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1.发明授权Stabilizing method of isocyanate compounds and isocyanate compositions stabilized thereby 失效由此稳定异氰酸酯化合物和异氰酸酯组合物的稳定方法
公开(公告)号：US5302749A
公开(公告)日：1994-04-12
申请号：US852724
申请日：1992-03-17
IPC分类号： C07C263/18 , C08G18/70
CPC分类号： C08G18/70 , C07C263/18 , C07C265/14 , C08G18/7642
摘要： A method for stabilizing an isocyanate compound by adding 10-5000 ppm of phenol to the isocyanate compound, and also an isocyanate composition so stabilized. In the isocyanate composition stabilized by the above method, coloring due to time-dependent changes and the occurrence of turbidity through self-polymerization are both suppressed so that it shows outstanding storage stability compared with a corresponding isocyanate composition containing a conventional stabilizer.
摘要翻译： 通过向异氰酸酯化合物中加入10-5000ppm的苯酚以及如此稳定的异氰酸酯组合物来稳定异氰酸酯化合物的方法。 在通过上述方法稳定的异氰酸酯组合物中，由于时间依赖性变化引起的着色和通过自聚合的浊度的发生都被抑制，因此与含有常规稳定剂的相应的异氰酸酯组合物相比，它具有优异的储存稳定性。
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公开(公告)号：US5194559A
公开(公告)日：1993-03-16
申请号：US854583
申请日：1992-03-20
CPC分类号： C08G18/8064 , C08G18/3876 , C08G18/70 , C08G18/775 , G02B1/04
摘要： Optical urethane resins according to the present invention are each obtained by reacting an active hydrogen compound with an isocyanate compound containing as a stabilizer a phenolic compound. Owing to their low yellowness, high light transmittance and optical-strain-free quality, these resins are useful as optical materials for plastic lenses or the like which are required to be colorless, transparent and uniform.
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公开(公告)号：US5389708A
公开(公告)日：1995-02-14
申请号：US9761
申请日：1993-01-27
IPC分类号： B29C33/60 , C08K5/5398 , G02C11/08
CPC分类号： C08K5/5398 , B29C33/60
摘要： An internal release agent comprises a sulfur-containing acid phosphoric esters selected from the group consisting of thiophosphoric acid esters and dithiophosphoric acid esters of the formula, ##STR1## where X and Y are independently selected from the group consisting of an oxygen atom and a sulfur atom, at least one of X and Y is a sulfur atom, and R.sub.1 and R.sub.2 are independently alkyl groups.
摘要翻译： 内部脱模剂包括选自下式的硫代磷酸酯和二硫代磷酸酯的含硫酸性磷酸酯，其中X和Y独立地选自氧原子 和硫原子，X和Y中的至少一个是硫原子，R 1和R 2独立地是烷基。
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4.发明授权Polysulfide-based resin composition, polysulfide-based resin, and optical material comprising the resin 失效聚硫醚系树脂组合物，聚硫醚系树脂，以及包含该树脂的光学材料
公开(公告)号：US5955206A
公开(公告)日：1999-09-21
申请号：US640442
申请日：1996-04-30
申请人： Koju Okazaki , Chitoshi Shimakawa , Mamoru Tanaka , Yoshinobu Kanemura , Teruyuki Nagata , Yoshihiro Irizato , Shinichi Umeda
发明人： Koju Okazaki , Chitoshi Shimakawa , Mamoru Tanaka , Yoshinobu Kanemura , Teruyuki Nagata , Yoshihiro Irizato , Shinichi Umeda
CPC分类号： C08G59/66 , C08G18/3876 , G02B1/041
摘要： A composition for polysulfide-based resin comprising a polythiol having 4 or more functional groups and a compound having a reactive unsaturated bond(s) and/or b epoxy group(s) and/or c iso(thio)cyanato group(s) in one molecule (however, a+b+c.gtoreq.2, and a and b are not simultaneously 0). A polysulfide-based resin obtained by curing the composition, an optical material comprising the resin, a lens consisting of the optical material and a method for producing the polysulfide-based resin are also set forth.
