公开(公告)号：US08742047B2

公开(公告)日：2014-06-03

申请号：US13380252

申请日：2010-08-24

申请人： Kevin M. Lewandowski ,  Larry R. Krepski ,  Yizhong Wang ,  Joel D. Oxman ,  Peiwang Zhu ,  Brian N. Holmes ,  Thomas P. Klun ,  Bryan V. Hunt

发明人： Kevin M. Lewandowski ,  Larry R. Krepski ,  Yizhong Wang ,  Joel D. Oxman ,  Peiwang Zhu ,  Brian N. Holmes ,  Thomas P. Klun ,  Bryan V. Hunt

IPC分类号： C08F26/00 ,  C08F12/30 ,  C08F2/46 ,  C08J3/28 ,  A61K6/00 ,  C08F118/02

CPC分类号： C09D4/00 ,  C07C219/06 ,  C07C229/16 ,  C07C271/16 ,  C07D233/60 ,  C08F22/22 ,  C08F222/1006 ,  C08F222/22

摘要： A multifunctional polymerizable ionic liquid is described comprising an anion and a cationic group having at least two ethylenically unsaturated polymerizable groups, each bonded to the cationic group via a divalent non-alkyl linking group. The multifunctional linking groups independently comprise a heteroatom such as oxygen or nitrogen. The linking groups may independently comprise one or more linkages such as an amide, urea, or ether linkage and more typically a urethane or ester linkage. The ethylenically unsaturated polymerizable groups are typically (meth)acrylate groups. Coatings and coated articles are also described.

摘要翻译： 描述了一种多功能可聚合离子液体，其包含具有至少两个烯属不饱和可聚合基团的阴离子和阳离子基团，各自通过二价非烷基连接基团与阳离子基团键合。 多官能连接基团独立地包含杂原子如氧或氮。 连接基团可以独立地包含一个或多个键，例如酰胺，脲或醚键，更典型的是氨基甲酸酯或酯键。 烯键式不饱和可聚合基团通常为（甲基）丙烯酸酯基团。 还描述了涂层和涂层制品。

公开(公告)号：US20120149800A1

公开(公告)日：2012-06-14

申请号：US13380252

申请日：2010-08-24

申请人： Kevin M. Lewandowski ,  Larry R. Krepski ,  Yizhong Wang ,  Joel D. Oxman ,  Peiwang Zhu ,  Brian N. Holmes ,  Thomas P. Klun ,  Bryan V. Hunt

发明人： Kevin M. Lewandowski ,  Larry R. Krepski ,  Yizhong Wang ,  Joel D. Oxman ,  Peiwang Zhu ,  Brian N. Holmes ,  Thomas P. Klun ,  Bryan V. Hunt

IPC分类号： C09D139/04 ,  C09D177/00 ,  C09D127/12 ,  C09D7/12

CPC分类号： C09D4/00 ,  C07C219/06 ,  C07C229/16 ,  C07C271/16 ,  C07D233/60 ,  C08F22/22 ,  C08F222/1006 ,  C08F222/22

摘要： A multifunctional polymerizable ionic liquid is described comprising an anion and a cationic group having at least two ethylenically unsaturated polymerizable groups, each bonded to the cationic group via a divalent non-alkyl linking group. The multifunctional linking groups independently comprise a heteroatom such as oxygen or nitrogen. The linking groups may independently comprise one or more linkages such as an amide, urea, or ether linkage and more typically a urethane or ester linkage. The ethylenically unsaturated polymerizable groups are typically (meth)acrylate groups. Coatings and coated articles are also described.

摘要翻译： 描述了一种多功能可聚合离子液体，其包含具有至少两个烯属不饱和可聚合基团的阴离子和阳离子基团，各自通过二价非烷基连接基团与阳离子基团键合。 多官能连接基团独立地包含杂原子如氧或氮。 连接基团可以独立地包含一个或多个键，例如酰胺，脲或醚键，更典型的是氨基甲酸酯或酯键。 烯键式不饱和可聚合基团通常为（甲基）丙烯酸酯基团。 还描述了涂层和涂层制品。

公开(公告)号：US08816029B2

公开(公告)日：2014-08-26

申请号：US13380267

申请日：2010-08-26

申请人： Yizhong Wang ,  Joel D. Oxman ,  Larry R. Krepski ,  Peiwang Zhu ,  Kevin M. Lewandowski ,  Brian N. Holmes ,  Richard L. Severance ,  Joseph D. Rule ,  Thomas P. Klun

