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    Process for preparing polyolefins
    1.
    发明授权
    Process for preparing polyolefins 失效
    聚烯烃的制备方法

    公开(公告)号：US4537938A

    公开(公告)日：1985-08-27

    申请号：US591912

    申请日：1984-03-21

    申请人： Kazuo Matsuura ,  Yutaka Shikatani ,  Hirofumi Kamiishi ,  Nobuyuki Kuroda ,  Mituji Miyoshi

    发明人： Kazuo Matsuura ,  Yutaka Shikatani ,  Hirofumi Kamiishi ,  Nobuyuki Kuroda ,  Mituji Miyoshi

    IPC分类号： C08F4/00 ,  C08F4/08 ,  C08F4/10 ,  C08F4/12 ,  C08F4/16 ,  C08F4/20 ,  C08F4/26 ,  C08F4/60 ,  C08F4/632 ,  C08F4/64 ,  C08F10/00 ,  C08F4/44 ,  C01B15/14

    CPC分类号： C08F10/00 ,  Y10S526/907

    摘要： Provided is an olefin-polymerization catalyst comprising the combination of the following components [I] and [II]:[I] a solid component obtained by intercontacting and reacting the following components (1) through (4):(1) a compound obtained by treating an oxide of an element of Groups II-IV in the Periodic Table with a compound represented by the general formula R.sup.1.sub.m Si(OR.sup.2).sub.n.sup.X.sub.4-m-n wherein R.sup.1 and R.sup.2 are each a hydrocarbon radical having 1 to 24 carbon atoms, a hydrocarbon radical containing oxygen, sulfur or nitrogen, or hydrogen, X is a halogen atom, m is 0.ltoreq.m

    摘要翻译： 本发明提供包含以下组分[I]和[II]的组合的烯烃聚合催化剂：[I]通过使下述组分（1）至（4）中间接触和反应获得的固体组分：（1）获得的化合物 通过用通式R1mSi（OR2）nX4-mn表示的化合物处理元素周期表中II-Ⅳ族元素的氧化物，其中R 1和R 2各自为具有1至24个碳原子的烃基，烃基 含有氧，硫或氮或氢，X是卤素原子，m是0 表示的化合物，其中R 4，R 5和R 6各自为具有1至24个碳原子的烃基，烷氧基，氢或卤素原子，R 7为具有1 至24个碳原子，n为1

    Process for preparing polyolefins
    3.
    发明授权
    Process for preparing polyolefins 失效
    聚烯烃的制备方法

    公开(公告)号：US4451688A

    公开(公告)日：1984-05-29

    申请号：US413829

    申请日：1982-09-01

    申请人： Nobuyuki Kuroda ,  Toru Nakamura ,  Yutaka Shikatani ,  Kazuo Matsuura ,  Mituji Miyoshi

    发明人： Nobuyuki Kuroda ,  Toru Nakamura ,  Yutaka Shikatani ,  Kazuo Matsuura ,  Mituji Miyoshi

    IPC分类号： C08F10/00 ,  C07C3/21 ,  C07C3/10

    CPC分类号： C08F10/00

    摘要： Olefins are polymerized in the presence of a catalyst which comprises the combination of:[I] a solid substance obtained by the reaction of at least the following two components:(i) a magnesium compound represented by the general formula R.sup.1.sub.m (OR.sup.2).sub.n MgX.sub.2-m-n wherein R.sup.1 and R.sup.2 are each a hydrocarbon radical having 1 to 24 carbon atoms, X is a halogen atom, m is 0.ltoreq.m.ltoreq.2 and n is 0.ltoreq.n.ltoreq.2, provided 0.ltoreq.m+n.ltoreq.2, and(ii) a titanium compound and/or a vanadium compound;[II] a silicon compound represented by general formula R.sup.1 mSi(OR.sup.2).sub.n X.sub.4-m-n wherein R.sup.1 and R.sup.2 are each hydrocarbon radical having 1 to 24 carbon atoms, X is a halogen atom, m is 0.ltoreq.m

    摘要翻译： 烯烃在催化剂的存在下聚合，该催化剂包含以下组合的组合：[I]通过至少以下两种组分的反应获得的固体物质：（i）由通式R 1 m（OR 2）表示的镁化合物nMgX2- mn其中R 1和R 2各自是具有1至24个碳原子的烃基，X是卤素原子，m是0≤n≤2且n是0

    Process for preparing polyolefins
    5.
    发明授权
    Process for preparing polyolefins 失效
    聚烯烃的制备方法

