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公开(公告)号:US20090198069A1
公开(公告)日:2009-08-06
申请号:US11909686
申请日:2006-03-24
申请人: Keisuke Umakoshi , Takashi Kojima , Seiji Akatsu , Masayoshi Onishi , Shoji Ishizaka , Noboru Kitamura
发明人: Keisuke Umakoshi , Takashi Kojima , Seiji Akatsu , Masayoshi Onishi , Shoji Ishizaka , Noboru Kitamura
IPC分类号: C07F15/00
CPC分类号: H01L51/0087 , C07D231/12 , C07F15/0093 , C09K11/06 , C09K2211/1044 , C09K2211/185 , C09K2211/188 , H01L51/009 , H01L51/0091 , H01L51/5012 , H05B33/14
摘要: An object of the present invention is to provide a novel metal complex. A metal complex having a composition of [(PtII)2(MI)4(L)8], where MI is H+, AgI, AuI or CuI, and L is a compound represented by the following chemical formula. A metal complex having a composition of [(PtII)2(MI)4(X)2(L)6], where MI is AgI, AuI or CuI, X is Cl−, Br− or I−, and L is a compound represented by the following chemical formula. In the formula, R1, R2 and R3 are independently a hydrogen atom, a chlorine atom, a bromine atom, an iodine atom, a hydroxyl group, a phenyl group, a trifluoromethylphenyl group, a pentafluorophenyl group, a naphthyl group, a methyl group, an ethyl group, an i-propyl group, a t-butyl group, a trifluoromethyl group, a hydroxymethyl group or a hydroxyethyl group. At least one of R1, R2 and R3 in the formula is not a hydrogen atom.
摘要翻译: 本发明的目的是提供一种新的金属络合物。 具有[(PtII)2(MI)4(L)8]的组成的金属络合物,其中MI是H +,AgI,AuI或CuI,L是由以下化学式表示的化合物。 具有[(PtII)2(MI)4(X)2(L)6]的组成的金属络合物,其中MI为AgI,AuI或CuI,X为Cl-,Br-或I-,L为 化合物由下列化学式表示。 在该式中,R 1,R 2和R 3独立地为氢原子,氯原子,溴原子,碘原子,羟基,苯基,三氟甲苯基,五氟苯基,萘基,甲基 乙基,异丙基,叔丁基,三氟甲基,羟甲基或羟乙基。 式中的R 1,R 2和R 3中的至少一个不是氢原子。
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公开(公告)号:US07893611B2
公开(公告)日:2011-02-22
申请号:US12444826
申请日:2007-11-01
CPC分类号: C07F15/0093 , C07D231/12 , C09K11/06 , C09K2211/1044 , C09K2211/185 , H01L51/0087 , H01L51/009 , H01L51/0091 , H01L51/5016 , H05B33/14
摘要: There is provided a novel luminescent metal complex. A metal complex having a composition of [(PtII)2(MI)2(X)2(L)4(LH)2], where MI denotes AgI, AuI or CuI, X denotes Cl, Br or I, L denotes a structure represented by the formula (1), and LH denotes a structure represented by the formula (2).
摘要翻译: 提供了一种新型的发光金属络合物。 具有[(PtII)2(MI)2(X)2(L)4(LH)2]的组成的金属络合物,其中MI表示AgI,AuI或CuI,X表示Cl,Br或I,L表示 式(1)表示的结构,LH表示由式(2)表示的结构。
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公开(公告)号:US20100010231A1
公开(公告)日:2010-01-14
申请号:US12444826
申请日:2007-11-01
CPC分类号: C07F15/0093 , C07D231/12 , C09K11/06 , C09K2211/1044 , C09K2211/185 , H01L51/0087 , H01L51/009 , H01L51/0091 , H01L51/5016 , H05B33/14
摘要: There is provided a novel luminescent metal complex. A metal complex having a composition of [(PtII)2(MI)2(X)2(L)4(LH)2], where MI denotes AgI, AuI or CuI, X denotes Cl, Br or I, L denotes a structure represented by the formula (1), and LH denotes a structure represented by the formula (2).
