公开(公告)号：US09567414B2

公开(公告)日：2017-02-14

申请号：US13982166

申请日：2012-01-30

申请人： Kozo Nogi ,  Masatoshi Nakamura ,  Hirofumi Shibata ,  Koji Honda ,  Yusuke Watanabe ,  Satoshi Matsumoto ,  Reiko Nakatsuru ,  Kunihiko Ishizaki ,  Kazuki Kimura ,  Sayaka Machida

发明人： Kozo Nogi ,  Masatoshi Nakamura ,  Hirofumi Shibata ,  Koji Honda ,  Yusuke Watanabe ,  Satoshi Matsumoto ,  Reiko Nakatsuru ,  Kunihiko Ishizaki ,  Kazuki Kimura ,  Sayaka Machida

IPC分类号： C08F20/06 ,  C08F220/06 ,  C08J3/12 ,  C09D133/04 ,  C08J3/24

CPC分类号： C08F20/06 ,  C08F220/06 ,  C08J3/12 ,  C08J3/24 ,  C08J3/245 ,  C08J2333/02 ,  C09D133/04 ,  C08F2222/1013

摘要： From a view point of reduction in an out of spec product after surface crosslinking, particularly, when an alkylene carbonate compound is used as a surface crosslinking agent, influence by an air temperature is great, and it is necessary to reduce ethylene glycol which is produced as a byproduct, and there is provided a process for producing a polyacrylic acid (salt)-based water absorbent resin powder, comprising a step of polymerizing an aqueous acrylic acid (salt)-based monomer solution, a step of drying the resulting polymer, an optional grinding•classifying step, and a surface crosslinking step, wherein in the surface crosslinking step, (1) a surface crosslinking agent containing an alkylene carbonate compound and a polyhydric alcohol compound is mixed into a water absorbent resin powder, the mixture is heat-reacted and, further, simultaneously with, or separately from the mixing, an ion reactive surface crosslinking agent is mixed, and/or (2) mixing treatment of mixing a surface crosslinking agent solution into a water absorbent resin powder containing at least one or more kinds of ion reactive surface crosslinking agents is performed two or more times.

摘要翻译： 从表面交联后的特定产品的减少的观点来看，特别是使用碳酸亚烷基酯化合物作为表面交联剂时，由于空气温度的影响大，所以需要还原所生成的乙二醇 作为副产物，并且提供了一种制备基于聚丙烯酸（盐）的吸水性树脂粉末的方法，包括使基于丙烯酸（盐）的单体水溶液聚合的步骤，干燥所得聚合物的步骤， 任选的研磨分级步骤和表面交联步骤，其中在表面交联步骤中，（1）将含有碳酸亚烃酯化合物和多元醇化合物的表面交联剂混合到吸水性树脂粉末中，将混合物加热 和/或（2）混合表面的混合处理，和/或（2）混合表面的混合处理 交联剂溶液进入含有至少一种或多种离子反应性表面交联剂的吸水性树脂粉末中进行两次或更多次。

公开(公告)号：US20140031473A1

公开(公告)日：2014-01-30

申请号：US13982166

申请日：2012-01-30

申请人： Kozo Nogi ,  Masatoshi Nakamura ,  Hirofumi Shibata ,  Koji Honda ,  Yusuke Watanabe ,  Satoshi Matsumoto ,  Reiko Nakatsuru ,  Kunihiko Ishizaki ,  Kazuki Kimura ,  Sayaka Machida

发明人： Kozo Nogi ,  Masatoshi Nakamura ,  Hirofumi Shibata ,  Koji Honda ,  Yusuke Watanabe ,  Satoshi Matsumoto ,  Reiko Nakatsuru ,  Kunihiko Ishizaki ,  Kazuki Kimura ,  Sayaka Machida

