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公开(公告)号：US20100029951A1
公开(公告)日：2010-02-04
申请号：US12588251
申请日：2009-10-08
申请人： Kenzo Fukuda , Yasuo Kondo , Norio Tanaka , Hideaki Suzuki , Masatoshi Ohnari , Koichi Nishio
发明人： Kenzo Fukuda , Yasuo Kondo , Norio Tanaka , Hideaki Suzuki , Masatoshi Ohnari , Koichi Nishio
IPC分类号： C07D213/84 , C07C255/18
CPC分类号： C07D231/12
摘要： There is provided a process for stereoselectively producing E-form of 3-acyloxyacrylonitrile compound (3) or Z-form which comprises reacting 3-oxopropionitrile compound (1) with an acid chloride (2), characterized in that the reaction is conducted with removal of hydrogen chloride, or by using an organic base or an inorganic base, to thereby regulate the stereostructure of the product; a process for producing the compound (1) characterized by reacting acetonitrile compound (5) with an aromatic ester compound (6) by use of an alkali metal alkoxide in a hydrocarbon solvent while removing alcohol formed as a by-product by azeotropic distillation in a separating tank; and a process for isomerizing E-form of 3-acyloxyacrylonitrile compound to Z-form thereof by use of an organic base.
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公开(公告)号：US20060178523A1
公开(公告)日：2006-08-10
申请号：US10551041
申请日：2004-03-26
申请人： Kenzo Fukuda , Yasuo Kondo , Norio Tanaka , Hideaki Suzuki , Masatoshi Ohnari , Koichi Nishio
发明人： Kenzo Fukuda , Yasuo Kondo , Norio Tanaka , Hideaki Suzuki , Masatoshi Ohnari , Koichi Nishio
IPC分类号： C07C255/18
CPC分类号： C07D231/12
摘要： There is provided a process for stereoselectively producing E-form of 3-acyloxyacrylonitrile compound (3) or Z-form which comprises reacting 3-oxopropionitrile compound (1) with an acid chloride (2), characterized in that the reaction is conducted with removal of hydrogen chloride, or by using an organic base or an inorganic base, to thereby regulate the stereostructure of the product; a process for producing the compound (1) characterized by reacting acetonitrile compound (5) with an aromatic ester compound (6) by use of an alkali metal alkoxide in a hydrocarbon solvent while removing alcohol formed as a by-product by azeotropic distillation in a separating tank; and a process for isomerizing E-form of 3-acyloxyacrylonitrile compound to Z-form thereof by use of an organic base.
摘要翻译： 提供了一种用于立体选择性地生产3-酰氧基丙烯腈化合物（3）或Z-型的E-型的方法，其包括使3-氧代丙腈化合物（1）与酰氯（2）反应，其特征在于反应进行除去 的氯化氢，或通过使用有机碱或无机碱，从而调节产物的立体结构; 一种制备化合物（1）的方法，其特征在于在烃溶剂中使用碱金属醇盐使乙腈化合物（5）与芳族酯化合物（6）反应，同时通过共沸蒸馏除去形成副产物的醇 分离罐 以及通过使用有机碱将E-型3-酰氧基丙烯腈化合物异构化为Z-形式的方法。
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公开(公告)号：US08324420B2
公开(公告)日：2012-12-04
申请号：US13137584
申请日：2011-08-26
申请人： Kenzo Fukuda , Yasuo Kondo , Norio Tanaka , Hideaki Suzuki , Masatoshi Ohnari , Koichi Nishio
发明人： Kenzo Fukuda , Yasuo Kondo , Norio Tanaka , Hideaki Suzuki , Masatoshi Ohnari , Koichi Nishio
IPC分类号： C07C255/03
CPC分类号： C07D231/12
摘要： There is provided a process for stereoselectively producing E-form of 3-acyloxyacrylonitrile compound (3) or Z-form which comprises reacting 3-oxopropionitrile compound (1) with an acid chloride (2), characterized in that the reaction is conducted with removal of hydrogen chloride, or by using an organic base or an inorganic base, to thereby regulate the stereostructure of the product; a process for producing the compound (1) characterized by reacting acetonitrile compound (5) with an aromatic ester compound (6) by use of an alkali metal alkoxide in a hydrocarbon solvent while removing alcohol formed as a by-product by azeotropic distillation in a separating tank; and a process for isomerizing E-form of 3-acyloxyacrylonitrile compound to Z-form thereof by use of an organic base.