摘要翻译： 一种用于多硫化物基树脂的组合物，其包含具有4个或更多个官能团的多硫醇和具有一个或多个反应性不饱和键和/或b个环氧基和/或c（硫代）氰基的化合物， 一个分子（然而，a + b + c> / = 2，a和b不同时为0）。 还提出了通过固化组合物获得的聚硫化物基树脂，包含树脂的光学材料，由光学材料组成的透镜和用于制备多硫化物基树脂的方法。
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5.发明授权Polythiol useful for preparing sulfur-containing urethane-based resin and process for producing the same 失效用于制备含硫氨基甲酸酯基树脂的聚硫醇及其制备方法
公开(公告)号：US5608115A
公开(公告)日：1997-03-04
申请号：US373083
申请日：1995-01-17
IPC分类号： G02B1/04 , C07C319/20 , C07C321/14 , C08G18/30 , C08G18/38 , C08G18/52 , C08G18/77
CPC分类号： C08G18/775 , C07C321/14 , C08G18/3876 , C08G18/52 , G02B1/041
摘要： A novel polythiol having four or more functional groups, a process for producing the polythiol comprising reacting thiourea with a specific compound, a sulfur-containing urethane-based resin prepared from the polythiol and a lens made of the resin. The resin has a high refractive index, and low dispersion of refractive index, is lightweight, colorless and transparent, has no optical distortion, and has excellent characteristics in weatherability, dye-affinity, heat resistance, impact resistance and machinability.
摘要翻译： 一种具有四个或更多个官能团的新型多硫醇，一种制备多硫醇的方法，包括使硫脲与特定化合物反应，由多硫醇制备的含硫氨基甲酸酯基树脂和由该树脂制成的透镜。 该树脂折射率高，折射率分散性低，重量轻，无色透明，无变形，耐候性，染料亲合性，耐热性，耐冲击性和切削性优异。
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6.发明授权Resin having a large refractive index, lenses comprising the resin and process for preparing the lens 失效树脂具有大的折射指数，包含树脂的镜片和准备镜片的过程
公开(公告)号：US5084545A
公开(公告)日：1992-01-28
申请号：US379378
申请日：1989-07-13
申请人： Teruyuki Nagata , Koju Okazaki , Tohru Miura
发明人： Teruyuki Nagata , Koju Okazaki , Tohru Miura
IPC分类号： G02B1/04 , B29C33/60 , B29C39/00 , B29C39/02 , B29D11/00 , B29K75/00 , B29K105/32 , B29L11/00 , C08G18/32 , C08G18/38 , C08G18/42 , C08G18/46 , C08G18/48 , C08G18/50 , C08G18/70 , C08G18/72 , C08G18/76 , C08G18/77 , C08G18/78
CPC分类号： B29C33/60 , C08G18/3203 , C08G18/3221 , C08G18/381 , C08G18/3863 , C08G18/3874 , C08G18/3876 , C08G18/72 , C08G18/76 , C08G18/775 , C08G18/7893
摘要： The present invention relates to a process for producing a resin useful in plastic lenses, to plastic lenses containing the resin and to a process for producing the lenses.
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7.发明授权Composition for urethane-base plastic lens, urethane-base plastic lens obtained from the composition, and process for the production of the plastic lens 失效用于聚氨酯基塑料透镜，由组合物获得的聚氨酯基塑料透镜的组合物，以及用于生产塑料透镜的方法
公开(公告)号：US5693738A
公开(公告)日：1997-12-02
申请号：US413113
申请日：1995-03-29
申请人： Koju Okazaki , Chitoshi Shimakawa , Mamoru Tanaka , Yoshinobu Kanemura , Teruyuki Nagata , Seiichi Kobayashi , Yoko Tajiri , Nobuya Kawauchi , Katsuyoshi Sasagawa
发明人： Koju Okazaki , Chitoshi Shimakawa , Mamoru Tanaka , Yoshinobu Kanemura , Teruyuki Nagata , Seiichi Kobayashi , Yoko Tajiri , Nobuya Kawauchi , Katsuyoshi Sasagawa
CPC分类号： C08G18/3876 , C08G18/1875 , C08G18/3203 , C08G18/3868 , G02B1/041
摘要： A composition for a urethane-base plastic lens, comprising: (a) at least one ester compound selected from the group consisting of isocyanate compounds, isothiocyanate compounds and isocyanato-containing isothiocyanate compounds, (b) at least one active hydrogen compound selected from the group consisting of hydroxyl compounds, mercapto compounds and mercapto-containing hydroxyl compounds, (c) a tertiary amine, and (d) a Lewis acid; a plastic lens obtained by heating and curing the composition, and a process for the production of the plastic lens. The composition has a long pot life and can produce an optically uniform plastic lens in a short time.
