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1.发明授权Selective non-precious metal-catalyzed mono-hydrosilylation polyunsaturated compounds 有权选择性非贵金属催化单氢化硅烷化多不饱和化合物公开(公告)号：US08895770B2
公开(公告)日：2014-11-25
申请号：US13302506
申请日：2011-11-22
申请人： Kenrick M. Lewis , Aaron M. Tondreau , Richard W. Cruse , Keith J. Weller , Johannes G. P. Delis , Susan A. Nye , Paul J. Chirik
发明人： Kenrick M. Lewis , Aaron M. Tondreau , Richard W. Cruse , Keith J. Weller , Johannes G. P. Delis , Susan A. Nye , Paul J. Chirik
CPC分类号： C07F15/025 , B01J31/1805
摘要： Disclosed herein is the selective synthesis of mono-hydrosilylated derivatives of polyunsaturated compounds, such as trivinylcyclohexane using non-precious metal based pyridinediimine and terpyridine complex as selective hydrosilylation catalysts.
摘要翻译： 本文公开了多不饱和化合物的单氢化硅烷化衍生物的选择性合成，例如使用非贵金属的吡啶二亚胺和三联吡啶络合物作为选择性氢化硅烷化催化剂的三乙烯基环己烷。
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2.发明授权Non-precious metal-containing 2,8-bis(imino)quinoline complexes and their use as hydrosilylation catalysts 有权非贵重金属的2,8-双（亚氨基）喹啉络合物及其作为氢化硅烷化催化剂的用途公开(公告)号：US08637626B2
公开(公告)日：2014-01-28
申请号：US13302448
申请日：2011-11-22
申请人： Aaron M. Tondreau , Paul J. Chirik , Johannes G. P. Delis , Keith J. Weller , Kenrick M. Lewis , Susan A. Nye
发明人： Aaron M. Tondreau , Paul J. Chirik , Johannes G. P. Delis , Keith J. Weller , Kenrick M. Lewis , Susan A. Nye
IPC分类号： C08G77/06
CPC分类号： C07F15/025 , C07F7/0829 , C07F7/0879
摘要： Disclosed herein are manganese, iron, cobalt, or nickel complexes containing 2,8-bis(imino)quinoline ligands and their use as catalysts or catalysts precursors for hydrosilylation reactions.
摘要翻译： 本文公开了含有2,8-双（亚氨基）喹啉配体的锰，铁，钴或镍络合物及其作为氢化硅烷化反应的催化剂或催化剂前体的用途。
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公开(公告)号：US08236915B2
公开(公告)日：2012-08-07
申请号：US12832627
申请日：2010-07-08
申请人： Johannes G. P. Delis , Susan A. Nye , Kenrick M. Lewis , Keith J. Weller , Paul J. Chirik , Aaron M. Tondreau , Sarah Kathleen Russell
发明人： Johannes G. P. Delis , Susan A. Nye , Kenrick M. Lewis , Keith J. Weller , Paul J. Chirik , Aaron M. Tondreau , Sarah Kathleen Russell
IPC分类号： C08G77/06
CPC分类号： C07F7/1876 , C07B2200/11 , C07F15/02
摘要： Disclosed herein are manganese, iron, cobalt, or nickel complexes containing terdentate pyridine diimine ligands and their use as efficient and selective hydrosilylation catalysts.
摘要翻译： 本文公开了含有三齿吡啶二亚胺配体的锰，铁，钴或镍配合物及其作为有效和选择性氢化硅烷化催化剂的用途。
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4.发明授权In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts 有权含有用作氢化硅烷化催化剂的三齿氮配体的金属络合物的原位活化公开(公告)号：US08765987B2
公开(公告)日：2014-07-01
申请号：US13302236
申请日：2011-11-22
申请人： Paul J. Chirik , Aaron M. Tondreau , Johannes G. P. Delis , Kenrick M. Lewis , Keith J. Weller , Susan A. Nye
发明人： Paul J. Chirik , Aaron M. Tondreau , Johannes G. P. Delis , Kenrick M. Lewis , Keith J. Weller , Susan A. Nye
IPC分类号： C07F7/18
CPC分类号： C07F7/0879 , C07F7/0838
摘要： Disclosed herein is a process for the hydrosilylation of a composition containing a silyl hydride and a compound containing at least one unsaturated group, the process comprising contacting a non-previous metal based complex as a catalyst precursor with an activator being a reducing agent shortly before, simultaneously or after contacting the complex with the composition, to cause the silyl hydride to react with the compound containing at least one unsaturated group to produce a hydrosilylation product.