摘要翻译: 提供了一种新型的发光金属络合物。 具有[(PtII)2(MI)2(X)2(L)4(LH)2]的组成的金属络合物,其中MI表示AgI,AuI或CuI,X表示Cl,Br或I,L表示 式(1)表示的结构,LH表示由式(2)表示的结构。
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公开(公告)号:US20100311982A1
公开(公告)日:2010-12-09
申请号:US12867188
申请日:2009-02-12
申请人: Keisuke Umakoshi , Kazutoyo Kimura , Masayoshi Onishi , Shoji Ishizaka , Noboru Kitamura , Satoshi Mikami
发明人: Keisuke Umakoshi , Kazutoyo Kimura , Masayoshi Onishi , Shoji Ishizaka , Noboru Kitamura , Satoshi Mikami
IPC分类号: C07F15/00
CPC分类号: C07F15/0066 , C07D231/12 , C09K11/06 , C09K2211/1007 , C09K2211/1044 , C09K2211/185 , C09K2211/188 , H01L51/0084 , H01L51/009 , H01L51/0091 , H01L51/5016 , H05B33/14
摘要: Disclosed is a metal complex containing a composition represented by the following formula (a). [(PdII)2(MI)2(X)2(L)4(L′)2] (In the formula (a), MI represents AgI, AuI or CuI; X represents Cl, Br or I; L represents a group represented by formula (1); L′ represents a group represented by formula (2); two MIs may be the same as or different from each other; four Ls may be the same as or different from each other; and two L's may be the same as or different from each other.) (In the formulae (1) and (2), R1, R2 and R3 independently represent a hydrogen atom, a halogen atom, a hydroxy group, an optionally substituted alkyl group, an optionally substituted aryl group or an optionally substituted monovalent heterocyclic group.)
摘要翻译: 公开了含有下述式(a)表示的组成的金属络合物。 [(PdII)2(MI)2(X)2(L)4(L')2](式(a)中,MI表示AgI,AuI或CuI; X表示Cl,Br或I; L表示 由式(1)表示的基团; L'表示由式(2)表示的基团;两个MI可以彼此相同或不同;四个L可以彼此相同或不同;并且两个L可以 彼此相同或不同。)(式(1)和(2)中,R 1,R 2和R 3独立地表示氢原子,卤素原子,羟基,任选取代的烷基,任选地 取代的芳基或任选取代的一价杂环基。)
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公开(公告)号:US08124784B2
公开(公告)日:2012-02-28
申请号:US12867188
申请日:2009-02-12
申请人: Keisuke Umakoshi , Kazutoyo Kimura , Masayoshi Onishi , Shoji Ishizaka , Noboru Kitamura , Satoshi Mikami
发明人: Keisuke Umakoshi , Kazutoyo Kimura , Masayoshi Onishi , Shoji Ishizaka , Noboru Kitamura , Satoshi Mikami
IPC分类号: C07F19/00
CPC分类号: C07F15/0066 , C07D231/12 , C09K11/06 , C09K2211/1007 , C09K2211/1044 , C09K2211/185 , C09K2211/188 , H01L51/0084 , H01L51/009 , H01L51/0091 , H01L51/5016 , H05B33/14
摘要: Disclosed is a metal complex containing a composition represented by the following formula (a). [(PdII)2(MI)2(X)2(L)4(L′)2] (In the formula (a), MI represents AgI, AuI or CuI; X represents Cl, Br or I; L represents a group represented by formula (1); L′ represents a group represented by formula (2); two MIs may be the same as or different from each other; four Ls may be the same as or different from each other; and two L's may be the same as or different from each other.) (In the formulae (1) and (2), R1, R2 and R3 independently represent a hydrogen atom, a halogen atom, a hydroxy group, an optionally substituted alkyl group, an optionally substituted aryl group or an optionally substituted monovalent heterocyclic group.)
