Polyethers obtainable by reacting alkylolated
bis-(4-hydroxyphenyl)-methanes with polyalkylene oxides, and their use
as oil demulsifiers
    3.
    发明授权
    Polyethers obtainable by reacting alkylolated bis-(4-hydroxyphenyl)-methanes with polyalkylene oxides, and their use as oil demulsifiers 失效
    通过羟烷基化的双 - (4-羟基苯基) - 甲烷与聚环氧烷反应获得的聚醚,以及它们作为油破乳剂的用途

    公开(公告)号:US4814394A

    公开(公告)日:1989-03-21

    申请号:US43591

    申请日:1987-04-28

    CPC分类号: C10G33/04 C08G65/34 C08G8/36

    摘要: Polyethers with are suitable as oil demulsifiers are obtainable by reacting(A) a polyalkylene oxide obtained from ethylene oxide and propylene oxide and containing in total from 5 to 200 alkylene oxide units with(B) an alkylolation product of a low molecular weight aldehyde and a bis-(4-hydroxyphenyl)-methane of the general formula II ##STR1## wherein R.sup.1 and R.sup.2 may be identical or different and are each hydrogen, low molecular weight alkyl, phenyl, carboxyl or low molecular weight alkoxycarbonyl, the molar reaction ratio of the compound of the formula II to the alkylolating aldehyde being from 1:1 to 1:4, at from 100.degree. to 180.degree. C. in the presence of an acidic catalyst with removal of the water of reaction, the weight ratio of A to B being from 5:1 to 1:3.

    摘要翻译: 适合作为油破乳剂的聚醚可通过使(A)由环氧乙烷和环氧丙烷获得的聚环氧烷烃和总共5至200个烯化氧单元与(B)低分子量醛的烷氧基化产物和 双(4-羟基苯基) - 甲烷,其中R 1和R 2可以相同或不同,各自为氢,低分子量烷基,苯基,羧基或低分子量烷氧基羰基,摩尔反应比例 在酸性催化剂存在下,式II化合物与烷醇化醛的比例为1:1至1:4,在100至180℃下,除去反应水,A与 B为5:1至1:3。

    Crosslinked oxyalkylated polyalkylenepolyamines
    5.
    发明授权
    Crosslinked oxyalkylated polyalkylenepolyamines 失效
    交联烷氧基化聚亚烷基多胺

    公开(公告)号:US4705834A

    公开(公告)日:1987-11-10

    申请号:US685256

    申请日:1984-12-24

    摘要: Crosslinked oxyalkylated polyalkylenepolyamines which can be obtained by reacting polyalkylenepolyamines, which are completely oxyalkylated at the nitrogen atoms, in each case by from 10 to 300 groups, and possess from 50 to 2,000 repeating alkyleneimine units in the molecule, with from 0.5 to 10% by weight, based on the oxyalkylated polyalkylenepolyamines, of a crosslinking compound which possesses two or more functional groups which are capable of reacting with the terminal alcohol groups of the oxyalkylated polyalkylenepolyamines, and a process for breaking water-in-oil emulsions.

    摘要翻译: 交联的烷氧基化多亚烷基多胺,其可以通过在氮原子上完全烷氧基化的聚亚烷基多胺,在每种情况下反应10〜300个,并且在分子中具有50〜2,000个重复的亚烷基亚胺单元,其中0.5〜10% 具有两个以上能够与烷氧基化聚亚烷基多胺的末端醇基反应的官能团的交联化合物的基于烷氧基化多亚烷基多胺的重量,以及破坏油包水乳液的方法。

    Apparatus for testing fuel additives and oil additives
    6.
    发明授权
    Apparatus for testing fuel additives and oil additives 失效
    用于测试燃料添加剂和油添加剂的装置

    公开(公告)号:US5036699A

    公开(公告)日:1991-08-06

    申请号:US422455

    申请日:1989-10-17

    IPC分类号: G01N33/28

    CPC分类号: G01N33/2835

    摘要: A sample of a fuel/oil/additive mixture is metered continuously to a channel-like, inclined test element along which there is an increasing temperature profile. Under the increasing action of heat on the flowing mixture, solid residual products form on the test element after a certain flow distance. Their weight and the flow distance are evaluated in order to evaluate the additive.

