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公开(公告)号：US08673277B2
公开(公告)日：2014-03-18
申请号：US13809245
申请日：2011-07-07
申请人： Krishnan Tamareselvy , Deborah S. Filla , Steven J. Smith , David L. Dashiell , Gary Gray , Yi Yang , John J. Mullay
发明人： Krishnan Tamareselvy , Deborah S. Filla , Steven J. Smith , David L. Dashiell , Gary Gray , Yi Yang , John J. Mullay
IPC分类号： C08L33/14
CPC分类号： C08L33/14 , A61K8/025 , A61K8/8141 , A61K2800/28 , A61K2800/48 , A61K2800/654 , A61Q1/12 , A61Q19/10 , C08F265/06 , C08F285/00 , Y10T428/31909 , Y10T428/31928 , C08F2/22
摘要： Disclosed are multi-staged acrylic based core-shell polymers comprising a linear core polymer and at least one subsequently polymerized shell polymers is crosslinked. The core-shell polymers surprisingly provide desirable rheological, clarity, and aesthetic properties in aqueous surfactant containing compositions, particularly at low pH.
摘要翻译： 公开了包含线性芯聚合物和至少一种随后聚合的壳聚合物的多阶段丙烯酸类核 - 壳聚合物是交联的。 核 - 壳聚合物令人惊讶地在含水表面活性剂组合物中提供所需的流变学，透明度和美学性能，特别是在低pH下。
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公开(公告)号：US20130115185A1
公开(公告)日：2013-05-09
申请号：US13809245
申请日：2011-07-07
申请人： Krishnan Tamareselvy , Deborah S. Filla , Steven J. Smith , David L. Dashiell , Gary Gray , Yi Yang , John J. Mullay
发明人： Krishnan Tamareselvy , Deborah S. Filla , Steven J. Smith , David L. Dashiell , Gary Gray , Yi Yang , John J. Mullay
IPC分类号： C08L33/14
CPC分类号： C08L33/14 , A61K8/025 , A61K8/8141 , A61K2800/28 , A61K2800/48 , A61K2800/654 , A61Q1/12 , A61Q19/10 , C08F265/06 , C08F285/00 , Y10T428/31909 , Y10T428/31928 , C08F2/22
摘要： Disclosed are multi-staged acrylic based core-shell polymers comprising a linear core polymer and at least one subsequently polymerized shell polymers is crosslinked. The core-shell polymers surprisingly provide desirable rheological, clarity, and aesthetic properties in aqueous surfactant containing compositions, particularly at low pH.
摘要翻译： 公开了包含线性芯聚合物和至少一种随后聚合的壳聚合物的多阶段丙烯酸类核 - 壳聚合物是交联的。 核 - 壳聚合物令人惊讶地在含水表面活性剂组合物中提供所需的流变学，透明度和美学性能，特别是在低pH下。
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公开(公告)号：US20130183361A1
公开(公告)日：2013-07-18
申请号：US13876007
申请日：2011-09-30
IPC分类号： A61K8/02 , D06M15/263 , A61Q19/10 , A61Q5/12 , C11D17/00
CPC分类号： A61K8/0245 , A61K8/8152 , A61K2800/262 , A61K2800/654 , A61Q5/02 , A61Q5/12 , A61Q19/10 , C08F265/06 , C09D133/14 , C11D3/3765 , C11D3/3773 , C11D17/0017 , C11D17/0039 , D06M15/263
摘要： Disclosed are multi-staged acrylic based core-shell polymers comprising a linear core polymer and at least one subsequently polymerized shell polymer. At least one of the subsequently polymerized shell polymers is crosslinked. The core-shell polymers surprisingly provide desirable rheological, clarity, and aesthetic properties in aqueous surfactant containing compositions, particularly at low pH. The multi-staged acrylic base core-shell polymers can be included in at least one phase of a multi-phase personal care, home care, health care, and institutional and industrial care composition to impart phase stability thereto.
