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1.发明授权Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation 有权饱和和不饱和硅烃通过铁和钴吡啶二亚胺催化烯烃甲硅烷基化公开(公告)号：US09371339B2
公开(公告)日：2016-06-21
申请号：US14243044
申请日：2014-04-02
申请人： Kenrick Martin Lewis , Crisita Carmen Hojilla Atienza , Julie L. Boyer , Paul J. Chirik , Johannes G. P. Delis , Aroop Kumar Roy
发明人： Kenrick Martin Lewis , Crisita Carmen Hojilla Atienza , Julie L. Boyer , Paul J. Chirik , Johannes G. P. Delis , Aroop Kumar Roy
CPC分类号： C07F7/0829 , C07F7/0805 , C07F7/0896 , C07F15/02 , C07F15/025 , C07F15/06 , C07F15/065
摘要： The present invention relates to processes for the synthesis of saturated and unsaturated silahydrocarbons using iron-containing or cobalt-containing catalysts. The processes of the invention can produce tetraalkylsilanes, phenyltrialkylsilanes, substituted phenyltrialkylsilanes and their mixtures, which are useful as lubricants and hydraulic fluids, as well as alkyl alkenylsilanes, phenyl alkenylsilanes and substituted phenyl alkenylsilanes and their mixtures, which are useful in the synthesis of saturated silahydrocarbons and other organofunctional silanes.
摘要翻译： 本发明涉及使用含铁或含钴催化剂合成饱和和不饱和硅烷烃的方法。 本发明的方法可以生产四烷基硅烷，苯基三烷基硅烷，取代的苯基三烷基硅烷及其混合物，其可用作润滑剂和液压流体，以及烷基烯基硅烷，苯基烯基硅烷和取代的苯基烯基硅烷及其混合物，其可用于合成饱和 硅烷烃等有机官能硅烷。
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2.发明申请ENANTIOPURE BASE-METAL CATALYSTS FOR ASYMMETRIC CATALYSIS AND BIS(IMINO)PYRIDINE IRON ALKYL COMPLEXES FOR CATALYSIS 有权用于不对称催化和BIS（IMINO）的吡啶金属催化剂用于催化的碱金属催化剂公开(公告)号：US20130079567A1
公开(公告)日：2013-03-28
申请号：US13589437
申请日：2012-08-20
CPC分类号： C07F15/06 , B01J31/1815 , B01J31/182 , B01J31/183 , B01J31/1835 , B01J31/184 , B01J2231/645 , B01J2531/0241 , B01J2531/842 , B01J2531/845 , C07B2200/07 , C07C5/02 , C07C5/03 , C07C41/20 , C07C2531/22 , C07C2601/14 , C07C2602/24 , C07F15/02 , C07F15/025 , C07F15/04 , C07F15/045 , C07F15/065 , Y02P20/52 , C07C15/02 , C07C15/107 , C07C13/18 , C07C13/465 , C07C43/205
摘要： Disclosed herein are iron, nickel, or cobalt compounds having tridentate ligands, which can have at least one chiral moiety in the molecular structure thereof and the use of these compounds for the hydrogenation and transformation of olefins (preferably prochiral) and alkynes.