    摘要翻译: 燃料/油/添加剂混合物的样品连续计量到通道样的倾斜测试元件,沿着该倾斜测试元件具有升高的温度分布。 在流动混合物的热量增加的作用下,在一定的流动距离之后,在测试元件上形成固体残余物。 评估它们的重量和流动距离以评估添加剂。

    Methods of demulsifying employing condensates as demulsifiers for oil-in
water emulsions
    8.
    发明授权
    Methods of demulsifying employing condensates as demulsifiers for oil-in water emulsions 失效
    使用冷凝剂作为水分乳化剂的分解剂的方法

    公开(公告)号:US5234626A

    公开(公告)日:1993-08-10

    申请号:US827170

    申请日:1991-02-11

    CPC分类号: C08G71/00 B01F17/005

    摘要: The present invention relates to methods of demulsifying employing condensates as demulsifiers for oil-in-water emulsions and prepared fromA) a precondensate from one or more trialkanolamines of the general formula I ##STR1## in which R.sup.1 to R.sup.3 denote the same or different 1,2-alkylene groups of from 2 to 4 carbon atoms, andB) from 0.1 to 30% w/w, based on said precondensate, of one or more of the following compounds II:a) urea or a urea derivative of the general formula IIa ##STR2## b) a urea derivative of the general formula IIb ##STR3## c) a urethane of the general formula IIc ##STR4## and/or d) a urethane of the general formula IId ##STR5## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.20 -alkyl or C.sub.2 -C.sub.20 -alkenyl,R.sup.2 and R.sup.3 are the same or different and denote hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.4 is C.sub.1 -C.sub.4 -alkyl andR.sup.5 is C.sub.1 -C.sub.12 -alkylene.

    摘要翻译: 本发明涉及使用缩合物作为水包油乳液的破乳剂进行破乳的方法,由A)来自一种或多种通式Ⅰ(I)的三链烷醇胺的预缩合物制备,其中R 1至R 3表示相同的 或不同的2至4个碳原子的1,2-亚烷基,以及B)0.1至30%w / w(基于所述预缩合物)一种或多种下列化合物II:a)脲或脲衍生物 通式IIa(IIa)的脲衍生物b)通式IIb的脲衍生物(IIb)c)通式IIc(IIc)的氨基甲酸酯和/或d)氨基甲酸酯 其中R 1是氢,C 1 -C 20 - 烷基或C 2 -C 20 - 链烯基,R 2和R 3相同或不同,表示氢或C 1 -C 4烷基,R 4是C 1 -C 4烷基, C4-烷基,R5是C1-C12-亚烷基。

    Preparation of ether sulfonates and polyglycol ether sulfonates, and
products prepared by this method
    9.
    发明授权
    Preparation of ether sulfonates and polyglycol ether sulfonates, and products prepared by this method 失效
    醚磺酸盐和聚乙二醇醚磺酸盐的制备,以及通过该方法制备的产物

    公开(公告)号:US4978780A

    公开(公告)日:1990-12-18

    申请号:US405582

    申请日:1989-09-11

    CPC分类号: C07C309/00

    摘要: A process for the preparation of ether sulfonates or polyglycol ether sulfonates by reacting an organic alcoholic or phenolic compound or the corresponding alkoxylate in aqueous solution with vinyl sulfonate in the presence of from 0.1 to 3.0% by weight of an alkaline catalyst and, if required, additionally in the presence of a phase-transfer catalyst, and ether sulfonates or polyglycol ether sulfonates prepared by this process and of the general formulaR--O(C.sub.n H.sub.2n O).sub.z --CH.sub.2 CH.sub.2 SO.sub.3 Xwhere R is H or an aliphatic or aromatic hydrocarbon radical (which may contain nitrogen as a heteroatom) of 1 to 30 carbon atoms, n is from 2 to 30, z is from 0 to 300 and X is an alkali metal.

    摘要翻译: 一种通过使有机醇或酚类化合物或相应的烷氧基化物在水溶液中与乙烯基磺酸酯在0.1至3.0重量%的碱性催化剂存在下反应制备醚磺酸盐或聚乙二醇醚磺酸盐的方法, 另外在相转移催化剂存在下,通过该方法和通式RO(CnH2nO)z-CH2CH2SO3X制备的醚磺酸盐或聚乙二醇醚磺酸盐,其中R为H或脂族或芳族烃基(可含有氮 作为杂原子)为1〜30个碳原子,n为2〜30,z为0〜300,X为碱金属。