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1.发明授权Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation 有权钴催化剂及其用于氢化硅烷化和脱氢甲硅烷基化的用途公开(公告)号：US09381506B2
公开(公告)日：2016-07-05
申请号：US14547726
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
CPC分类号： C07F5/025 , B01J31/183 , B01J31/2295 , B01J2231/14 , B01J2231/323 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F19/00
摘要： Disclosed herein are cobalt terpyridine complexes containing a single ligand coordinated to the cobalt, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译： 本文公开了含有与钴配位的单一配体的钴三联吡啶络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。 钴配合物还表现出足够的空气稳定性用于处理和操作。
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2.发明申请COBALT CATALYSTS AND THEIR USE FOR HYDROSILYLATION AND DEHYDROGENATIVE SILYLATION 有权钴催化剂及其用于氢化和脱氢硅烷的使用公开(公告)号：US20150141648A1
公开(公告)日：2015-05-21
申请号：US14547726
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
CPC分类号： C07F5/025 , B01J31/183 , B01J31/2295 , B01J2231/14 , B01J2231/323 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F19/00
摘要： Disclosed herein are cobalt terpyridine complexes containing a single ligand coordinated to the cobalt, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译： 本文公开了含有与钴配位的单一配体的钴三联吡啶络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。 钴配合物还表现出足够的空气稳定性用于处理和操作。
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3.发明授权Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation 有权钴催化剂及其用于氢化硅烷化和脱氢甲硅烷基化的用途公开(公告)号：US09387468B2
公开(公告)日：2016-07-12
申请号：US14547641
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
CPC分类号： B01J31/2295 , B01J2231/14 , B01J2231/323 , B01J2231/766 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F15/065 , C08G81/02
摘要： Disclosed herein are cobalt complexes containing pyridine di-imine ligands and chelating alkenyl-modified silyl ligands, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译： 本文公开了含有吡啶二亚胺配体和螯合烯基 - 修饰的甲硅烷基配体的钴络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。 钴配合物还表现出足够的空气稳定性用于处理和操作。
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4.发明申请DEHYDROGENATIVE SILYLATION, HYDROSILYLATION AND CROSSLINKING USING COBALT CATALYSTS 有权脱氢硅烷化，使用钴催化剂的氢化和交联公开(公告)号：US20150080536A1
公开(公告)日：2015-03-19
申请号：US14547696
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
CPC分类号： C07F7/0829 , B01J31/1815 , B01J2231/323 , B01J2531/0241 , B01J2531/0244 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/065 , C08G77/12 , C08G77/20 , C08G77/38 , C08L83/04 , C08L83/14
摘要： Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient and selective dehydrogenative silylation, hydrosilylation, and crosslinking catalysts.
摘要翻译： 本文公开了含有三齿吡啶二亚胺配体的钴络合物及其作为有效和选择性脱氢甲硅烷基化，氢化硅烷化和交联催化剂的用途。
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5.发明授权Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation 有权钴催化剂及其用于氢化硅烷化和脱氢甲硅烷基化的用途公开(公告)号：US09381505B2
公开(公告)日：2016-07-05
申请号：US14547661
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Johannes G. P. Delis , Keith J. Weller
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Johannes G. P. Delis , Keith J. Weller
CPC分类号： B01J31/2295 , B01J2231/323 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F15/065 , C08J3/24 , C08J2383/04
摘要： Disclosed herein are cobalt complexes containing terpyridine ligands and chelating alkene-modified silyl ligands, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译： 本文公开了含有三联吡啶配体和螯合烯烃修饰的甲硅烷基配体的钴络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。 钴配合物还表现出足够的空气稳定性用于处理和操作。
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6.发明申请COBALT CATALYSTS AND THEIR USE FOR HYDROSILYLATION AND DEHYDROGENATIVE SILYLATION 有权钴催化剂及其用于氢化和脱氢硅烷的使用公开(公告)号：US20150137033A1
公开(公告)日：2015-05-21
申请号：US14547641
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G.P. Delis , Renyuan Yu
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G.P. Delis , Renyuan Yu
CPC分类号： B01J31/2295 , B01J2231/14 , B01J2231/323 , B01J2231/766 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F15/065 , C08G81/02
摘要： Disclosed herein are cobalt complexes containing pyridine di-imine ligands and chelating alkenyl-modified silyl ligands, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译： 本文公开了含有吡啶二亚胺配体和螯合烯基 - 修饰的甲硅烷基配体的钴络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。 钴配合物还表现出足够的空气稳定性用于处理和操作。
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7.发明授权Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation 有权用于脱氢甲硅烷基化和串联脱氢甲硅烷基化氢化的可重复使用的均匀的钴吡啶二亚胺催化剂公开(公告)号：US09447125B2
公开(公告)日：2016-09-20
申请号：US14270710
申请日：2014-05-06
申请人： Aroop Kumar Roy , Crisita Carmen Hojilla Atienza , Paul J. Chirik , Kenrick M. Lewis , Keith J. Weller , Susan Nye , Johannes G. P. Delis , Julie L. Boyer , Tianning Diao , Eric Pohl
发明人： Aroop Kumar Roy , Crisita Carmen Hojilla Atienza , Paul J. Chirik , Kenrick M. Lewis , Keith J. Weller , Susan Nye , Johannes G. P. Delis , Julie L. Boyer , Tianning Diao , Eric Pohl
IPC分类号： C08G77/06 , C07F7/18 , C07F7/08 , C08G77/38 , B01J31/18 , C07F15/06 , C08L83/04 , C08L83/14 , C08G77/04 , C08G77/12 , C08G77/20
CPC分类号： C07F7/1876 , B01J31/1815 , B01J2231/323 , B01J2531/0241 , B01J2531/0244 , B01J2531/845 , C07F7/0829 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F15/065 , C08G77/12 , C08G77/20 , C08G77/38 , C08L83/04 , C08L83/14
摘要： Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient, reusable, and selective dehydrogenative silylation, crosslinking, and tandem dehydrogenative silylation-hydrogenation catalysts.