摘要翻译： 本文公开了具有三齿配体的铁，镍或钴化合物，其可以在其分子结构中具有至少一个手性部分，以及这些化合物用于烯烃（优选前手性）和炔烃的氢化和转化的用途。
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3.发明授权Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation 有权钴催化剂及其用于氢化硅烷化和脱氢甲硅烷基化的用途公开(公告)号：US09381506B2
公开(公告)日：2016-07-05
申请号：US14547726
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
CPC分类号： C07F5/025 , B01J31/183 , B01J31/2295 , B01J2231/14 , B01J2231/323 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F19/00
摘要： Disclosed herein are cobalt terpyridine complexes containing a single ligand coordinated to the cobalt, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译： 本文公开了含有与钴配位的单一配体的钴三联吡啶络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。 钴配合物还表现出足够的空气稳定性用于处理和操作。
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4.发明申请SATURATED AND UNSATURATED SILAHYDROCARBONS VIA IRON AND COBALT PYRIDINE DIIMINE CATALYZED OLEFIN SILYLATION 有权饱和和不饱和硅烷通过铁和钴吡啶二胺催化烯烃硅酸盐公开(公告)号：US20140330036A1
公开(公告)日：2014-11-06
申请号：US14243044
申请日：2014-04-02
申请人： Kenrick Martin Lewis , Crisita Carmen Hojilla Atienza , Julie L. Boyer , Paul J. Chirik , Johannes G.P. Delis , Aroop Kumar Roy
发明人： Kenrick Martin Lewis , Crisita Carmen Hojilla Atienza , Julie L. Boyer , Paul J. Chirik , Johannes G.P. Delis , Aroop Kumar Roy
IPC分类号： C07F7/08
CPC分类号： C07F7/0829 , C07F7/0805 , C07F7/0896 , C07F15/02 , C07F15/025 , C07F15/06 , C07F15/065
摘要： The present invention relates to processes for the synthesis of saturated and unsaturated silahydrocarbons using iron-containing or cobalt-containing catalysts. The processes of the invention can produce tetraalkylsilanes, phenyltrialkylsilanes, substituted phenyltrialkylsilanes and their mixtures, which are useful as lubricants and hydraulic fluids, as well as alkyl alkenylsilanes, phenyl alkenylsilanes and substituted phenyl alkenylsilanes and their mixtures, which are useful in the synthesis of saturated silahydrocarbons and other organofunctional silanes.
摘要翻译： 本发明涉及使用含铁或含钴催化剂合成饱和和不饱和硅烷烃的方法。 本发明的方法可以生产四烷基硅烷，苯基三烷基硅烷，取代的苯基三烷基硅烷及其混合物，其可用作润滑剂和液压流体，以及烷基烯基硅烷，苯基烯基硅烷和取代的苯基烯基硅烷及其混合物，其可用于合成饱和 硅烷烃等有机官能硅烷。
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5.发明授权Non-precious metal-containing 2,8-bis(imino)quinoline complexes and their use as hydrosilylation catalysts 有权非贵重金属的2,8-双（亚氨基）喹啉络合物及其作为氢化硅烷化催化剂的用途公开(公告)号：US08637626B2
公开(公告)日：2014-01-28
申请号：US13302448
申请日：2011-11-22
申请人： Aaron M. Tondreau , Paul J. Chirik , Johannes G. P. Delis , Keith J. Weller , Kenrick M. Lewis , Susan A. Nye
发明人： Aaron M. Tondreau , Paul J. Chirik , Johannes G. P. Delis , Keith J. Weller , Kenrick M. Lewis , Susan A. Nye
IPC分类号： C08G77/06
CPC分类号： C07F15/025 , C07F7/0829 , C07F7/0879
摘要： Disclosed herein are manganese, iron, cobalt, or nickel complexes containing 2,8-bis(imino)quinoline ligands and their use as catalysts or catalysts precursors for hydrosilylation reactions.
摘要翻译： 本文公开了含有2,8-双（亚氨基）喹啉配体的锰，铁，钴或镍络合物及其作为氢化硅烷化反应的催化剂或催化剂前体的用途。
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公开(公告)号：US08236915B2
公开(公告)日：2012-08-07
申请号：US12832627
申请日：2010-07-08
申请人： Johannes G. P. Delis , Susan A. Nye , Kenrick M. Lewis , Keith J. Weller , Paul J. Chirik , Aaron M. Tondreau , Sarah Kathleen Russell
发明人： Johannes G. P. Delis , Susan A. Nye , Kenrick M. Lewis , Keith J. Weller , Paul J. Chirik , Aaron M. Tondreau , Sarah Kathleen Russell
IPC分类号： C08G77/06
CPC分类号： C07F7/1876 , C07B2200/11 , C07F15/02
摘要： Disclosed herein are manganese, iron, cobalt, or nickel complexes containing terdentate pyridine diimine ligands and their use as efficient and selective hydrosilylation catalysts.