摘要翻译： 公开了包含线性芯聚合物和至少一种随后聚合的壳聚合物的多阶段丙烯酸类核 - 壳聚合物。 至少一种随后聚合的壳聚合物是交联的。 核 - 壳聚合物令人惊讶地在含水表面活性剂组合物中提供所需的流变学，透明度和美学性能，特别是在低pH下。 多阶段丙烯酸类核 - 壳聚合物可以包括在多相个人护理，家庭护理，保健和机构和工业护理组合物的至少一个阶段中，以赋予相位稳定性。
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公开(公告)号：US08293845B2
公开(公告)日：2012-10-23
申请号：US11937671
申请日：2007-11-09
IPC分类号： C08F220/06 , C08F8/44
CPC分类号： C11D3/3765 , C08F8/44 , C08F265/04 , C08F290/062 , C08L51/003 , C08F22/02 , C08F20/06 , C08L2666/02
摘要： A method for increasing the efficacy of hydrophobically modified (meth)acrylic based polymers to increase the critical micelle concentration of a surfactant composition by attenuating the degree of neutralization (DN) of the polymer is disclosed.
摘要翻译： 公开了一种通过减弱聚合物的中和度（DN）来提高疏水改性的（甲基）丙烯酸类聚合物的功效以增加表面活性剂组合物的临界胶束浓度的方法。
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公开(公告)号：US20080113895A1
公开(公告)日：2008-05-15
申请号：US11937671
申请日：2007-11-09
IPC分类号： C11D3/37 , C08F120/06 , C08F120/56
CPC分类号： C11D3/3765 , C08F8/44 , C08F265/04 , C08F290/062 , C08L51/003 , C08F22/02 , C08F20/06 , C08L2666/02
摘要： A method for increasing the efficacy of hydrophobically modified (meth)acrylic based polymers to increase the critical micelle concentration of a surfactant composition by attenuating the degree of neutralization (DN) of the polymer is disclosed.
摘要翻译： 公开了一种通过减弱聚合物的中和度（DN）来提高疏水改性的（甲基）丙烯酸类聚合物的功效以增加表面活性剂组合物的临界胶束浓度的方法。
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公开(公告)号：US20120316308A1
公开(公告)日：2012-12-13
申请号：US13513306
申请日：2010-12-01
IPC分类号： C08F220/34
CPC分类号： C08F220/34 , C08F216/1416 , C08F220/18 , C08F220/26 , C08F222/1006 , C08F230/08
摘要： The present invention relates to hydrolytically stable multi-purpose polymers that are polymerized from a monomer mixture comprising: at least one amino-substituted meth(acrylate) (ASMA) monomer or salt thereof; and at least one nonionic vinyl (NIV) monomer, wherein the monomer mixture optionally comprises one or more of at least one vinyl associative (VA) monomer; at least one vinyl surfactant (VS) monomer; and/or at least one polymerizable silicone macromer (PSM) and wherein the monomer mixture further optionally comprises one or more of at least one crosslinking (XL) monomer; at least one chain transfer agent (CTA); and/or at least one polymeric stabilizer. The multi-purpose polymers of the present invention can also be prepared from monomer mixtures containing chain transfer agents or other functional components commonly utilized in polymerization process.
摘要翻译： 本发明涉及由单体混合物聚合的水解稳定的多用途聚合物，所述单体混合物包含：至少一种氨基取代的（丙烯酸酯）（ASMA）单体或其盐; 和至少一种非离子乙烯基（NIV）单体，其中所述单体混合物任选地包含一种或多种至少一种乙烯基缔合（VA）单体; 至少一种乙烯基表面活性剂（VS）单体; 和/或至少一种可聚合硅氧烷大分子单体（PSM），并且其中所述单体混合物还任选地包含至少一种交联（XL）单体中的一种或多种; 至少一种链转移剂（CTA）; 和/或至少一种聚合物稳定剂。 本发明的多用途聚合物也可以由含有链转移剂或通常用于聚合过程的其它功能组分的单体混合物制备。
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公开(公告)号：US20120237465A1
公开(公告)日：2012-09-20
申请号：US13513299
申请日：2010-12-01
摘要： The present invention relates to compositions containing hydrolytically stable multi-purpose polymers that are polymerized from a monomer mixture comprising: at least one amino-substituted meth(acrylate) (ASMA) monomer or salt thereof; and at least one nonionic vinyl (NIV) monomer, wherein the monomer mixture optionally comprises one or more of at least one vinyl associative (VA) monomer; at least one vinyl surfactant (VS) monomer; and/or at least one polymerizable silicone macromer (PSM) and wherein the monomer mixture further optionally comprises one or more of at least one crosslinking (XL) monomer; at least one chain transfer agent (CTA); and/or at least one polymeric stabilizer. The multi-purpose polymers of the present invention can also be prepared from monomer mixtures containing chain transfer agents or other functional components commonly utilized in polymerization processes.