摘要翻译： 本文公开了含有三齿吡啶二亚胺配体的钴配合物及其作为有效，可重复使用和选择性脱氢甲硅烷基化，交联和串联脱氢甲硅烷基化氢化催化剂的用途。
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8.发明申请COBALT CATALYSTS AND THEIR USE FOR HYDROSILYLATION AND DEHYDROGENATIVE SILYLATION 有权钴催化剂及其用于氢化和脱氢硅烷的使用公开(公告)号：US20150141647A1
公开(公告)日：2015-05-21
申请号：US14547661
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Johannes G.P. Delis , Keith J. Weller
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Johannes G.P. Delis , Keith J. Weller
CPC分类号： B01J31/2295 , B01J2231/323 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F15/065 , C08J3/24 , C08J2383/04
摘要： Disclosed herein are cobalt complexes containing terpyridine ligands and chelating alkene-modified silyl ligands, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译： 本文公开了含有三联吡啶配体和螯合烯烃修饰的甲硅烷基配体的钴络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。 钴配合物还表现出足够的空气稳定性用于处理和操作。
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9.发明申请SELECTIVE 1,2-HYDROSILYLATION OF TERMINALLY UNSATURATED 1,3-DIENES USING IRON CATALYSTS 有权使用铁催化剂的终端不饱和1,3-二氧化物的选择性1,2-脱氢公开(公告)号：US20140330024A1
公开(公告)日：2014-11-06
申请号：US14270661
申请日：2014-05-06
申请人： Crisita Carmen Hojilla Atienza , Aroop Kumar Roy , Paul J. Chirik , Keith J. Weller , Johannes G.P. Delis , Tianning Diao
发明人： Crisita Carmen Hojilla Atienza , Aroop Kumar Roy , Paul J. Chirik , Keith J. Weller , Johannes G.P. Delis , Tianning Diao
IPC分类号： C07F7/08
CPC分类号： C07F7/0812 , B01J31/1815 , B01J2231/323 , B01J2531/0216 , B01J2531/0244 , B01J2531/842 , C07F7/0803
摘要： The present invention is directed to a selective and efficient process for the hydrosilylation of compounds containing terminally unsaturated 1,3-dienes using iron-based hydrosilylation catalysts. The resulting 1,2-addition products are useful as precursors for various silicone materials or silane- or silyl/silicone-functionalized polyolefins.
摘要翻译： 本发明涉及使用铁基氢化硅烷化催化剂对含有末端不饱和1,3-二烯的化合物进行氢化硅烷化的选择性和有效的方法。 所得1,2-加成产物可用作各种有机硅材料或硅烷或甲硅烷基/硅氧烷官能化聚烯烃的前体。
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10.发明申请REUSABLE HOMOGENEOUS COBALT PYRIDINE DIIMINE CATALYSTS FOR DEHYDROGENATIVE SILYLATION AND TANDEM DEHYDROGENATIVE-SILYLATION-HYDROGENATION 有权用于去离子硅烷化和均聚脱氢硅烷化加氢反应的均匀的均匀的钴盐酸二丁酯催化剂公开(公告)号：US20140243486A1
公开(公告)日：2014-08-28
申请号：US14270710
申请日：2014-05-06
申请人： Aroop Kumar Roy , Crisita Carmen Hojilla Atienza , Paul J. Chirik , Kenrick M. Lewis , Keith J. Weller , Susan Nye , Johannes G.P. Delis , Julie L. Boyer , Tianning Diao , Eric Pohl
发明人： Aroop Kumar Roy , Crisita Carmen Hojilla Atienza , Paul J. Chirik , Kenrick M. Lewis , Keith J. Weller , Susan Nye , Johannes G.P. Delis , Julie L. Boyer , Tianning Diao , Eric Pohl
CPC分类号： C07F7/1876 , B01J31/1815 , B01J2231/323 , B01J2531/0241 , B01J2531/0244 , B01J2531/845 , C07F7/0829 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F15/065 , C08G77/12 , C08G77/20 , C08G77/38 , C08L83/04 , C08L83/14
摘要： Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient, reusable, and selective dehydrogenative silylation, crosslinking, and tandem dehydrogenative silylation-hydrogenation catalysts.
摘要翻译： 本文公开了含有三齿吡啶二亚胺配体的钴配合物及其作为有效，可重复使用和选择性脱氢甲硅烷基化，交联和串联脱氢甲硅烷基化氢化催化剂的用途。
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