摘要翻译： 本文公开了含有甲硅烷基氢化物和含有至少一个不饱和基团的化合物的组合物的氢化硅烷化方法，该方法包括使非先前的作为催化剂前体的金属络合物与不久之前的还原剂的活化剂接触， 同时或使复合物与组合物接触后，使甲硅烷基氢化物与含有至少一个不饱和基团的化合物反应产生氢化硅烷化产物。
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5.发明申请SELECTIVE NON-PRECIOUS METAL-CATALYZED MONO-HYDROSILYLATION OF POLYUNSATURATED COMPOUNDS 有权选择性非金属金属催化的聚氧化复合化合物的单羟基化公开(公告)号：US20120130105A1
公开(公告)日：2012-05-24
申请号：US13302506
申请日：2011-11-22
申请人： Kenrick M. Lewis , Aaron M. Tondreau , Richard W. Cruse , Keith J. Weller , Johannes G.P. Delis , Susan A. Nye , Paul J. Chirik
发明人： Kenrick M. Lewis , Aaron M. Tondreau , Richard W. Cruse , Keith J. Weller , Johannes G.P. Delis , Susan A. Nye , Paul J. Chirik
CPC分类号： C07F15/025 , B01J31/1805
摘要： Disclosed herein is the selective synthesis of mono-hydrosilylated derivatives of polyunsaturated compounds, such as trivinylcyclohexane using non-precious metal based pyridinediimine and terpyridine complex as selective hydrosilylation catalysts.
摘要翻译： 本文公开了多不饱和化合物的单氢化硅烷化衍生物的选择性合成，例如使用非贵金属的吡啶二亚胺和三联吡啶络合物作为选择性氢化硅烷化催化剂的三乙烯基环己烷。
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6.发明申请NON-PRECIOUS METAL-CONTAINING 2,8-BIS(IMINO)QUINOLINE COMPLEXES AND THEIR USE AS HYDROSILYLATION CATALYSTS 有权非金属含金属2,8位（IMINO）喹啉配合物及其作为氢化催化剂的用途公开(公告)号：US20120130021A1
公开(公告)日：2012-05-24
申请号：US13302448
申请日：2011-11-22
申请人： Aaron M. Tondreau , Paul J. Chirik , Johannes G.P. Delis , Keith J. Weller , Kenrick M. Lewis , Susan A. Nye
发明人： Aaron M. Tondreau , Paul J. Chirik , Johannes G.P. Delis , Keith J. Weller , Kenrick M. Lewis , Susan A. Nye
CPC分类号： C07F15/025 , C07F7/0829 , C07F7/0879
摘要： Disclosed herein are manganese, iron, cobalt, or nickel complexes containing 2,8-bis(imino)quinoline ligands and their use as catalysts or catalysts precursors for hydrosilylation reactions.
摘要翻译： 本文公开了含有2,8-双（亚氨基）喹啉配体的锰，铁，钴或镍络合物及其作为氢化硅烷化反应的催化剂或催化剂前体的用途。
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公开(公告)号：US20110009573A1
公开(公告)日：2011-01-13
申请号：US12832627
申请日：2010-07-08
申请人： Johannes G.P. Delis , Susan A. Nye , Kenrick M. Lewis , Keith J. Weller , Paul J. Chirik , Aaron M. Tondreau , Sarah Kathleen Russell
发明人： Johannes G.P. Delis , Susan A. Nye , Kenrick M. Lewis , Keith J. Weller , Paul J. Chirik , Aaron M. Tondreau , Sarah Kathleen Russell
CPC分类号： C07F7/1876 , C07B2200/11 , C07F15/02
摘要： Disclosed herein are manganese, iron, cobalt, or nickel complexes containing terdentate pyridine diimine ligands and their use as efficient and selective hydrosilylation catalysts.