发明人： Yizhong Wang ,  Joel D. Oxman ,  Larry R. Krepski ,  Peiwang Zhu ,  Kevin M. Lewandowski ,  Brian N. Holmes ,  Richard L. Severance ,  Joseph D. Rule ,  Thomas P. Klun

IPC分类号： C08F26/00 ,  C08F12/30 ,  C08F118/02 ,  A61K6/00

CPC分类号： C08F28/02 ,  A61K6/083 ,  C07D233/58 ,  C07D233/60 ,  C07D233/61 ,  C08F22/22 ,  C08F26/02 ,  C08K5/3445 ,  C09D4/06 ,  C09D133/066 ,  C09D139/00 ,  C09D141/00 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31935

摘要： Presently described are curable compositions comprising a mixture of at least one (e.g. free-radically) polymerizable ionic liquid and at least one other ethylenically unsaturated monomer, oligomer, or polymer. The polymerizable ionic liquid is characterized as having an air to nitrogen curing exotherm ratio of at least 0.70. Also described are articles and methods of making articles from such curable compositions. A monofunctional polymerizable ionic liquid is also described comprising a non-polymerizable substituted imidazolium cationic group and a polymerizable sulfonate anion.

摘要翻译： 目前描述的是包含至少一种（例如自由基）可聚合离子液体和至少一种其它烯属不饱和单体，低聚物或聚合物的混合物的可固化组合物。 可聚合离子液体的特征在于具有至少0.70的空气至氮固化放热比。 还描述了从这种可固化组合物制备制品的制品和方法。 还描述了单官能可聚合离子液体，其包含不可聚合的取代的咪唑鎓阳离子基团和可聚合的磺酸根阴离子。

公开(公告)号：US20120101184A1

公开(公告)日：2012-04-26

申请号：US13380267

申请日：2010-08-26

申请人： Yizhong Wang ,  Joel D. Oxman ,  Larry R. Krepski ,  Peiwang Zhu ,  Kevin M. Lewandowski ,  Brian N. Holmes ,  Richard L. Severance ,  Joseph D. Rule ,  Thomas P. Klun

发明人： Yizhong Wang ,  Joel D. Oxman ,  Larry R. Krepski ,  Peiwang Zhu ,  Kevin M. Lewandowski ,  Brian N. Holmes ,  Richard L. Severance ,  Joseph D. Rule ,  Thomas P. Klun

IPC分类号： C09D135/02 ,  C08F222/24 ,  C08F222/22 ,  C07C229/38 ,  C07D233/61 ,  C07C305/04 ,  C07C229/34 ,  C08F226/06 ,  C08F2/46

CPC分类号： C08F28/02 ,  A61K6/083 ,  C07D233/58 ,  C07D233/60 ,  C07D233/61 ,  C08F22/22 ,  C08F26/02 ,  C08K5/3445 ,  C09D4/06 ,  C09D133/066 ,  C09D139/00 ,  C09D141/00 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31935

摘要： Presently described are curable compositions comprising a mixture of at least one (e.g. free-radically) polymerizable ionic liquid and at least one other ethylenically unsaturated monomer, oligomer, or polymer. The polymerizable ionic liquid is characterized as having an air to nitrogen curing exotherm ratio of at least 0.70. Also described are articles and methods of making articles from such curable compositions. A monofunctional polymerizable ionic liquid is also described comprising a non-polymerizable substituted imidazolium cationic group and a polymerizable sulfonate anion.

摘要翻译： 目前描述的是包含至少一种（例如自由基）可聚合离子液体和至少一种其它烯属不饱和单体，低聚物或聚合物的混合物的可固化组合物。 可聚合离子液体的特征在于具有至少0.70的空气至氮固化放热比。 还描述了从这种可固化组合物制备制品的制品和方法。 还描述了单官能可聚合离子液体，其包含不可聚合的取代的咪唑鎓阳离子基团和可聚合的磺酸根阴离子。

公开(公告)号：US20120276503A1

公开(公告)日：2012-11-01

申请号：US13510991

申请日：2010-12-06

申请人： Yizhong Wang ,  Joel D. Oxman ,  Larry R. Krepski ,  Peiwang Zhu ,  Kevin M. Lewandowski ,  Brian N. Holmes

发明人： Yizhong Wang ,  Joel D. Oxman ,  Larry R. Krepski ,  Peiwang Zhu ,  Kevin M. Lewandowski ,  Brian N. Holmes

