摘要:
An electron-withdrawing group-containing metal compound (I) of an atom of the Group III to the Group XII or lanthanide series of the Periodic Table of the Elements, a catalyst component for addition polymerization composed of the compound (I), a catalyst for addition polymerization obtained by contacting the compound (I) with a specific compound (II) of metal of the Group III to the Group XIII or lanthanide series and optionally an organoaluminum compound (III), and a process for producing an addition polymer using the catalyst.
摘要:
A catalyst component for addition polymerization containing (A) a compound containing an atom of the Group II to the Group XII or Lanthanide series in which the lowest energy level of unoccupied molecular orbital having the valence p-type atomic orbital of the atom of the Group II to the Group XII or Lanthanide series as a main component, wherein the coefficient represented by a linear combination, is 0.4 or more) is calculated to be 0.008 atomic unit (Hartree) or less by the calculation of density functional method (B3LYP/3-21G level), a catalyst for addition polymerization containing the same, and a process for producing an addition polymer with the catalyst.
摘要:
A modified particles obtained by contacting particles(a) with a metal compound(b) selected from the group consisting of compounds of the Group VI, VII, XIV metal elements and compounds of the lanthanide series, and contacting the particles with a compound(c) having a functional group containing active hydrogen or a non-proton donative Lewis basic functional group and an electron-withdrawing group; a carrier composed of the modified particles; a catalyst component for olefin polymerization composed of said modified particles; a catalyst for olefin polymerization obtained by contacting the modified particles(A) and a transition metal compound(B), or further an organometallic compound(C); and a process for producing an olefin polymer with the catalyst.
摘要:
An electron-withdrawing group-containing metal compound (I) of an atom of the Group III to the Group XII or lanthanide series of the Periodic Table of the Elements, a catalyst component for addition polymerization composed of the compound (I), a catalyst for addition polymerization obtained by contacting the compound (I) with a specific compound (II) of metal of the Group III to the Group XIII or lanthanide series and optionally an organoaluminum compound (III), and a process for producing an addition polymer using the catalyst.
摘要:
A modified particle obtained by a process containing contacting a Bi compound, a compound having an electron-withdrawing group and an active hydrogen and particle; and a catalyst component for addition polymerization containing the modified particle; a catalyst for addition polymerization prepared by a process containing contacting the modified particle (A) and a transition metal compound of Groups 3 to 11 or lantanide series (B); and a catalyst for addition polymerization prepared by a process containing contacting the modified particle (A) and a transition metal compound of Groups 3 to 11 or lantanide series (B) and an orbanoaluminum compound (C); and a process for producing an addition polymer with the catalyst.
摘要:
A transition metal compound represented by the formula (1-1) or the formula (1-2) (M is a transition metal atom) and a process for producing a catalyst for olefin polymerization comprising a step of bringing the transition metal compound into contact with a co-catalytic component for activation.
摘要:
There are provided (1) a process for producing a contact product, which comprises the step of contacting at least a phthalocyanine complex, a porphyrin complex, or their combination with a surfactant; (2) a catalyst component for addition polymerization, which comprises said contact product; (3) a process for producing a catalyst for addition polymerization, which comprises the step of contacting said catalyst component, a compound of a metal atom of Groups 3 to 12 or the lanthanide series, and an optional organoaluminum compound with one another; and (4) a process for producing an addition polymer, which comprises the step of polymerizing an addition polymerizable monomer in the presence of said catalyst.
摘要:
A production process of an olefin polymerization catalyst, comprising steps of (1) contacting a defined zinc compound, Zn(L1)2, with a defined halogenated alcohol, thereby forming a zinc atom-containing compound, and (2) contacting the zinc atom-containing compound with a defined transition metal compound and an optional organoaluminum compound; and a production process of an olefin polymer using such an olefin polymerization catalyst.
摘要:
A contact product obtained by a process comprising the step of contacting a compound (a) represented by the formula, M1L1r, a compound (b) represented by the formula, R1s-1T1H, a compound (c) represented by the formula, R2t-2T2H2, and a nonionic surfactant (d) having no active hydrogen; a catalyst component for addition polymerization comprising said contact product; a catalyst for addition polymerization obtained by a process comprising the step of contacting said catalyst component with a compound of a metal selected from the group consisting of metals of the Groups 3 to 12 and Lanthanide Series of the Periodic Table, and optionally an organoaluminum compound; and a process for producing an addition polymer comprising the step of polymerizing an addition polymerizable monomer in the presence of said catalyst.
摘要:
There are provided (1) a process for producing a contact product, which comprises the step of contacting at least a phthalocyanine complex, a porphyrin complex, or their combination with a surfactant; (2) a catalyst component for addition polymerization, which comprises said contact product; (3) a process for producing a catalyst for addition polymerization, which comprises the step of contacting said catalyst component, a compound of a metal atom of Groups 3 to 12 or the lanthanide series, and an optional organoaluminum compound with one another; and (4) a process for producing an addition polymer, which comprises the step of polymerizing an addition polymerizable monomer in the presence of said catalyst.