IPC分类号： C08F20/06

CPC分类号： C08F20/06 ,  C08F220/06 ,  C08J3/12 ,  C08J3/24 ,  C08J3/245 ,  C08J2333/02 ,  C09D133/04 ,  C08F2222/1013

摘要： From a viewpoint of reduction in an out of spec product after surface crosslinking, particularly, when an alkylene carbonate compound is used as a surface crosslinking agent, influence by an air temperature is great, and it is necessary to reduce ethylene glycol which is produced as a byproduct, and there is provided a process for producing a polyacrylic acid (salt)-based water absorbent resin powder, comprising a step of polymerizing an aqueous acrylic acid (salt)-based monomer solution, a step of drying the resulting polymer, an optional grinding•classifying step, and a surface crosslinking step, wherein in the surface crosslinking step, (1) a surface crosslinking agent containing an alkylene carbonate compound and a polyhydric alcohol compound is mixed into a water absorbent resin powder, the mixture is heat-reacted and, further, simultaneously with, or separately from the mixing, an ion reactive surface crosslinking agent is mixed, and/or (2) mixing treatment of mixing a surface crosslinking agent solution into a water absorbent resin powder containing at least one or more kinds of ion reactive surface crosslinking agents is performed two or more times.

摘要翻译： 从表面交联后的特定产品的减少的观点出发，特别是使用碳酸亚烷基酯化合物作为表面交联剂时，空气温度的影响大，需要将生成的乙二醇 副产物，并且提供了一种生产聚丙烯酸（盐）基吸水性树脂粉末的方法，包括使基于丙烯酸（盐）的单体水溶液聚合的步骤，干燥所得聚合物的步骤， 任选的研磨分级步骤和表面交联步骤，其中在表面交联步骤中，（1）将含有碳酸亚烃酯化合物和多元醇化合物的表面交联剂混合到吸水性树脂粉末中， 与混合反应，进一步，同时或分开地混合，离子反应性表面交联剂混合，和/或（2）混合处理混合表面cr 将含有至少一种以上离子反应性表面交联剂的吸水性树脂粉末中的脱硫剂溶液进行两次以上。

公开(公告)号：US08247491B2

公开(公告)日：2012-08-21

申请号：US10544348

申请日：2004-02-06

申请人： Kazushi Torii ,  Yoshiro Mitsukami ,  Motohiro Imura ,  Taku Iwamura ,  Toshimasa Kitayama ,  Kenji Kadonaga ,  Hiroki Inoue ,  Koji Miyake ,  Kozo Nogi ,  Masatoshi Nakamura ,  Shigeru Sakamoto ,  Sayaka Machida

发明人： Kazushi Torii ,  Yoshiro Mitsukami ,  Motohiro Imura ,  Taku Iwamura ,  Toshimasa Kitayama ,  Kenji Kadonaga ,  Hiroki Inoue ,  Koji Miyake ,  Kozo Nogi ,  Masatoshi Nakamura ,  Shigeru Sakamoto ,  Sayaka Machida

IPC分类号： C08L33/02 ,  C08L31/00 ,  C08L29/04 ,  C08F20/06 ,  C08K3/22

CPC分类号： A61L15/60

摘要： There are disclosed a water-absorbent resin composition and its production process, wherein the water-absorbent resin composition causes little gel-blocking and is excellent in the liquid permeability and liquid diffusibility and is high also in the absorption performances and further is strong also against the physical damage; and there are further disclosed a water-absorbent resin composition and its production process, wherein the water-absorbent resin composition has the following further advantages, in addition to the above, of involving little segregation of the metal compound and further having a dust prevention effect. One of water-absorbent resin compositions according to the present invention is a water-absorbent resin composition comprising water-absorbent resin particles obtained by polymerizing a monomer including acrylic acid and/or its salt, with the composition having a mass-average particle diameter of 100 to 600 μm and comprising water-soluble polyvalent metal salt particles and the water-absorbent resin particles that have been surface-crosslinked.

摘要翻译： 公开了吸水性树脂组合物及其制造方法，其中吸水性树脂组合物几乎没有凝胶阻塞，并且液体渗透性和液体扩散性优异，并且吸收性能也高，并且还强 物理伤害; 并且还公开了一种吸水性树脂组合物及其制造方法，其中除了上述之外，吸水性树脂组合物具有以下进一步的优点，即涉及金属化合物几乎不偏析并且还具有防尘效果 。 根据本发明的吸水性树脂组合物之一是吸收性树脂组合物，其包含通过使包含丙烯酸和/或其盐的单体聚合而获得的吸水性树脂颗粒，其组成物的质量平均粒径为 100〜600μm，并且包含水溶性多价金属盐颗粒和表面交联的吸水性树脂颗粒。

公开(公告)号：US09447203B2

公开(公告)日：2016-09-20

申请号：US13639082

申请日：2011-04-07

申请人： Sayaka Machida ,  Kazushi Torii ,  Yoko Shirai ,  Hiroyuki Ikeuchi ,  Shigeru Sakamoto ,  Koji Tachi ,  Reiko Nakatsuru