IPC分类号： C08F26/06 ,  A61C19/06 ,  C08F2/46 ,  A61K6/083 ,  C08F28/02 ,  C08F26/02

CPC分类号： A61K6/083 ,  A61C5/70 ,  A61C13/26 ,  A61K6/0017 ,  A61K6/0023 ,  A61K6/0029 ,  C08F220/60 ,  C08F2220/606 ,  C08L33/00

摘要： Presently described are curable dental compositions comprising a polymerizable ionic liquid. The polymerizable ionic liquid comprises one or more ethylenically unsaturated (e.g. free-radically polymerizable) groups. Various embodiments of curable dental compositions are described. In some embodiments, the polymerizable ionic liquid is a monofunctional polymerizable ionic liquid comprising an ethylenically unsaturated group. In other embodiments, the polymerizable ionic liquid is a multi-functional polymerizable ionic liquid comprising at least two ethylenically unsaturated groups. The curable dental compositions describe herein can be utilized as dental primers, dental adhesives, dental sealants, and dental composites. In many embodiments, the curable dental compositions further comprise an initiator such as a photoinitiator.

摘要翻译： 目前描述的是包含可聚合离子液体的可固化牙科组合物。 可聚合离子液体包含一种或多种烯属不饱和（例如可自由基聚合的）基团。 描述了可固化牙科组合物的各种实施方案。 在一些实施方案中，可聚合离子液体是包含烯属不饱和基团的单官能可聚合离子液体。 在其它实施方案中，可聚合离子液体是包含至少两个烯属不饱和基团的多官能可聚合离子液体。 本文描述的可治疗牙科用组合物可用作牙科引物，牙科粘合剂，牙科密封剂和牙科复合材料。 在许多实施方案中，可固化牙科组合物还包含引发剂如光引发剂。

公开(公告)号：US08853338B2

公开(公告)日：2014-10-07

申请号：US13510991

申请日：2010-12-06

申请人： Yizhong Wang ,  Joel D. Oxman ,  Larry R. Krepski ,  Peiwang Zhu ,  Kevin M. Lewandowski ,  Brian N. Holmes

发明人： Yizhong Wang ,  Joel D. Oxman ,  Larry R. Krepski ,  Peiwang Zhu ,  Kevin M. Lewandowski ,  Brian N. Holmes

IPC分类号： C08F26/06 ,  A61C19/06 ,  C08F2/46 ,  A61K6/083 ,  C08F28/02 ,  C08F26/02 ,  A61K6/00

CPC分类号： A61K6/083 ,  A61C5/70 ,  A61C13/26 ,  A61K6/0017 ,  A61K6/0023 ,  A61K6/0029 ,  C08F220/60 ,  C08F2220/606 ,  C08L33/00

摘要： Presently described are curable dental compositions comprising a polymerizable ionic liquid. The polymerizable ionic liquid comprises one or more ethylenically unsaturated (e.g. free-radically polymerizable) groups. Various embodiments of curable dental compositions are described. In some embodiments, the polymerizable ionic liquid is a monofunctional polymerizable ionic liquid comprising an ethylenically unsaturated group. In other embodiments, the polymerizable ionic liquid is a multifunctional polymerizable ionic liquid comprising at least two ethylenically unsaturated groups. The curable dental compositions describe herein can be utilized as dental primers, dental adhesives, dental sealants, and dental composites. In many embodiments, the curable dental compositions further comprise an initiator such as a photoinitiator.

摘要翻译： 目前描述的是包含可聚合离子液体的可固化牙科组合物。 可聚合离子液体包含一种或多种烯属不饱和（例如可自由基聚合的）基团。 描述了可固化牙科组合物的各种实施方案。 在一些实施方案中，可聚合离子液体是包含烯属不饱和基团的单官能可聚合离子液体。 在其它实施方案中，可聚合离子液体是包含至少两个烯属不饱和基团的多官能可聚合离子液体。 本文描述的可治疗牙科用组合物可用作牙科引物，牙科粘合剂，牙科密封剂和牙科复合材料。 在许多实施方案中，可固化牙科组合物还包含引发剂如光引发剂。

