticidal composition which comprises an ester compound given by formula (1): [wherein R represents a methyl or methoxymethyl group] and 2,4,6-triisopropyl-1,3,5-trioxane as active ingredients, wherein the weight ratio of the ester compound to 2,4,6-triisopropyl-1,3,5-trioxane is 1:4000 to 1:4, is useful for controlling insects, especially insects which are harmful to fabric.
摘要翻译： 一种杀虫组合物，其包含由式（1）给出的酯化合物：[其中R表示甲基或甲氧基甲基]和2,4,6-三异丙基-1,3,5-三恶烷作为活性成分，其中重量比 该酯化合物与2,4,6-三异丙基-1,3,5-三恶烷的比例为1:4000至1:4，可用于防治昆虫，特别是对织物有害的昆虫。
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