发明人： Sayaka Machida ,  Kazushi Torii ,  Yoko Shirai ,  Hiroyuki Ikeuchi ,  Shigeru Sakamoto ,  Koji Tachi ,  Reiko Nakatsuru

IPC分类号： B01J20/26 ,  C08F6/00 ,  C08F220/06 ,  C08J3/24 ,  B29B9/06 ,  B29C47/00 ,  B29C47/38 ,  C08F222/10 ,  B29C47/30 ,  B29C47/66 ,  B29C47/92 ,  B29B9/16

CPC分类号： B01J20/267 ,  B01J20/28004 ,  B01J20/28016 ,  B01J20/3007 ,  B01J20/3021 ,  B01J20/3078 ,  B01J20/3085 ,  B29B9/06 ,  B29B2009/161 ,  B29C47/0011 ,  B29C47/30 ,  B29C47/385 ,  B29C47/667 ,  B29C47/92 ,  B29C2947/9259 ,  B29C2947/92704 ,  C08F6/008 ,  C08F220/06 ,  C08F220/20 ,  C08F222/1006 ,  C08J3/245 ,  C08J2333/02 ,  Y10T428/2982 ,  C08L33/02

摘要： An object of the present invention is to provide a method for producing water absorbent resin powder in which permeability potential (SFC) is improved while a water absorbing rate (FSR) is being kept. The method is a method for producing water absorbent polyacrylic acid (salt) resin powder including the steps of: (i) polymerizing an acrylic acid (salt) monomer aqueous solution; (ii) during or after the step of (i), performing gel grinding of a hydrogel crosslinked polymer obtained by the polymerization, wherein the hydrogel crosslinked polymer has resin solid content of 10 wt % to 80 wt %, and the gel grinding is carried out with gel grinding energy (GGE) of 18 [J/g] to 60 [J/g]; (iii) drying a particulate hydrogel crosslinked polymer obtained by the gel grinding, wherein the drying is performed at 150° C. to 250° C.; and (iv) carrying out a surface treatment to the particulate hydrogel crosslinked polymer thus dried.

摘要翻译： 本发明的目的是提供一种吸水性树脂粉末的制造方法，其中在保持吸水率（FSR）的同时提高渗透率（SFC）。 该方法是生产吸水性聚丙烯酸（盐）树脂粉末的方法，包括以下步骤：（i）使丙烯酸（盐）单体水溶液聚合; （ii）在（i）的步骤期间或之后，进行通过聚合获得的水凝胶交联聚合物的凝胶研磨，其中所述水凝胶交联聚合物的树脂固含量为10重量％至80重量％，并且进行凝胶研磨 （GGE）为18 [J / g]至60 [J / g]; （iii）干燥通过凝胶研磨获得的颗粒状水凝胶交联聚合物，其中干燥在150℃至250℃下进行; 和（iv）对由此干燥的颗粒状水凝胶交联聚合物进行表面处理。

公开(公告)号：US20130026412A1

公开(公告)日：2013-01-31

申请号：US13639082

申请日：2011-04-07

申请人： Sayaka Machida ,  Kazushi Torii ,  Yoko Shirai ,  Hiroyuki Ikeuchi ,  Shigeru Sakamoto ,  Koji Tachi ,  Reiko Nakatsuru

发明人： Sayaka Machida ,  Kazushi Torii ,  Yoko Shirai ,  Hiroyuki Ikeuchi ,  Shigeru Sakamoto ,  Koji Tachi ,  Reiko Nakatsuru

IPC分类号： B01J20/26 ,  C08F222/20

CPC分类号： B01J20/267 ,  B01J20/28004 ,  B01J20/28016 ,  B01J20/3007 ,  B01J20/3021 ,  B01J20/3078 ,  B01J20/3085 ,  B29B9/06 ,  B29B2009/161 ,  B29C47/0011 ,  B29C47/30 ,  B29C47/385 ,  B29C47/667 ,  B29C47/92 ,  B29C2947/9259 ,  B29C2947/92704 ,  C08F6/008 ,  C08F220/06 ,  C08F220/20 ,  C08F222/1006 ,  C08J3/245 ,  C08J2333/02 ,  Y10T428/2982 ,  C08L33/02