公开(公告)号：US6151433A

公开(公告)日：2000-11-21

申请号：US85198

申请日：1998-05-27

申请人： William V. Dower ,  Joel D. Oxman ,  Brian N. Holmes

发明人： William V. Dower ,  Joel D. Oxman ,  Brian N. Holmes

IPC分类号： G02B6/38 ,  G02B6/30

CPC分类号： G02B6/3861 ,  Y10S359/90

摘要： A fiber optic connector including a holder for one ore more optical cables, each optical cable having an optical fiber surrounded by strengthening fibers, both of which are surrounded by at least one polymeric coating layer. The cable is stripped in a layerwise manner such that an area of exposed fiber is succeeded by an area of exposed strengthening fibers, succeeded by an area of coated cable. A visible light curable adhesive is injected into the holder and cured by exposure to visible light for up to about 30 seconds, bonding the optical fiber layers and the holder into a unified structure.

摘要翻译： 一种光纤连接器，其包括用于一个或多个光缆的保持器，每个光缆具有被强化纤维包围的光纤，两者都被至少一个聚合物涂层包围。 电缆以分层方式被剥离，使得暴露的纤维的区域由暴露的强化纤维的区域继续，接着是涂覆电缆的区域。 将可见光可固化粘合剂注入保持器中并通过暴露于可见光固化长达约30秒，将光纤层和保持器结合成统一的结构。

公开(公告)号：US6085004A

公开(公告)日：2000-07-04

申请号：US17966

申请日：1998-02-03

申请人： William V. Dower ,  Joel D. Oxman ,  Brian N. Holmes

发明人： William V. Dower ,  Joel D. Oxman ,  Brian N. Holmes

IPC分类号： G02B6/38 ,  G02B6/36

CPC分类号： G02B6/3861 ,  Y10S359/90

摘要： A fiber optic connector including a holder for one ore more optical cables, each optical cable having an optical fiber surrounded by strengthening fibers, both of which are surrounded by at least one polymeric coating layer. The cable is stripped in a layerwise manner such that an area of exposed fiber is succeeded by an area of exposed strengthening fibers, succeeded by an area of coated cable. A visible light curable adhesive is injected into the holder and cured by exposure to visible light for up to about 30 seconds, bonding the optical fiber layers and the holder into a unified structure.

公开(公告)号：US20130101967A1

公开(公告)日：2013-04-25

申请号：US13641899

申请日：2011-06-09

申请人： Ryan E. Johnson ,  Joel D. Oxman ,  Brian N. Holmes

发明人： Ryan E. Johnson ,  Joel D. Oxman ,  Brian N. Holmes

IPC分类号： A61K6/00 ,  A61B6/14

CPC分类号： A61K6/002 ,  A61B6/145 ,  A61C9/00 ,  A61C9/0053 ,  A61C2201/005 ,  A61K6/10 ,  C09D5/028 ,  C09D7/43 ,  C09D7/69 ,  G01B11/00 ,  G21F1/02

摘要： Presently described are methods of intra-oral scanning and an aqueous dental compositions suitable for use for scanning comprising an aqueous solution of a polymer, wherein the solution increases in viscosity from ambient temperature to body temperature; and diffuse reflective particles having an average particle size of at least about 1 micron.

摘要翻译： 目前描述的是口腔内扫描方法和适合用于扫描的水性牙科用组合物，其包括聚合物的水溶液，其中该溶液的粘度从环境温度升高至体温; 和平均粒度为至少约1微米的漫反射粒子。

公开(公告)号：US07576144B2

公开(公告)日：2009-08-18

申请号：US11571944

申请日：2005-07-13

申请人： Kevin M. Lewandowski ,  Ahmed S. Abuelyaman ,  Babu N. Gaddam ,  Sumita B. Mitra ,  Brian N. Holmes ,  Adrian S. Eckert ,  Peter Bissinger

发明人： Kevin M. Lewandowski ,  Ahmed S. Abuelyaman ,  Babu N. Gaddam ,  Sumita B. Mitra ,  Brian N. Holmes ,  Adrian S. Eckert ,  Peter Bissinger

IPC分类号： A61K6/083

CPC分类号： A61K6/083 ,  A61K6/093 ,  C08L33/06 ,  C08L83/16

摘要： Carbosilane monomers that include the following structural features: at least two Si-arylene bonds; at least one (meth)acrylate moiety; no Si—O bonds; and preferably at least two silicon atoms.

摘要翻译： 包括以下结构特征的碳硅烷单体：至少两个Si-亚芳基键; 至少一个（甲基）丙烯酸酯部分; 无Si-O键; 并且优选至少两个硅原子。