Production of dihydronepetalactone
    2.
    发明授权
    Production of dihydronepetalactone 有权
    生产二氢荆芥内酯

    公开(公告)号:US08765975B2

    公开(公告)日:2014-07-01

    申请号:US12519770

    申请日:2007-12-20

    IPC分类号: C07D311/02

    CPC分类号: C07D311/94

    摘要: This invention provides a process for producing dihydronepetalactone using mixtures comprising both trans-cis nepetalactone and cis-trans nepetalactone. A reaction mixture comprising trans-cis nepetalactone and cis-trans nepetalactone is first contacted with hydrogen in the presence of at least one hydrogenation catalyst under conditions that optimise the preferential conversion of trans-cis nepetalactone to dihydronepetalactone. Cis-trans nepetalactone is subsequently converted to dihydronepetalactone by contact with hydrogen in the presence of at least one hydrogenation catalyst.

    摘要翻译: 本发明提供了使用包含反式 - 顺式荆芥内酯和顺 - 反脯氨酸内酯的混合物生产二氢荆芥内酯的方法。 在优化反式 - 顺式荆芥内酯与二氢脯氨酸内酯的优先转化的条件下,首先在至少一种氢化催化剂的存在下,将包含反式 - 顺式荆芥内酯和顺 - 反脯氨酸内酯的反应混合物与氢气接触。 顺反尼泊尔内酯随后在至少一种氢化催化剂存在下通过与氢接触而转化为二氢荆芥内酯。

    PRODUCTION OF DIHYDRONEPETALACTONE
    5.
    发明申请
    PRODUCTION OF DIHYDRONEPETALACTONE 有权
    生产二氢萘酮

    公开(公告)号:US20100168447A1

    公开(公告)日:2010-07-01

    申请号:US12519770

    申请日:2007-12-20

    IPC分类号: C07D311/94

    CPC分类号: C07D311/94

    摘要: This invention provides a process for producing dihydronepetalactone using mixtures comprising both trans-cis nepetalactone and cis-trans nepetalactone. A reaction mixture comprising trans-cis nepetalactone and cis-trans nepetalactone is first contacted with hydrogen in the presence of at least one hydrogenation catalyst under conditions that optimise the preferential conversion of trans-cis nepetalactone to dihydronepetalactone. Cis-trans nepetalactone is subsequently converted to dihydronepetalactone by contact with hydrogen in the presence of at least one hydrogenation catalyst.

    摘要翻译: 本发明提供了使用包含反式 - 顺式荆芥内酯和顺 - 反脯氨酸内酯的混合物生产二氢荆芥内酯的方法。 在优化反式 - 顺式荆芥内酯与二氢脯氨酸内酯的优先转化的条件下,首先在至少一种氢化催化剂的存在下,将包含反式 - 顺式荆芥内酯和顺 - 反脯氨酸内酯的反应混合物与氢气接触。 顺反尼泊尔内酯随后在至少一种氢化催化剂存在下通过与氢接触而转化为二氢荆芥内酯。