摘要： An object of the present invention is to provide a method for producing water absorbent resin powder in which permeability potential (SFC) is improved while a water absorbing rate (FSR) is being kept. The method is a method for producing water absorbent polyacrylic acid (salt) resin powder including the steps of: (i) polymerizing an acrylic acid (salt) monomer aqueous solution; (ii) during or after the step of (i), performing gel grinding of a hydrogel crosslinked polymer obtained by the polymerization, wherein the hydrogel crosslinked polymer has resin solid content of 10 wt % to 80 wt %, and the gel grinding is carried out with gel grinding energy (GGE) of 18 [J/g] to 60 [J/g]; (iii) drying a particulate hydrogel crosslinked polymer obtained by the gel grinding, wherein the drying is performed at 150° C. to 250° C.; and (iv) carrying out a surface treatment to the particulate hydrogel crosslinked polymer thus dried.

摘要翻译： 本发明的目的是提供一种吸水性树脂粉末的制造方法，其中在保持吸水率（FSR）的同时提高渗透率（SFC）。 该方法是生产吸水性聚丙烯酸（盐）树脂粉末的方法，包括以下步骤：（i）使丙烯酸（盐）单体水溶液聚合; （ii）在（i）的步骤期间或之后，进行通过聚合获得的水凝胶交联聚合物的凝胶研磨，其中所述水凝胶交联聚合物的树脂固含量为10重量％至80重量％，并且进行凝胶研磨 （GGE）为18 [J / g]至60 [J / g]; （iii）干燥通过凝胶研磨获得的颗粒状水凝胶交联聚合物，其中干燥在150℃至250℃下进行; 和（iv）对由此干燥的颗粒状水凝胶交联聚合物进行表面处理。

公开(公告)号：US20120220745A1

公开(公告)日：2012-08-30

申请号：US13496440

申请日：2010-09-16

申请人： Sayaka Machida ,  Kazushi Torii ,  Yoko Shirai ,  Hiroyuki Ikeuchi ,  Kunihiko Ishizaki

发明人： Sayaka Machida ,  Kazushi Torii ,  Yoko Shirai ,  Hiroyuki Ikeuchi ,  Kunihiko Ishizaki

IPC分类号： C08F20/06

CPC分类号： C08J3/28 ,  C08F220/06 ,  C08F222/1006 ,  C08J3/122 ,  C08J3/245 ,  C08J2300/00

摘要： [PROBLEM]It is an object of the present invention to enhance and stabilize properties of a water-absorbing resin, for example, damage resistance or water-absorbing speed, by a simple and convenient method without requiring change of raw materials or expensive facility investment, in a large scale production method for the water-absorbing resin.[MEANS FOR SOLVING THE PROBLEM]It is solved by circulation of the water-absorbing resin in a predetermined amount or more in the pulverization step before the surface cross-linking step. That is, at least a part of the classified polymer is supplied again to the same or different pulverization step, before the surface cross-linking step, wherein circulation pulverization ratio in the pulverization step, represented by the following equation is larger than 1.50: (Circulation pulverization ratio)=(total supply amount of the water-absorbing resin to the pulverization step)/(total discharge amount of the water-absorbing resin at the drying step) (wherein total supply amount of the water-absorbing resin to the pulverization step)=(total discharge amount of the water-absorbing resin at the drying step)+(amount of the classified polymer supplied again to the same or different pulverization step)).

摘要翻译： 本发明的目的是通过简单方便的方法来增强和稳定吸水树脂的性能，例如耐损伤性或吸水速度，而不需要改变原料或昂贵的设备投资 在大量的吸水树脂的制造方法中。 解决问题的手段通过在表面交联工序之前的粉碎工序中使吸水性树脂循环一定量以上来解决。 也就是说，在表面交联步骤之前，将分类的聚合物的至少一部分再次供给到相同或不同的粉碎步骤，其中由下式表示的粉碎步骤中的循环粉碎比大于1.50：（ 循环粉碎比）=（粉碎步骤中的吸水性树脂的总供给量）/（干燥工序中的吸水性树脂的总排出量）（其中，吸水性树脂与粉碎的总供给量 步骤）=（干燥步骤中的吸水性树脂的总排出量）+（再次供给相同或不同的粉碎步骤的分类聚合物的量））。