摘要翻译： 一种聚氨酯类塑料透镜用组合物，其含有：（a）至少一种选自异氰酸酯化合物，异硫氰酸酯化合物和含异氰酸酯基的异硫氰酸酯化合物的酯化合物，（b）至少一种选自 由羟基化合物，巯基化合物和含巯基的羟基化合物组成的组，（c）叔胺和（d）路易斯酸; 通过加热和固化组合物获得的塑料透镜，以及用于生产塑料透镜的方法。 该组合物具有长的适用期，并可在短时间内产生光学均匀的塑料透镜。
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8.发明授权Resin for plastic lens having high-refractive index, lens comprising the resin, and method for preparation of the lens 失效具有高折射率的塑料透镜用树脂，包含该树脂的透镜以及该透镜的制备方法
公开(公告)号：US5021503A
公开(公告)日：1991-06-04
申请号：US311352
申请日：1989-02-15
申请人： Teruyuki Nagata , Koju Okazaki , Nobuyuki Kajimoto , Tohru Miura , Yoshinobu Kanemura , Katsuyoshi Sasagawa
发明人： Teruyuki Nagata , Koju Okazaki , Nobuyuki Kajimoto , Tohru Miura , Yoshinobu Kanemura , Katsuyoshi Sasagawa
CPC分类号： C08G18/3876 , C08G18/34 , C08G18/775
摘要： The present invention relates to resin useful in preparing plastic lenses having a high refractive index comprising reacting an aliphatic polyisocyanate compounds having at least one sulfur atom with one or more of active hydrogen compounds selected from the group consisting of a polyol, a polythiol having sulfur atoms only in a mercapto groups, and a polythiol having at least one sulfur atom other than in the mercapto groups; lenses containing the above-mentioned resin; and a method for the preparation thereof characterized by adding an internal release agent to the mixture of the above-mentioned raw materials in casting lenses from the resin; and lenses obtained by this method.
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公开(公告)号：US5013496A
公开(公告)日：1991-05-07
申请号：US310388
申请日：1989-02-15
申请人： Teruyuki Nagata , Koju Okazaki , Nobuyuki Kajimoto , Tohru Miura , Yoshinobu Kanemura , Katsuyoshi Sasagawa
发明人： Teruyuki Nagata , Koju Okazaki , Nobuyuki Kajimoto , Tohru Miura , Yoshinobu Kanemura , Katsuyoshi Sasagawa
IPC分类号： G02B1/04 , B29C39/02 , B29K75/00 , B29K105/32 , B29L11/00 , C08G18/00 , C08G18/34 , C08G18/38 , C08G18/77 , C08L75/00
CPC分类号： C08G18/3876 , C08G18/34 , C08G18/775
摘要： A process for producing a plastic lens having a high refractive index and profile regularity which includes forming a mixture of one or more of sulfur-containing aromatic polyisocyanate compounds, one or more of active hydrogen compounds selected from the group consisting of polyol compounds and polythiol compounds, and at least one internal mold releasing agent. Then subjecting the resulting mixture to casting polymerization, to form the plastic lens.
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10.发明授权Polyurethane base lens resin, plastic lens comprising the resin and preparation method of the lens 失效聚氨酯基础透镜树脂，包含树脂的塑料透镜和透镜的制备方法
公开(公告)号：US4929707A
公开(公告)日：1990-05-29
申请号：US305905
申请日：1989-02-03
申请人： Teruyuki Nagata , Koju Okazaki , Nobuyuki Kajimoto , Tohru Miura , Yoshinobu Kanemura , Katsuyoshi Sasagawa
发明人： Teruyuki Nagata , Koju Okazaki , Nobuyuki Kajimoto , Tohru Miura , Yoshinobu Kanemura , Katsuyoshi Sasagawa
IPC分类号： B29C33/60 , B29C39/02 , B29K75/00 , B29K105/32 , B29L11/00 , C08G18/30 , C08G18/32 , C08G18/38 , C08G18/77 , G02B1/04
CPC分类号： C08G18/775 , B29C33/60 , C08G18/3863 , G02B1/041 , B29K2075/00 , B29L2011/0016
摘要： Polyurethane base lens resins obtained by reacting one or more of sulfur-containing polyisocyanates compound with one or more of sulfur-containing polyols, and polyurethane base lenses comprising these resins are disclosed.A method for preparing polyurethane base lenses which comprises adding internal mold releasing agents to the mixture of the above polyisocyanates and polyols prior to casting polymerization is also disclosed.
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