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    Condensed polycyclic aromatic compound, aromatic polymer, and method for synthesizing aromatic compound
    3.
    发明授权
    Condensed polycyclic aromatic compound, aromatic polymer, and method for synthesizing aromatic compound 有权
    缩合多环芳香族化合物，芳香族聚合物，芳香族化合物的合成方法

    公开(公告)号：US08829202B2

    公开(公告)日：2014-09-09

    申请号：US14237103

    申请日：2012-08-03

    申请人： Yoshinori Ikeda ,  Azusa Kohno ,  Takashi Shiro ,  Kazuo Takimiya

    发明人： Yoshinori Ikeda ,  Azusa Kohno ,  Takashi Shiro ,  Kazuo Takimiya

    IPC分类号： C07D495/14 ,  C07D495/18 ,  C07D495/04 ,  C07F7/08

    CPC分类号： C07D495/04 ,  C07D495/18 ,  C07F7/0812 ,  H01L51/0036 ,  H01L51/0074 ,  H01L51/0094 ,  H01L51/0558

    摘要： Provided is a condensed polycyclic aromatic compound that can be used as a precursor for synthesizing a condensed polycyclic aromatic compound having relatively high solubility. Also provided is a method for synthesizing and using such a novel condensed polycyclic aromatic compound. The condensed polycyclic aromatic compound is represented by formula (II): (II) (where X1 and X2 are each independently selected from the group consisting of a hydrogen atom, halogen atom, alkyl group, and the like, but at least one of X1 and X2 is a halogen atom; B is a condensed ring having at least one benzene ring moiety; each Y is independently selected from chalcogens; and A1 through A4 are each independently selected from the group consisting of hydrogen atoms, halogen atoms, alkyl groups, and the like and two adjacent atoms or groups can bond together to form an aromatic group).

    摘要翻译： 提供可以用作合成具有较高溶解度的缩合多环芳族化合物的前体的缩合多环芳族化合物。 还提供了合成和使用这种新型缩合多环芳族化合物的方法。 缩合多环芳香族化合物由式（II）表示：（II）（其中X1和X2各自独立地选自氢原子，卤素原子，烷基等，但是X1中的至少一个 X2是卤素原子; B是具有至少一个苯环部分的稠环;每个Y独立地选自硫属元素;而A1至A4各自独立地选自氢原子，卤素原子，烷基， 等等和两个相邻的原子或基团可以键合在一起形成芳族基团）。

    Novel Heterocyclic Compound And Use Thereof
    5.
    发明申请
    Novel Heterocyclic Compound And Use Thereof 有权
    新型杂环化合物及其用途

    公开(公告)号：US20110204295A1

    公开(公告)日：2011-08-25

    申请号：US13126771

    申请日：2009-11-20

    申请人： Hirokazu Kuwabara ,  Masaaki Ikeda ,  Kazuo Takimiya

    发明人： Hirokazu Kuwabara ,  Masaaki Ikeda ,  Kazuo Takimiya

    IPC分类号： C09K19/34 ,  H01B1/12 ,  C07D495/14 ,  C07D209/86

    CPC分类号： C09K19/3491 ,  C07D495/14 ,  C07D517/14 ,  C09B57/00 ,  C09B57/008 ,  C09K11/06 ,  C09K19/40 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1092 ,  C09K2211/1096 ,  G02F1/133634 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/0541 ,  H01L51/0545 ,  H01L51/5048 ,  H05B33/14 ,  Y02E10/549

    摘要： Disclosed are a heterocyclic compound characterized by being represented by formula (1), and a composition of the compound. Also disclosed is an organic electronic device using the compound. (In formula (1), X1, X2 and X3 each independently represents a sulfur atom or a selenium atom; and R1-R6 each independently represents an aromatic hydrocarbon group, an aliphatic hydrocarbon group, a halogen atom, a hydroxyl group, an alkoxyl group, a mercapto group, an alkylthio group, a boronic acid group, a nitro group, a substituted amino group, an amide group, an acyl group, a carboxyl group, an acyloxy group, a cyano group, a sulfo group, a sulfamoyl group, an alkylsulfamoyl group, a carbamoyl group, an alkylcarbamoyl group or a hydrogen atom, provided that all the R1-R6 are not hydrogen atoms at the same time.) The compound represented by formula (1) is suitable for use in an organic electronic device such as an organic EL element, an organic transistor element and a liquid crystal element.

