摘要:
The present invention discloses a molded product which is heat-resistant, has a high elongation and is produced by a process including the steps of (1) curing a substantially linear polyarylene thioether having a melt viscosity of about 1,000 to 15,000 poise, thereby forming a polyarylene thioether resin having a melt viscosity of about 5,000 to 16,000 poise and a non-Newtonian coefficient, n, of about 1.5 to 2.1, (2) melt extruding the formed polyarylene thioether resin, (3) taking off the extruded polyarylene thioether resin at an R.sub.1 (ratio of the taking-off speed to the extruding speed at the nozzle of the melt extruded product) of about 10 to 1,000 and (4) crystallizing the taken off polyarylene thioether resin until its crystallization degree is not lower than 20 wt %; and coated electric wires having the above molded product as a coating layer.
摘要:
A para-phenylene sulfide block copolymer consisting essentially of a recurring unit (A) ##STR1## and a recurring unit (B) ##STR2## said recurring units (A) being present in the form of a block of 20 to 5,000 units of (A) on the average in the molecular chain, the mol fraction of the recurring units (A) being in the range of 0.50 to 0.98, the block copolymer having a melt viscosity (.eta.*) of 50 to 100,000 poise as determined at 310.degree. C. at a shear rate of 200 sec.sup.-1 and having: (a) a glass transition temperature (Tg) of 20.degree. to 80.degree. C., (b) a crystalline melting point (Tm) of 250.degree. to 285.degree. C., and (c) a crystallization index (Ci) of 15 to 45, this value being that of the heat-treated, but not stretch-oriented copolymer, which block copolymer is preferably produced by a process comprising a first step of heating an aprotic polar organic solvent containing a dihaloaromatic compound consisting essentially of a m-dihalobenzene and an alkali metal sulfide to form a reaction liquid (E) containing a m-phenylene sulfide polymer consisting essentially of recurring units (B) ##STR3## and a second step of adding a p-dihalobenzene to the reaction liquid (E) and heating the mixture in the presence of an alkali metal sulfide and an aprotic polar organic solvent to form a block copolymer consisting essentially of the recurring units (B) and recurring units (A) ##STR4##
摘要:
Novel polyarylenesulfide complexes are obtained by reacting a polyarylenesulfide with 0.05 to 20 mols of at least one strongly basic metal compound per 100 mols of arylenesulfide groups contained in the polyarylenesulfide under a uniformly dispersed condition, and have the properties defined in the following (A) through (C):(A) .eta.*/.eta..sub.0 *=3 to 100, wherein the .eta.* and .eta..sub.0 * stand for melt viscosities of the complex and the starting polyarylenesulfide, respectively;(B) .DELTA.T.sub.c2 =(T.sub.c2).sub.0 -T.sub.c2 =10 to 100.degree. C., wherein T.sub.c2 and (T.sub.c2).sub.0 stand for crystallization temperaturs of the complex and the starting polyarylenesulfide, respectively, observed when the polyarylenesulfide is cooled from its moten state; and(C) .DELTA.(.DELTA.E)=.DELTA.E-(.DELTA.E).sub.0 =5 to 75 kcal/mol, wherein .DELTA.E and (.DELTA.E).sub.0 stand for apparent flow activation energies of the complex and the starting polyarylenesulfide, respectively.The polyarylenesulfide complexes have higher melt viscosity with improved flow characteristics.
摘要:
A process for forming a polyarylenethioether stretched blow molded vessel, by a modified blow molding of a substantially linear polyarylenethioether having a melt viscosity of 3,000 to 20,000 poise [at 310.degree. C., shear rate=200 sec.sup.-1 ]. The modified blow molding involves injecting the polymer in a mold to form a bottomed parison, stretching the bottomed parison along its axis by means of a rod or mandrel, and the stretched bottomed parison is then subjected to blow molding to effect lateral stretching. The blow parison is then heat set.