公开(公告)号：US20090305884A1

公开(公告)日：2009-12-10

申请号：US12296808

申请日：2007-09-28

申请人： Shigeru Sakamoto ,  Yoshio Irie ,  Hiroyuki Ikeuchi ,  Makoto Nagasawa ,  Kunihiko Ishizaki ,  Sayaka Machida

发明人： Shigeru Sakamoto ,  Yoshio Irie ,  Hiroyuki Ikeuchi ,  Makoto Nagasawa ,  Kunihiko Ishizaki ,  Sayaka Machida

IPC分类号： B01J20/26

CPC分类号： C08J3/12 ,  B29B9/06 ,  B29B17/00 ,  C08J2300/14 ,  Y02W30/62

摘要： The present invention provides a method for producing a water absorbent resin particle, in high productivity, not only in a controlled manner of particle size but also enhancing fundamental property (absorption capacity or absorption capacity against pressure) of a water absorbent resin. A method for producing a water absorbent resin particle having the cross-linking polymerization step for an aqueous solution of an unsaturated monomer; the grain refining step for water-swellable, water-containing gel-like cross-linked polymer (a) obtained in the cross-linking polymerization step; the drying step for grain refined gel; and the crushing step for a dried substance, wherein, in the grain refining step for the water-swellable, water-containing gel-like cross-linked polymer (a), water-swellable, water-containing gel-like cross-linked polymer (b), having solid content or centrifuge retention capacity different from solid content or centrifuge retention capacity of the cross-linked polymer (a) by equal to or larger than 1%, is subjected to coexistence.

摘要翻译： 本发明提供了一种生产吸水性树脂颗粒的方法，不仅以受控的粒度控制，而且提高了吸水性树脂的基本性能（吸收能力或抗吸收能力）。 一种制备具有用于不饱和单体的水溶液的交联聚合步骤的吸水性树脂颗粒的方法; 在交联聚合步骤中获得的水溶胀性含水凝胶状交联聚合物（a）的晶粒细化步骤; 颗粒精制凝胶的干燥步骤; 和干物质的破碎步骤，其中在水溶胀性含水凝胶状交联聚合物（a）的晶粒细化工序中，水溶胀性含水凝胶状交联聚合物 （b）具有不同于交联聚合物（a）的固体含量或离心保留能力等于或大于1％的固体含量或离心保留能力共存。

公开(公告)号：US08513378B2

公开(公告)日：2013-08-20

申请号：US13496440

申请日：2010-09-16

申请人： Sayaka Machida ,  Kazushi Torii ,  Yoko Shirai ,  Hiroyuki Ikeuchi ,  Kunihiko Ishizaki

发明人： Sayaka Machida ,  Kazushi Torii ,  Yoko Shirai ,  Hiroyuki Ikeuchi ,  Kunihiko Ishizaki

IPC分类号： C08G64/00 ,  C08G63/02

CPC分类号： C08J3/28 ,  C08F220/06 ,  C08F222/1006 ,  C08J3/122 ,  C08J3/245 ,  C08J2300/00

摘要： The present invention provides a method for producing a water-absorbing resin powder. The method includes a polymerization step, a drying step, a pulverization step, a classification step, and a surface cross-linking step. It further includes an additional step, performed before the surface cross-linking step, in which at least part of the classified polymer is supplied again to the same or a different pulverization step. The circulation pulverization ratio in the pulverization step is higher than 1.50.

摘要翻译： 本发明提供一种吸水性树脂粉末的制造方法。 该方法包括聚合步骤，干燥步骤，粉碎步骤，分级步骤和表面交联步骤。 其还包括在表面交联步骤之前进行的另外的步骤，其中将至少部分分类的聚合物再次供应到相同或不同的粉碎步骤。 粉碎步骤中的循环粉碎比高于1.50。

公开(公告)号：US09593212B2

公开(公告)日：2017-03-14

申请号：US12296808

申请日：2007-09-28

申请人： Shigeru Sakamoto ,  Yoshio Irie ,  Hiroyuki Ikeuchi ,  Makoto Nagasawa ,  Kunihiko Ishizaki ,  Sayaka Machida

发明人： Shigeru Sakamoto ,  Yoshio Irie ,  Hiroyuki Ikeuchi ,  Makoto Nagasawa ,  Kunihiko Ishizaki ,  Sayaka Machida