    摘要翻译： 公开了以式（1）表示的杂环化合物和化合物的组成。 还公开了使用该化合物的有机电子器件。 （式（1）中，X1，X2和X3各自独立地表示硫原子或硒原子; R1-R6分别独立地表示芳香族烃基，脂肪族烃基，卤素原子，羟基，烷氧基 基团，巯基，烷硫基，硼酸基，硝基，取代氨基，酰胺基，酰基，羧基，酰氧基，氰基，磺基，氨磺酰基 基团，烷基氨磺酰基，氨基甲酰基，烷基氨基甲酰基或氢原子，条件是所有的R 1 -R 6不同时为氢原子。）式（1）表示的化合物适用于有机 电子器件如有机EL元件，有机晶体管元件和液晶元件。

    METHOD FOR PRODUCING AROMATIC COMPOUND
    6.
    发明申请
    METHOD FOR PRODUCING AROMATIC COMPOUND 有权
    生产芳香化合物的方法

    公开(公告)号：US20100137617A1

    公开(公告)日：2010-06-03

    申请号：US12451537

    申请日：2008-05-13

    申请人： Hirokazu Kuwabara ,  Masaaki Ikeda ,  Kazuo Takimiya

    发明人： Hirokazu Kuwabara ,  Masaaki Ikeda ,  Kazuo Takimiya

    IPC分类号： C07D495/04 ,  C07D345/00

    CPC分类号： C07D495/04 ,  C07D495/22 ,  C07D517/04

    摘要： Disclosed is a method for producing an aromatic compound represented by the general formula (2) below, which is characterized in that a compound represented by the general formula (1) below is reacted with a sulfur compound (at least one member selected from the group consisting of sulfur, hydrogen sulfide, metal hydrosulfides and metal sulfides) or a selenium compound. (In the formula (1), R1 represents a hydrogen atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an ester group, an optionally substituted alkyl group having 1-18 carbon atoms or the like; R2 represents a halogen atom; R3 represents a hydrogen atom, C≡C—R1 or R2; and n represents an integer of 0-4. When n is not less than 2, R3's may be the same as or different from each other.) (In the formula (2), R1, R3 and n are as defined in the formula (1); and X represents a sulfur atom or a selenium atom.)

    摘要翻译： 公开了下述通式（2）表示的芳香族化合物的制造方法，其特征在于，将下述通式（1）表示的化合物与硫化合物（选自下述的至少一种 由硫，硫化氢，金属氢硫化物和金属硫化物组成）或硒化合物。 （式（1）中，R 1表示氢原子，卤素原子，羟基，氰基，硝基，酯基，可具有取代基的碳原子数为1〜18的烷基等; R 2 表示卤素原子; R3表示氢原子，C≡C-R1或R2; n表示0-4的整数，当n不小于2时，R 3可以相同或不同） （式（2）中，R 1，R 3，n如式（1）所定义，X表示硫原子或硒原子。

    Method for producing aromatic compound
    7.
    发明授权
    Method for producing aromatic compound 有权
    芳香族化合物的制备方法