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公开(公告)号：US08138368B2
公开(公告)日：2012-03-20
申请号：US12588251
申请日：2009-10-08
申请人： Kenzo Fukuda , Yasuo Kondo , Norio Tanaka , Hideaki Suzuki , Masatoshi Ohnari , Koichi Nishio
发明人： Kenzo Fukuda , Yasuo Kondo , Norio Tanaka , Hideaki Suzuki , Masatoshi Ohnari , Koichi Nishio
IPC分类号： C07C255/03 , C07C211/78
CPC分类号： C07D231/12
摘要： There is provided a process for stereoselectively producing E-form of 3-acyloxyacrylonitrile compound (3) or Z-form which comprises reacting 3-oxopropionitrile compound (1) with an acid chloride (2), characterized in that the reaction is conducted with removal of hydrogen chloride, or by using an organic base or an inorganic base, to thereby regulate the stereostructure of the product; a process for producing the compound (1) characterized by reacting acetonitrile compound (5) with an aromatic ester compound (6) by use of an alkali metal alkoxide in a hydrocarbon solvent while removing alcohol formed as a by-product by azeotropic distillation in a separating tank; and a process for isomerizing E-form of 3-acyloxyacrylonitrile compound to Z-form thereof by use of an organic base.
摘要翻译： 提供了一种用于立体选择性地生产3-酰氧基丙烯腈化合物（3）或Z-型的E-型的方法，其包括使3-氧代丙腈化合物（1）与酰氯（2）反应，其特征在于反应进行除去 的氯化氢，或通过使用有机碱或无机碱，从而调节产物的立体结构; 一种制备化合物（1）的方法，其特征在于在烃溶剂中使用碱金属醇盐使乙腈化合物（5）与芳族酯化合物（6）反应，同时通过共沸蒸馏除去形成副产物的醇 分离罐 以及通过使用有机碱将E-型3-酰氧基丙烯腈化合物异构化为Z-形式的方法。
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公开(公告)号：US20110313173A1
公开(公告)日：2011-12-22
申请号：US13137584
申请日：2011-08-26
申请人： Kenzo Fukuda , Yasuo Kondo , Norio Tanaka , Hideaki Suzuki , Masatoshi Ohnari , Koichi Nishio
发明人： Kenzo Fukuda , Yasuo Kondo , Norio Tanaka , Hideaki Suzuki , Masatoshi Ohnari , Koichi Nishio
IPC分类号： C07D403/06 , C07D231/12
CPC分类号： C07D231/12
摘要： There is provided a process for stereoselectively producing E-form of 3-acyloxyacrylonitrile compound (3) or Z-form which comprises reacting 3-oxopropionitrile compound (1) with an acid chloride (2), characterized in that the reaction is conducted with removal of hydrogen chloride, or by using an organic base or an inorganic base, to thereby regulate the stereostructure of the product; a process for producing the compound (1) characterized by reacting acetonitrile compound (5) with an aromatic ester compound (6) by use of an alkali metal alkoxide in a hydrocarbon solvent while removing alcohol formed as a by-product by azeotropic distillation in a separating tank; and a process for isomerizing E-form of 3-acyloxyacrylonitrile compound to Z-form thereof by use of an organic base.
摘要翻译： 提供了一种用于立体选择性地生产3-酰氧基丙烯腈化合物（3）或Z-型的E-型的方法，其包括使3-氧代丙腈化合物（1）与酰氯（2）反应，其特征在于反应进行除去 的氯化氢，或通过使用有机碱或无机碱，从而调节产物的立体结构; 一种制备化合物（1）的方法，其特征在于在烃溶剂中使用碱金属醇盐使乙腈化合物（5）与芳族酯化合物（6）反应，同时通过共沸蒸馏除去形成副产物的醇 分离罐 以及通过使用有机碱将E-型3-酰氧基丙烯腈化合物异构化为Z-形式的方法。
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公开(公告)号：US07649104B2
公开(公告)日：2010-01-19
申请号：US10551041
申请日：2004-03-26
申请人： Kenzo Fukuda , Yasuo Kondo , Norio Tanaka , Hideaki Suzuki , Masatoshi Ohnari , Koichi Nishio
发明人： Kenzo Fukuda , Yasuo Kondo , Norio Tanaka , Hideaki Suzuki , Masatoshi Ohnari , Koichi Nishio
IPC分类号： C07C255/07
CPC分类号： C07D231/12
摘要： There is provided a process for stereoselectively producing E-form of 3-acyloxyacrylonitrile compound (3) or Z-form which comprises reacting 3-oxopropionitrile compound (1) with an acid chloride (2), characterized in that the reaction is conducted with removal of hydrogen chloride, or by using an organic base or an inorganic base, to thereby regulate the stereostructure of the product; a process for producing the compound (1) characterized by reacting acetonitrile compound (5) with an aromatic ester compound (6) by use of an alkali metal alkoxide in a hydrocarbon solvent while removing alcohol formed as a by-product by azeotropic distillation in a separating tank; and a process for isomerizing E-form of 3-acyloxyacrylonitrile compound to Z-form thereof by use of an organic base.