IPC分类号： C08J3/12 ,  B29B17/00

CPC分类号： C08J3/12 ,  B29B9/06 ,  B29B17/00 ,  C08J2300/14 ,  Y02W30/62

摘要： The present invention provides a method for producing a water absorbent resin particle, in high productivity, not only in a controlled manner of particle size but also enhancing fundamental property (absorption capacity or absorption capacity against pressure) of a water absorbent resin. A method for producing a water absorbent resin particle having the cross-linking polymerization step for an aqueous solution of an unsaturated monomer; the grain refining step for water-swellable, water-containing gel-like cross-linked polymer (a) obtained in the cross-linking polymerization step; the drying step for grain refined gel; and the crushing step for a dried substance, wherein, in the grain refining step for the water-swellable, water-containing gel-like cross-linked polymer (a), water-swellable, water-containing gel-like cross-linked polymer (b), having solid content or centrifuge retention capacity different from solid content or centrifuge retention capacity of the cross-linked polymer (a) by equal to or larger than 1%, is subjected to coexistence.

摘要翻译： 本发明提供了一种生产吸水性树脂颗粒的方法，不仅以受控的粒度控制，而且提高了吸水性树脂的基本性能（吸收能力或抗吸收能力）。 一种制备具有用于不饱和单体的水溶液的交联聚合步骤的吸水性树脂颗粒的方法; 在交联聚合步骤中获得的水溶胀性含水凝胶状交联聚合物（a）的晶粒细化步骤; 颗粒精制凝胶的干燥步骤; 和干物质的破碎步骤，其中在水溶胀性含水凝胶状交联聚合物（a）的晶粒细化工序中，水溶胀性含水凝胶状交联聚合物 （b）具有不同于交联聚合物（a）的固体含量或离心保留能力等于或大于1％的固体含量或离心保留能力共存。

公开(公告)号：US20120220733A1

公开(公告)日：2012-08-30

申请号：US13395912

申请日：2010-09-16

申请人： Sayaka Machida ,  Kazushi Torii ,  Yoko Shirai ,  Hiroyuki Ikeuchi ,  Kunihiko Ishizaki

发明人： Sayaka Machida ,  Kazushi Torii ,  Yoko Shirai ,  Hiroyuki Ikeuchi ,  Kunihiko Ishizaki

IPC分类号： C08F120/06 ,  C08F2/10 ,  C08F6/12

CPC分类号： C08J3/28 ,  C08F220/06 ,  C08F222/1006 ,  C08J3/122 ,  C08J3/245 ,  C08J2300/00

摘要： [PROBLEM]It is an object of the present invention to enhance and stabilize properties of a water-absorbing resin, for example, damage resistance or water-absorbing speed, by a simple and convenient method without requiring change of raw materials or expensive facility investment, in a large scale production method for the water-absorbing resin.[MEANS FOR SOLVING THE PROBLEM]It is solved by circulation of the water-absorbing resin in a predetermined amount or more in the pulverization step before the surface cross-linking step. That is, at least a part of the classified polymer is supplied again to the same or different pulverization step, before the surface cross-linking step, wherein circulation pulverization ratio in the pulverization step, represented by the following equation is 1.10 to 1.50: (Circulation pulverization ratio)=(total supply amount of the water-absorbing resin to the pulverization step)/(total discharge amount of the water-absorbing resin at the drying step) (wherein total supply amount of the water-absorbing resin to the pulverization step)=(total discharge amount of the water-absorbing resin at the drying step)+(amount of the classified polymer supplied again to the same or different pulverization step)).

摘要翻译： 本发明的目的是通过简单方便的方法来增强和稳定吸水树脂的性能，例如耐损伤性或吸水速度，而不需要改变原料或昂贵的设备投资 在大量的吸水树脂的制造方法中。 解决问题的手段通过在表面交联工序之前的粉碎工序中使吸水性树脂循环一定量以上来解决。 也就是说，在表面交联步骤之前，将分类的聚合物的至少一部分再次供给到相同或不同的粉碎步骤，其中由下式表示的粉碎步骤中的循环粉碎比为1.10至1.50：（ 循环粉碎比）=（粉碎步骤中的吸水性树脂的总供给量）/（干燥工序中的吸水性树脂的总排出量）（其中，吸水性树脂与粉碎的总供给量 步骤）=（干燥步骤中的吸水性树脂的总排出量）+（再次供给相同或不同的粉碎步骤的分类聚合物的量））。