    公开(公告)号：US09073938B2

    公开(公告)日：2015-07-07

    申请号：US12451537

    申请日：2008-05-13

    申请人： Hirokazu Kuwabara ,  Masaaki Ikeda ,  Kazuo Takimiya

    发明人： Hirokazu Kuwabara ,  Masaaki Ikeda ,  Kazuo Takimiya

    IPC分类号： C07D495/04 ,  C07D495/22 ,  C07D517/04

    CPC分类号： C07D495/04 ,  C07D495/22 ,  C07D517/04

    摘要： Disclosed is a method for producing an aromatic compound represented by the general formula (2) below, which is characterized in that a compound represented by the general formula (1) below is reacted with a sulfur compound (at least one member selected from the group consisting of sulfur, hydrogen sulfide, metal hydrosulfides and metal sulfides) or a selenium compound. (In the formula (1), R1 represents a hydrogen atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an ester group, an optionally substituted alkyl group having 1-18 carbon atoms or the like; R2 represents a halogen atom; R3 represents a hydrogen atom, C≡C—R1 or R2; and n represents an integer of 0-4. When n is not less than 2, R3's may be the same as or different from each other.) (In the formula (2), R1, R3 and n are as defined in the formula (1); and X represents a sulfur atom or a selenium atom.)

    摘要翻译： 公开了下述通式（2）表示的芳香族化合物的制造方法，其特征在于，将下述通式（1）表示的化合物与硫化合物（选自下述的至少一种 由硫，硫化氢，金属氢硫化物和金属硫化物组成）或硒化合物。 （式（1）中，R 1表示氢原子，卤素原子，羟基，氰基，硝基，酯基，可具有取代基的碳原子数为1〜18的烷基等; R 2 表示卤素原子; R3表示氢原子，C≡C-R1或R2; n表示0-4的整数，当n不小于2时，R 3可以相同或不同） （式（2）中，R 1，R 3，n如式（1）所定义，X表示硫原子或硒原子。

    Fused polycyclic aromatic compound, process for producing the same, and use thereof
    10.
    发明授权
    Fused polycyclic aromatic compound, process for producing the same, and use thereof 有权
    稠合多环芳香族化合物，其制造方法及其用途

    公开(公告)号：US08232546B2

    公开(公告)日：2012-07-31

    申请号：US12312083

    申请日：2007-10-22

    申请人： Kazuo Takimiya ,  Tatsuya Yamamoto

    发明人： Kazuo Takimiya ,  Tatsuya Yamamoto

    IPC分类号： H01L51/00 ,  C07D495/02 ,  C07D517/02

    CPC分类号： H01L51/0071 ,  C07C319/14 ,  C07C319/20 ,  C07C391/02 ,  C07D495/04 ,  C07D517/04 ,  H01L51/0074 ,  H01L51/0558 ,  Y10S428/917 ,  C07C321/28 ,  C07C323/22

    摘要： In one embodiment of the present invention, a novel fused polycyclic aromatic compound of the present invention is (a) a compound including a benzodichalcogenophenobenzodichalcogenophene (BXBX) skeleton further having an aromatic ring(s) located outside the BXBX skeleton, or (b) a compound including a BXBX skeleton in which a benzene ring is substituted with a heterocyclic ring. The compound can strengthen intermolecular interaction due to greater π electron orbits. This improves an electron field effect mobility of an organic semiconductor device that is manufactured by use of the compound as an organic semiconductor material. Further, since the number of fused rings included in the compound is small, the compound does not cause problems that generally occur in compounds having an extremely large number of fused rings, i.e., poor solubility in solvent and poor atmospheric stability due to high affinity to oxygen. As a result, the fused polycyclic aromatic compound of the present invention can be preferably used as an organic semiconductor material.

    摘要翻译： 在本发明的一个实施方案中，本发明的新型稠合多环芳香族化合物是（a）还含有位于BXBX骨架外侧的芳香环的苯并二硫代苯并苯并二硫代苯并（BXBX）骨架的化合物，或（b） 包括其中苯环被杂环取代的BXBX骨架的化合物。 该化合物可以增强分子间的相互作用， 电子轨道。 这提高了通过使用化合物作为有机半导体材料制造的有机半导体器件的电子场效应迁移率。 此外，由于化合物中包含的稠合环的数量少，所以化合物不会产生通常发生在具有极大数目的稠环的化合物中的问题，即在溶剂中的溶解性差和由于高亲和力而导致的差的大气稳定性 氧。 结果，本发明的稠合多环芳族化合物可以优选用作有机半导体材料。