摘要翻译： 提供了一种用于立体选择性地生产3-酰氧基丙烯腈化合物（3）或Z-型的E-型的方法，其包括使3-氧代丙腈化合物（1）与酰氯（2）反应，其特征在于反应进行除去 的氯化氢，或通过使用有机碱或无机碱，从而调节产物的立体结构; 一种制备化合物（1）的方法，其特征在于在烃溶剂中使用碱金属醇盐使乙腈化合物（5）与芳族酯化合物（6）反应，同时通过共沸蒸馏除去形成副产物的醇 分离罐 以及通过使用有机碱将E-型3-酰氧基丙烯腈化合物异构化为Z-形式的方法。
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公开(公告)号：USD795141S1
公开(公告)日：2017-08-22
申请号：US29582827
申请日：2016-10-31
申请人： Gen Ikeda , Hideaki Suzuki
设计人： Gen Ikeda , Hideaki Suzuki
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公开(公告)号：US09376467B2
公开(公告)日：2016-06-28
申请号：US14004058
申请日：2012-02-28
申请人： Yusuke Kono , Shuji Fujita , Hideaki Suzuki , Mari Okumoto , Takashi Nakae , Kazuhiro Chiba
发明人： Yusuke Kono , Shuji Fujita , Hideaki Suzuki , Mari Okumoto , Takashi Nakae , Kazuhiro Chiba
摘要： The purpose of the present invention is to provide a cross-linked peptide containing a novel non-peptide cross-linked structure, and a method for synthesizing the same. A cross-linked peptide having a novel non-peptide cross-linked structure, a useful intermediate for synthesizing the cross-linked peptide, and a method for synthesizing the novel cross-linked peptide and the intermediate are provided. The cross-linked peptide is characterized by having an —NR— bond in the cross-linked structure. By using the method for synthesizing the cross-linked peptide, a cross-link can be freely designed and an change can be freely made to a cross-link.
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9.发明授权公开(公告)号：US09292011B2
公开(公告)日：2016-03-22
申请号：US14113633
申请日：2012-04-24
申请人： Hideaki Suzuki , Kozo Nakamura , Shinya Yuda , Hiroki Uchiyama , Takashi Saeki , Kesaaki Minemura , Jyunsuke Fujiwara
发明人： Hideaki Suzuki , Kozo Nakamura , Shinya Yuda , Hiroki Uchiyama , Takashi Saeki , Kesaaki Minemura , Jyunsuke Fujiwara
摘要： A hydraulic shovel includes: a storage unit which stores an operation history of a target component of the shovel targeted for life span estimation, a discrimination threshold value used for classifying usage of the target component into a plurality of usage modes based on the operation history, and a usage mode-specific estimated life span indicative of an estimated life span of the target component in each of the usage modes; and an arithmetic and control unit which calculates an operating time of the target component in each of the usage modes in accordance with the operation history and the discrimination threshold value, and estimates the life span of the target component based on the operating time calculated for each of the usage modes and on the usage mode-specific estimated life span.
摘要翻译： 液压挖掘机包括：存储单元，其存储针对寿命估计的铲的目标分量的操作历史;基于操作历史将用于将目标分量的使用分类为多个使用模式的鉴别阈值， 以及指示每个使用模式中目标组件的估计使用寿命的使用模式特定估计寿命; 以及算术和控制单元，其根据操作历史和鉴别阈值来计算每个使用模式中的目标分量的操作时间，并且基于针对每个使用模式计算的操作时间来估计目标分量的寿命 的使用模式和使用模式特定的估计寿命。
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公开(公告)号：US09026184B2
公开(公告)日：2015-05-05
申请号：US12378707
申请日：2009-02-18
申请人： Hideaki Suzuki
发明人： Hideaki Suzuki
CPC分类号： H04W4/16 , H04M1/6091 , H04W88/04 , H04W92/08
摘要： An in-vehicle handsfree apparatus establishes a handsfree profile connection with a first cellular phone and a second cellular phone simultaneously. It is assumed that while the first cellular phone is in a calling state, the second cellular phone receives an incoming call. When a user operates a response to the second cellular phone in the incoming call receiving state, a suspension request signal is transmitted to the first cellular phone in the calling state to thereby switch the call link of the first cellular phone to a suspending state. In contrast, an incoming call response request signal is transmitted to the second cellular phone to thereby switch the call link of the second cellular phone from the incoming call receiving state to a calling state. The connection partner of a call sound path is changed from the first cellular phone to the second cellular phone.
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