摘要翻译： 本文公开了含有三齿吡啶二亚胺配体的锰，铁，钴或镍配合物及其作为有效和选择性氢化硅烷化催化剂的用途。
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8.发明申请IN-SITU ACTIVATION OF METAL COMPLEXES CONTAINING TERDENTATE NITROGEN LIGANDS USED AS HYDROSILYLATION CATALYSTS 有权含有作为氢化催化剂的硫酸氮配体的金属络合物的原位活化公开(公告)号：US20120130106A1
公开(公告)日：2012-05-24
申请号：US13302236
申请日：2011-11-22
申请人： Paul J. Chirik , Aaron M. Tondreau , Johannes G.P. Delis , Kenrick M. Lewis , Keith J. Weller , Susan A. Nye
发明人： Paul J. Chirik , Aaron M. Tondreau , Johannes G.P. Delis , Kenrick M. Lewis , Keith J. Weller , Susan A. Nye
IPC分类号： C07F7/08
CPC分类号： C07F7/0879 , C07F7/0838
摘要： Disclosed herein is a process for the hydrosilylation of a composition containing a silyl hydride and a compound containing at least one unsaturated group, the process comprising contacting a non-previous metal based complex as a catalyst precursor with an activator being a reducing agent shortly before, simultaneously or after contacting the complex with the composition, to cause the silyl hydride to react with the compound containing at least one unsaturated group to produce a hydrosilylation product.
摘要翻译： 本文公开了含有甲硅烷基氢化物和含有至少一个不饱和基团的化合物的组合物的氢化硅烷化方法，该方法包括使非先前的作为催化剂前体的金属络合物与不久之前的还原剂的活化剂接触， 同时或使复合物与组合物接触后，使甲硅烷基氢化物与含有至少一个不饱和基团的化合物反应产生氢化硅烷化产物。
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9.发明授权Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation 有权用于脱氢甲硅烷基化和串联脱氢甲硅烷基化氢化的可重复使用的均匀的钴吡啶二亚胺催化剂公开(公告)号：US09447125B2
公开(公告)日：2016-09-20
申请号：US14270710
申请日：2014-05-06
申请人： Aroop Kumar Roy , Crisita Carmen Hojilla Atienza , Paul J. Chirik , Kenrick M. Lewis , Keith J. Weller , Susan Nye , Johannes G. P. Delis , Julie L. Boyer , Tianning Diao , Eric Pohl
发明人： Aroop Kumar Roy , Crisita Carmen Hojilla Atienza , Paul J. Chirik , Kenrick M. Lewis , Keith J. Weller , Susan Nye , Johannes G. P. Delis , Julie L. Boyer , Tianning Diao , Eric Pohl
IPC分类号： C08G77/06 , C07F7/18 , C07F7/08 , C08G77/38 , B01J31/18 , C07F15/06 , C08L83/04 , C08L83/14 , C08G77/04 , C08G77/12 , C08G77/20
CPC分类号： C07F7/1876 , B01J31/1815 , B01J2231/323 , B01J2531/0241 , B01J2531/0244 , B01J2531/845 , C07F7/0829 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F15/065 , C08G77/12 , C08G77/20 , C08G77/38 , C08L83/04 , C08L83/14
摘要： Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient, reusable, and selective dehydrogenative silylation, crosslinking, and tandem dehydrogenative silylation-hydrogenation catalysts.
摘要翻译： 本文公开了含有三齿吡啶二亚胺配体的钴配合物及其作为有效，可重复使用和选择性脱氢甲硅烷基化，交联和串联脱氢甲硅烷基化氢化催化剂的用途。
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10.发明授权Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation 有权钴催化剂及其用于氢化硅烷化和脱氢甲硅烷基化的用途公开(公告)号：US09381506B2
公开(公告)日：2016-07-05
申请号：US14547726
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
CPC分类号： C07F5/025 , B01J31/183 , B01J31/2295 , B01J2231/14 , B01J2231/323 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F19/00
摘要： Disclosed herein are cobalt terpyridine complexes containing a single ligand coordinated to the cobalt, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译： 本文公开了含有与钴配位的单一配体的钴三联吡啶络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。 钴配合物还表现出足够的空气稳定性用于处理和操作。
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