摘要翻译： 本发明涉及包含水解稳定的多用途聚合物的组合物，其由单体混合物聚合，所述单体混合物包含：至少一种氨基取代的（丙烯酸酯）（ASMA）单体或其盐; 和至少一种非离子乙烯基（NIV）单体，其中所述单体混合物任选地包含一种或多种至少一种乙烯基缔合（VA）单体; 至少一种乙烯基表面活性剂（VS）单体; 和/或至少一种可聚合硅氧烷大分子单体（PSM），并且其中所述单体混合物还任选地包含至少一种交联（XL）单体中的一种或多种; 至少一种链转移剂（CTA）; 和/或至少一种聚合物稳定剂。 本发明的多用途聚合物也可以由含有链转移剂或通常用于聚合方法的其它功能组分的单体混合物制备。
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公开(公告)号：US08044156B2
公开(公告)日：2011-10-25
申请号：US12125288
申请日：2008-05-22
申请人： Krishnan Tamareselvy , Thomas A. Barker , James E. Mullee , Charles T. Greenslade , Julie F. Schmucker-Castner , Deborah S. Filla
发明人： Krishnan Tamareselvy , Thomas A. Barker , James E. Mullee , Charles T. Greenslade , Julie F. Schmucker-Castner , Deborah S. Filla
IPC分类号： C08F122/38
CPC分类号： C08L53/00 , A61K8/8158 , A61K2800/5426 , A61Q5/06 , A61Q5/12 , C08F220/28 , C08F220/34 , C08F220/60 , C08F290/06 , C08F290/062 , C08F293/005 , C09D153/00 , C08L2666/02
摘要： Disclosed are multi-purpose polymers that are the polymerization product of a monomer mixture comprising at least one amino-substituted vinyl monomer; at least one nonionic vinyl monomer; at least one associative vinyl monomer; at least one semihydrophobic vinyl surfactant monomer; and, optionally, comprising one or more hydroxy-substituted nonionic vinyl monomer, crosslinking monomer, chain transfer agent or polymeric stabilizer. These vinyl addition polymers have a combination of substituents, including amino substituents that provide cationic properties at low pH, hydrophobic substituents, hydrophobically modified polyoxyalkylene substituents, and hydrophilic polyoxyalkylene substituents. The polymers provide surprisingly beneficial rheological properties in acidic aqueous compositions, and are compatible with cationic materials. The multi-purpose polymers are useful in a variety of products for personal care, health care, household care, institutional and industrial care, and industrial applications.
摘要翻译： 公开了作为包含至少一个氨基取代的乙烯基单体的单体混合物的聚合产物的多用途聚合物; 至少一种非离子型乙烯基单体; 至少一种缔合乙烯基单体; 至少一种半疏水乙烯基表面活性剂单体; 和任选地包含一种或多种羟基取代的非离子乙烯基单体，交联单体，链转移剂或聚合物稳定剂。 这些乙烯基加成聚合物具有取代基的组合，包括在低pH下提供阳离子性质的氨基取代基，疏水取代基，疏水改性聚氧化烯取代基和亲水性聚氧化烯取代基。 聚合物在酸性含水组合物中提供令人惊讶的有利的流变性能，并与阳离子材料相容。 多用途聚合物可用于个人护理，保健，家庭护理，机构和工业保健以及工业应用的各种产品。
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公开(公告)号：US07378479B2
公开(公告)日：2008-05-27
申请号：US10646856
申请日：2003-08-22
申请人： Krishnan Tamareselvy , Thomas A. Barker , James E. Mullee , Charles T. Greenslade , Julie F. Schmucker-Castner , Deborah S. Filla
发明人： Krishnan Tamareselvy , Thomas A. Barker , James E. Mullee , Charles T. Greenslade , Julie F. Schmucker-Castner , Deborah S. Filla
IPC分类号： C08F216/12 , C08F220/10 , C08F20/52
CPC分类号： C08L53/00 , A61K8/8158 , A61K2800/5426 , A61Q5/06 , A61Q5/12 , C08F220/28 , C08F220/34 , C08F220/60 , C08F290/06 , C08F290/062 , C08F293/005 , C09D153/00 , C08L2666/02
摘要： Disclosed are multi-purpose polymers that are the polymerization product of a monomer mixture comprising at least one amino-substituted vinyl monomer; at least one nonionic vinyl monomer; at least one associative vinyl monomer; at least one semihydrophobic vinyl surfactant monomer; and, optionally, comprising one or more hydroxy-substituted nonionic vinyl monomer, crosslinking monomer, chain transfer agent or polymeric stabilizer. These vinyl addition polymers have a combination of substituents, including amino substituents that provide cationic properties at low pH, hydrophobic substituents, hydrophobically modified polyoxyalkylene substituents, and hydrophilic polyoxyalkylene substituents. The polymers provide surprisingly beneficial rheological properties in acidic aqueous compositions, and are compatible with cationic materials. The multi-purpose polymers are useful in a variety of products for personal care, health care, household care, institutional and industrial care, and industrial applications.