    公开(公告)号：US4093789A

    公开(公告)日：1978-06-06

    申请号：US705607

    申请日：1976-07-15

    申请人： Nobuyuki Kuroda ,  Toru Nakamura ,  Takeichi Shiraishi ,  Kazuo Matsuura ,  Mituji Miyoshi

    发明人： Nobuyuki Kuroda ,  Toru Nakamura ,  Takeichi Shiraishi ,  Kazuo Matsuura ,  Mituji Miyoshi

    IPC分类号： C08F4/00 ,  C08F4/02 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F10/02

    CPC分类号： C08F10/00 ,  C08F4/022 ,  Y10S526/903 ,  Y10S526/906

    摘要： According to the present invention, there is provided a process for preparing polyolefins by polymerizing or copolymerizing olefins in the presence of a catalyst consisting of a solid component and an organometallic compound component, characterized in that said solid component is obtained by copulverizing(1) a magnesium halide and/or a manganese halide,(2) an aromatic hydrocarbon,(3) a tetravalent titanium compound, and(4) a trivalent titanium compoundAnd in that said organometallic compound component is a mixture of(5) a trialkylaluminum and(6) a compound represented by the general formula AlR.sub.n X.sub.3-n wherein R is alkyl having 1 to 10 carbon atoms and may be the same or different, X is halogen and O

    摘要翻译： 根据本发明，提供一种通过在由固体成分和有机金属化合物成分组成的催化剂存在下聚合或共聚烯烃制备聚烯烃的方法，其特征在于所述固体组分通过共混（1）A （2）芳族碳氢化合物，（3）四价钛化合物，和（4）多价钛化合物，以及所述有机元素化合物组分是（5）三烯丙基铝和（ 6）由通式AlRnX 3-n表示的化合物，其中R是具有1至10个碳原子的烷基并且可以相同或不同，X是卤素且O

    Process for preparing polyolefins
    7.
    发明授权
    Process for preparing polyolefins 失效
    聚烯烃的制备方法

    公开(公告)号：US4410670A

    公开(公告)日：1983-10-18

    申请号：US45961

    申请日：1979-06-06

    申请人： Yoshio Tajima ,  Kazuo Matsuura ,  Nobuyuki Kuroda ,  Mituji Miyoshi

    发明人： Yoshio Tajima ,  Kazuo Matsuura ,  Nobuyuki Kuroda ,  Mituji Miyoshi

    IPC分类号： C08F10/00 ,  C08F4/66

    CPC分类号： C08F10/00

    摘要： This invention provides a process for preparing polyolefins using a new catalyst. According to this invention, .alpha.-olefins can be polymerized or copolymerized to have good stereoregularity and at a high activity by the use of such new catalyst. The new catalyst used in this invention consists of [A] a solid component obtained by contacting (1) a magnesium oxide, (2) an aluminum trihalide, (3) a hydroxy compound represented by the general formula ROH wherein R is an organic radical having 1 to 20 carbon atoms and (4) a titanium halide and/or an addition product of a titanium halide and an aromatic carboxylic acid ester, and [B] an organometallic compound and/or an addition product of an organometallic compound and an aromatic carboxylic acid ester; or it consists of the solid component of the above [A], the organometallic compound and/or the addition product of an organometallic compound and an aromatic carboxylic acid ester of the above [B], and [C] an aromatic carboxylic acid ester. The said catalyst is prepared, in one of the most preferred embodiments thereof, by using the solid component of the above [A] which is obtained by first co-pulverizing the compounds of the above (1),(2) and (3), then washing the co-pulverized product with an aromatic compound, separating the liquid phase to give a solid substance (a) and contacting the latter with the compound and/or the addition product of the above (4).

    摘要翻译： 本发明提供使用新催化剂制备聚烯烃的方法。 根据本发明，通过使用这种新的催化剂，α-烯烃可以聚合或共聚以具有良好的立构规整性和高活性。 本发明中使用的新型催化剂由[A]一种固体组分组成，该固体组分通过使（1）氧化镁，（2）三卤化铝，（3）由通式ROH表示的羟基化合物，其中R是有机基团 具有1至20个碳原子和（4）卤化钛和/或卤化钛和芳族羧酸酯的加成产物，和[B]有机金属化合物和/或有机金属化合物和芳族化合物的加成产物 羧酸酯; 或者由上述[A]的固体组分，有机金属化合物和/或上述[B]的有机金属化合物和芳族羧酸酯的加成产物和[C]芳族羧酸酯组成。 所述催化剂在其最优选的实施方案之一中，通过使用上述[A]的固体成分，其是通过首先共混上述（1），（2）和（3）的化合物而获得的， ，然后用芳族化合物洗涤共粉碎产物，分离液相，得到固体物质（a），并使其与上述（4）的化合物和/或加成产物接触。