摘要翻译: 公开了含有下述式(a)表示的组成的金属络合物。 [(PdII)2(MI)2(X)2(L)4(L')2](式(a)中,MI表示AgI,AuI或CuI; X表示Cl,Br或I; L表示 由式(1)表示的基团; L'表示由式(2)表示的基团;两个MI可以彼此相同或不同;四个L可以彼此相同或不同;并且两个L可以 彼此相同或不同。)(式(1)和(2)中,R 1,R 2和R 3独立地表示氢原子,卤素原子,羟基,任选取代的烷基,任选地 取代的芳基或任选取代的一价杂环基。)
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公开(公告)号:US07973167B2
公开(公告)日:2011-07-05
申请号:US12529742
申请日:2008-03-05
IPC分类号: C07F15/00
CPC分类号: C07D231/12 , C07F15/0093 , C09K11/06 , C09K2211/1044 , C09K2211/188 , H01L51/0087 , H01L51/009 , H01L51/0091 , H01L51/5016
摘要: A novel luminescent metal complex comprises a composition of [(PtII)2(AuI)2(MI)2(L)8] where MI denotes AgI or CuI, and L denotes a structure represented by the formula (1)
摘要翻译: 新型发光金属络合物包含[(PtII)2(AuI)2(MI)2(L)8]的组成,其中MI表示AgI或CuI,L表示由式(1)表示的结构,
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公开(公告)号:US20100105918A1
公开(公告)日:2010-04-29
申请号:US12529742
申请日:2008-03-05
CPC分类号: C07D231/12 , C07F15/0093 , C09K11/06 , C09K2211/1044 , C09K2211/188 , H01L51/0087 , H01L51/009 , H01L51/0091 , H01L51/5016
摘要: A novel luminescent metal complex comprises a composition of [(PtII)2(AuI)2(MI)2(L)8] where MI denotes AgI or CuI, and L denotes a structure represented by the formula (1)
摘要翻译: 新型发光金属络合物包含[(PtII)2(AuI)2(MI)2(L)8]的组成,其中MI表示AgI或CuI,L表示由式(1)表示的结构,
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公开(公告)号:US08765952B2
公开(公告)日:2014-07-01
申请号:US13825269
申请日:2011-09-15
CPC分类号: H01L51/009 , C07D213/22 , C07D231/12 , C07D239/26 , C07F15/0093 , C09K11/06 , C09K2211/1029 , C09K2211/1044 , C09K2211/185 , C09K2211/188 , H01L51/0087 , H01L51/0091 , H05B33/14
摘要: The present invention provides a metal complex containing a cation represented by [(MII)2(MI)2(LC)2(LB)4]2+ [in the aforementioned formula, MII is PtII or PdII, MI is H+, AuI, AgI, CuI, HgI, TlI or PbI, and LC and LB are ligands]. The metal complex of the present invention is useful as a light emitting material of an organic EL device.
摘要翻译: 本发明提供了含有由[(MII)2(MI)2(LC)2(L))4] 2+表示的阳离子的金属络合物[在上述式中,MII是PtII或PdII,MI是H +,AuI, AgI,CuI,HgI,TlI或PbI,LC和LB是配体]。 本发明的金属络合物可用作有机EL器件的发光材料。
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公开(公告)号:US20130253189A1
公开(公告)日:2013-09-26
申请号:US13825269
申请日:2011-09-15
IPC分类号: H01L51/00
CPC分类号: H01L51/009 , C07D213/22 , C07D231/12 , C07D239/26 , C07F15/0093 , C09K11/06 , C09K2211/1029 , C09K2211/1044 , C09K2211/185 , C09K2211/188 , H01L51/0087 , H01L51/0091 , H05B33/14
摘要: The present invention provides a metal complex containing a cation represented by [(MII)2(MI)2(LC)2(LB)4]2+ [in the aforementioned formula, MII is PtII or PdII, MI is H+, AuI, AgI, CuI, HgI, TlI or PbI, and LC and LB are ligands]. The metal complex of the present invention is useful as a light emitting material of an organic EL device.
摘要翻译: 本发明提供了含有由[(MII)2(MI)2(LC)2(L))4] 2+表示的阳离子的金属络合物[在上述式中,MII是PtII或PdII,MI是H +,AuI, AgI,CuI,HgI,TlI或PbI,LC和LB是配体]。 本发明的金属络合物可用作有机EL器件的发光材料。
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10.
公开(公告)号:US6086724A
公开(公告)日:2000-07-11
申请号:US453776
申请日:1995-05-30
IPC分类号: B01J19/08 , B01J19/12 , B23K26/00 , C25B3/00 , G01N21/27 , G01N27/26 , G01N27/416 , G21K1/00 , H05H3/04 , C07B61/00
摘要: Particulates are trapped by laser beam and brought into contact with electrodes to electrochemically and spectroscopically measure the reaction process thereof.Precise measurement of the process of chemical reactions such as electrochemical and photochemical ones of a single particulate is made possible.
摘要翻译: 颗粒被激光束捕获并与电极接触以电化学和光谱测量其反应过程。 可以精确测量化学反应过程,如单一颗粒的电化学和光化学反应过程。
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