摘要翻译： 本文公开了含有三齿吡啶二亚胺配体的锰，铁，钴或镍配合物及其作为有效和选择性氢化硅烷化催化剂的用途。
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7.发明申请SELECTIVE NON-PRECIOUS METAL-CATALYZED MONO-HYDROSILYLATION OF POLYUNSATURATED COMPOUNDS 有权选择性非金属金属催化的聚氧化复合化合物的单羟基化公开(公告)号：US20120130105A1
公开(公告)日：2012-05-24
申请号：US13302506
申请日：2011-11-22
申请人： Kenrick M. Lewis , Aaron M. Tondreau , Richard W. Cruse , Keith J. Weller , Johannes G.P. Delis , Susan A. Nye , Paul J. Chirik
发明人： Kenrick M. Lewis , Aaron M. Tondreau , Richard W. Cruse , Keith J. Weller , Johannes G.P. Delis , Susan A. Nye , Paul J. Chirik
CPC分类号： C07F15/025 , B01J31/1805
摘要： Disclosed herein is the selective synthesis of mono-hydrosilylated derivatives of polyunsaturated compounds, such as trivinylcyclohexane using non-precious metal based pyridinediimine and terpyridine complex as selective hydrosilylation catalysts.
摘要翻译： 本文公开了多不饱和化合物的单氢化硅烷化衍生物的选择性合成，例如使用非贵金属的吡啶二亚胺和三联吡啶络合物作为选择性氢化硅烷化催化剂的三乙烯基环己烷。
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8.发明授权Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation 有权钴催化剂及其用于氢化硅烷化和脱氢甲硅烷基化的用途公开(公告)号：US09387468B2
公开(公告)日：2016-07-12
申请号：US14547641
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
CPC分类号： B01J31/2295 , B01J2231/14 , B01J2231/323 , B01J2231/766 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F15/065 , C08G81/02
摘要： Disclosed herein are cobalt complexes containing pyridine di-imine ligands and chelating alkenyl-modified silyl ligands, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译： 本文公开了含有吡啶二亚胺配体和螯合烯基 - 修饰的甲硅烷基配体的钴络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。 钴配合物还表现出足够的空气稳定性用于处理和操作。
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9.发明申请COBALT CATALYSTS AND THEIR USE FOR HYDROSILYLATION AND DEHYDROGENATIVE SILYLATION 有权钴催化剂及其用于氢化和脱氢硅烷的使用公开(公告)号：US20150137033A1
公开(公告)日：2015-05-21
申请号：US14547641
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G.P. Delis , Renyuan Yu
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G.P. Delis , Renyuan Yu
CPC分类号： B01J31/2295 , B01J2231/14 , B01J2231/323 , B01J2231/766 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F15/065 , C08G81/02
摘要： Disclosed herein are cobalt complexes containing pyridine di-imine ligands and chelating alkenyl-modified silyl ligands, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译： 本文公开了含有吡啶二亚胺配体和螯合烯基 - 修饰的甲硅烷基配体的钴络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。 钴配合物还表现出足够的空气稳定性用于处理和操作。
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10.发明申请DEHYDROGENATIVE SILYLATION, HYDROSILYLATION AND CROSSLINKING USING COBALT CATALYSTS 有权脱氢硅烷化，使用钴催化剂的氢化和交联公开(公告)号：US20150080536A1
公开(公告)日：2015-03-19
申请号：US14547696
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
CPC分类号： C07F7/0829 , B01J31/1815 , B01J2231/323 , B01J2531/0241 , B01J2531/0244 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/065 , C08G77/12 , C08G77/20 , C08G77/38 , C08L83/04 , C08L83/14
摘要： Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient and selective dehydrogenative silylation, hydrosilylation, and crosslinking catalysts.
摘要翻译： 本文公开了含有三齿吡啶二亚胺配体的钴络合物及其作为有效和选择性脱氢甲硅烷基化，氢化硅烷化和交联催化剂的用途。
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