    Process for the production of polyolefins
    8.
    发明授权
    Process for the production of polyolefins 失效
    生产聚烯烃的方法

    公开(公告)号：US4209602A

    公开(公告)日：1980-06-24

    申请号：US887009

    申请日：1978-03-16

    申请人： Nobuyuki Kuroda ,  Takeichi Shiraishi ,  Akio Itoh ,  Kazuo Matsuura ,  Mituji Miyoshi

    发明人： Nobuyuki Kuroda ,  Takeichi Shiraishi ,  Akio Itoh ,  Kazuo Matsuura ,  Mituji Miyoshi

    IPC分类号： C08F4/02 ,  C08F10/00 ,  C08F10/02

    CPC分类号： C08F10/00 ,  C08F4/022 ,  Y10S526/906

    摘要： The present invention discloses improved catalysts for polymerizing or copolymerizing olefins and a process for the production of polyolefins comprising a polymerization or copolymerization of olefins by the use of said catalysts. According to the invention there is provided a process for the production of polyolefins by polymerizing or copolymerizing olefins using as the catalyst a solid component containing a titanium compound and/or a vanadium compound and an organometallic compound, said solid component comprising a substance obtained by co-pulverizing (1) a metal halide selected from the group consisting of magnesium halides and manganese halides, (2) a compound represented by the general formula Mg(OR).sub.n X.sub.2-n in which n is a number of the range 0

    摘要翻译： 本发明公开了用于聚合或共聚烯烃的改进的催化剂和用于生产聚烯烃的方法，其包括通过使用所述催化剂聚合或共聚烯烃。 根据本发明，提供了一种通过使用作为催化剂使含有钛化合物和/或钒化合物和有机金属化合物的固体组分作为催化剂聚合或共聚烯烃的方法，所述固体组分包含通过共聚物获得的物质 粉碎（1）选自卤化镁和卤化锰的金属卤化物，（2）由通式Mg（OR）nX2-n表示的化合物，其中n是0

    Continuous process for the preparation of polyolefins having widely distributed molecular weights
    10.
    发明授权
    Continuous process for the preparation of polyolefins having widely distributed molecular weights 失效
    用于制备具有广泛分布分子量的聚烯烃的连续方法

    公开(公告)号：US4414369A

    公开(公告)日：1983-11-08

    申请号：US138104

    申请日：1980-04-07

    申请人： Nobuyuki Kuroda ,  Tatsuo Horie ,  Kazuo Matsuura ,  Kunimichi Kubo ,  Mituji Miyoshi

    发明人： Nobuyuki Kuroda ,  Tatsuo Horie ,  Kazuo Matsuura ,  Kunimichi Kubo ,  Mituji Miyoshi

    IPC分类号： C08F10/00 ,  C08F2/14 ,  C08F4/66

    CPC分类号： C08F10/00 ,  Y10S526/905

    摘要： Polyolefins having a wide distribution of molecular weights are prepared in a plural stage process, by initially polymerizing the olefins in the presence of a solvent, hydrogen and a highly active Ziegler type catalyst under pressure, and beneath a gas phase containing an inert gas, to form in the first stage a polymer having a relatively high molecular weight. The polymerization reaction mixture from the first stage is continuously flowed to a second stage reactor. The second stage reactor is maintained at a relatively lower pressure, such that the flow is driven by the higher pressure in the first stage. The second stage is agitated and the polymerization reaction mixture is maintained beneath an atmosphere containing olefins and hydrogen gas. Polymers of relatively low molecular weight are formed in the second stage. The product continuously removed from the second stage contains a polymer having a wide distribution of molecular weight.

    摘要翻译： 通过在溶剂，氢气和高活性齐格勒型催化剂的存在下，在压力下，在含有惰性气体的气相之下，在烯烃存在下，首先使烯烃聚合，在多级方法中制备分子量分布广泛的聚烯烃， 在第一阶段形成具有相对较高分子量的聚合物。 将来自第一阶段的聚合反应混合物连续流入第二级反应器。 第二级反应器保持在相对较低的压力下，使得流在第一级中被较高的压力驱动。 搅拌第二阶段，聚合反应混合物保持在含有烯烃和氢气的气氛下。 在第二阶段形成相对低分子量的聚合物。 从第二阶段连续除去的产物含有分子量分布广泛的聚合物。