摘要:
A para-phenylene sulfide block copolymer consisting essentially of a recurring unit (A) ##STR1## and a recurring unit (B) ##STR2## said recurring units (A) being present in the form of a block of 20 to 5,000 units of (A) on the average in the molecular chain, the mol fraction of the recurring units (A) being in the range of 0.50 to 0.98, the block copolymer having a melt viscosity (.eta.*) of 50 to 100,000 poise as determined at 310.degree. C. at a shear rate of 200 sec.sup.-1 and having: (a) a glass transition temperature (Tg) of 20.degree. to 80.degree. C., (b) a crystalline melting point (Tm) of 250.degree. to 285.degree. C., and (c) a crystallization index (Ci) of 15 to 45, this value being that of the heat-treated, but not stretch-oriented copolymer, which block copolymer is preferably produced by a process comprising a first step of heating an aprotic polar organic solvent containing a dihaloaromatic compound consisting essentially of a m-dihalobenzene and an alkali metal sulfide to form a reaction liquid (e) containing a m-phenylene sulfide polymer consisting essentially of recurring units (B) ##STR3## and a second step of adding a p-dihalobenzene to the reaction liquid (E) and heating the mixture in the presence of an alkali metal sulfide an an aprotic polar organic solvent to form a block copolymer consisting essentially of the recurring units (B) and recurring units (A) ##STR4##
摘要:
Polyarylene thioethers having increased melt crystallization temperature are produced by subjecting a polyarylene thioether recovered from a conventional polycondensation of dichlorobenzene with sodium sulfide to a treatment with an aqueous non-oxidative strong acid such asd HCl, H.sub.2 SO.sub.4 or H.sub.3 PO.sub.4 or with an aqueous salt of the non-oxidative strong acid with a weak base such as ammonia.
摘要翻译:具有增加的熔融结晶温度的聚亚芳基硫醚通过将二氯苯与硫化钠的常规缩聚反应的聚亚芳基硫醚用非水氧化性强酸如HCl,H 2 SO 4或H 3 PO 4水溶液或非水溶液 氧化强酸与弱碱如氨。
摘要:
Corrosion of a melt-processing apparatus for processing a polyarylene thioether at a temperature higher than the melting point thereof is prevented by a method which comprises adding to 100 parts by weight of the polyarylene thioether 0.001 to 10 parts by weight of at least one member selected from the group consisting of (i) hydroxides of metals of the group IIa of the Periodic Table, (ii) oxides of metals of the group IIa of the Periodic Table and (iii) aromatic carboxylic acid salts of metals of the group IIa of the Periodic Table.By this method, even if the melt-processing article obtained is exposed to moisture, the electrical properties of the article formed (for example, insulation characteristics) and the water resistance are not substantially deteriorated.
摘要:
A content reproducing apparatus includes: a content control unit that controls reproduction of a content by reading a program from a BD and executing the program; a reproduction information recording unit that records reproduction information including a reproduction position within the content during the reproduction; a reproduction information acquiring unit that acquires, upon a start of the reproduction of the BD, the reproduction information recorded at a time of previous reproduction; and a resume-reproduction control unit that starts to reproduce the BD from the reproduction position identified based on the acquired reproduction information or from a vicinity thereof, wherein the content control unit controls the reproduction if the reproduction information has not been acquired by the reproduction information acquiring unit, and the resume-reproduction control unit controls the reproduction if the reproduction information has been acquired by the reproduction information acquiring unit.
摘要:
To provide a fuel injection system that can efficiently supply high pressure fuel with respect to fuel injectors of an internal combustion engine, whose pump is capable of being made versatile, and which has excellent maintainability such as service, replacement and detachment.An internal combustion engine fuel injection system comprises: one cassette type pump that is detachably attached to an internal combustion engine disposed with a cam and pressurizes fuel to a high pressure and pressure-feeds fuel in accompaniment with rotation of the cam; and a common rail that accumulates high pressure fuel that is pressure-fed from the one cassette type pump and supplies the high pressure fuel with respect to plural fuel injectors, wherein the cam is fixed to a camshaft and the camshaft is connected in a predetermined gear ratio with respect to a crankshaft of the internal combustion engine, and the one cassette type pump is disposed with just one plunger for pressurizing fuel in accompaniment with rotation of the cam and just one discharge valve for discharging fuel that has been pressurized by the plunger.
摘要:
In preparation for facsimile transmission, a destination list is displayed. The destination list shows destination-name columns, Fax buttons, and E-mail buttons.