摘要翻译： 公开了作为包含至少一个氨基取代的乙烯基单体的单体混合物的聚合产物的多用途聚合物; 至少一种非离子型乙烯基单体; 至少一种缔合乙烯基单体; 至少一种半疏水乙烯基表面活性剂单体; 和任选地包含一种或多种羟基取代的非离子乙烯基单体，交联单体，链转移剂或聚合物稳定剂。 这些乙烯基加成聚合物具有取代基的组合，包括在低pH下提供阳离子性质的氨基取代基，疏水取代基，疏水改性聚氧化烯取代基和亲水性聚氧化烯取代基。 聚合物在酸性含水组合物中提供令人惊讶的有利的流变性能，并与阳离子材料相容。 多用途聚合物可用于个人护理，保健，家庭护理，机构和工业保健以及工业应用的各种产品。
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公开(公告)号：US09187590B2
公开(公告)日：2015-11-17
申请号：US13513306
申请日：2010-12-01
IPC分类号： C08F12/28 , C08F220/44 , C08F2/00 , C08G61/02 , C08G61/04 , C08F297/02 , C08F8/00 , C08G63/48 , C08F220/34 , C08F220/18 , C08F216/14 , C08F220/26 , C08F222/10 , C08F230/08
CPC分类号： C08F220/34 , C08F216/1416 , C08F220/18 , C08F220/26 , C08F222/1006 , C08F230/08
摘要： The present invention relates to hydrolytically stable multi-purpose polymers that are polymerized from a monomer mixture comprising: at least one amino-substituted meth(acrylate) (ASMA) monomer or salt thereof; and at least one nonionic vinyl (NIV) monomer, wherein the monomer mixture optionally comprises one or more of at least one vinyl associative (VA) monomer; at least one vinyl surfactant (VS) monomer; and/or at least one polymerizable silicone macromer (PSM) and wherein the monomer mixture further optionally comprises one or more of at least one crosslinking (XL) monomer; at least one chain transfer agent (CTA); and/or at least one polymeric stabilizer. The multi-purpose polymers of the present invention can also be prepared from monomer mixtures containing chain transfer agents or other functional components commonly utilized in polymerization process.
摘要翻译： 本发明涉及由单体混合物聚合的水解稳定的多用途聚合物，所述单体混合物包含：至少一种氨基取代的（丙烯酸酯）（ASMA）单体或其盐; 和至少一种非离子乙烯基（NIV）单体，其中所述单体混合物任选地包含一种或多种至少一种乙烯基缔合（VA）单体; 至少一种乙烯基表面活性剂（VS）单体; 和/或至少一种可聚合硅氧烷大分子单体（PSM），并且其中所述单体混合物还任选地包含至少一种交联（XL）单体中的一种或多种; 至少一种链转移剂（CTA）; 和/或至少一种聚合物稳定剂。 本发明的多用途聚合物也可以由含有链转移剂或通常用于聚合过程的其它功能组分的单体混合物制备。
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