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公开(公告)号：US5508296A
公开(公告)日：1996-04-16
申请号：US190093
申请日：1994-01-31
申请人： Kunihiro Niigata , Takumi Takahashi , Takashi Yoneda , Osamu Noshiro , Reiko Koike , Akiyoshi Shimaya
发明人： Kunihiro Niigata , Takumi Takahashi , Takashi Yoneda , Osamu Noshiro , Reiko Koike , Akiyoshi Shimaya
IPC分类号： C07D263/44 , C07D277/20 , C07D277/34 , C07D277/36 , C07D493/04 , A61K31/42 , A61K31/425
CPC分类号： C07D263/44 , C07D277/20 , C07D277/34 , C07D493/04 , Y02P20/55
摘要： ##STR1## A bisheterocyclic compound represented by general formula (I), stereoisomers thereof, tautomers thereof, a pharmaceutically acceptable salt or a pharmaceutically acceptable solvate thereof, a pharmaceutical composition containing the same, and a process for the production thereof. In formula (I), R
1 and R
2 may be the same or different from each other and each represents (II) or (III), R
3 represents hydrogen or a protective group, X, Y
1 and Y
2 may be the same or different from one another and each represents oxygen or sulfur, B
1 and B
2 represent each phenylene, B
3 represents phenylene, naphthylene, cyclohexylene or furo[3,2-b]furanylene, L
1 and L
2 represent each --(O)
n --A--, n represents 0 or 1, and A represents a single bond or lower alkylene, provided that when n is 1, A represents alkylene and the oxygen atom of each of L
1 and L
2 is bonded to B
3 . The above compounds are useful as a hypoglycemic drug based on the activity of enhancing insulin sensitivity.摘要翻译： PCT No.PCT / JP92 / 00954 Sec。 371日期1994年1月31日 102（e）日期1994年1月31日PCT提交1992年7月28日PCT公布。 公开号WO93 / 03021 通式（I）其通式（I），其立体异构体，其互变异构体，其药学上可接受的盐或药学上可接受的溶剂化物，含有 相同，以及其生产方法。 在式（I）中，R 1和R 2可以相同或不同，各自表示（II）或（III），R 3表示氢或保护基，X，Y 1和Y 2可以相同或不同 另一个和每个代表氧或硫，B1和B2表示各亚苯基，B3表示亚苯基，亚萘基，亚环己基或呋喃并[3,2-b]呋喃，L1和L2表示 - （O）nA-，n表示0或1 A表示单键或低级亚烷基，条件是当n为1时，A表示亚烷基，L1和L2各自的氧原子与B3结合。 基于增强胰岛素敏感性的活性，上述化合物可用作降血糖药物。
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公开(公告)号：US08927219B2
公开(公告)日：2015-01-06
申请号：US12744064
申请日：2008-11-25
IPC分类号： G01N33/53 , G01N33/74 , G01N33/558 , G01N33/94
CPC分类号： G01N33/54366 , G01N33/558 , G01N33/9493
摘要： A method for evaluating the quality of a blood sample, comprising the steps of: mixing labeled anti-cortisol antibodies with a blood sample to be subjected, to conduct the antigen-antibody reaction of the labeled anti-cortisol antibody with cortisol contained in the blood sample, developing a mixture obtained in the above step on an immunochromatographic test strip having a substrate on which cortisol is immobilized to cause the antigen-antibody reaction of the labeled anti-cortisol antibodies which are free in the mixture with the cortisol immobilized on the substrate, thereby bonding the antibody to the cortisol, determining the amount of the labeled anti-cortisol antibodies bonded to the cortisol in the above step, and evaluating whether or not the blood sample has a quality suitable for suprarenal vein sampling test on the basis of the amount of the labeled anti-cortisol antibodies determined in the above step.
摘要翻译： 一种用于评估血液样品质量的方法，包括以下步骤：将标记的抗皮质醇抗体与待进行血液样品混合，进行标记的抗皮质醇抗体与血液中含有的皮质醇的抗原 - 抗体反应 样品，将在上述步骤中获得的混合物在具有固定有皮质醇的底物的免疫色谱试纸上培养，引起与固定在底物上的皮质醇混合物中游离的标记抗皮质醇抗体的抗原 - 抗体反应 从而将抗体结合到皮质醇上，确定在上述步骤中与皮质醇结合的标记的抗皮质醇抗体的量，并且基于上述步骤评估血液样品是否具有适合于肾上静脉取样试验的质量 在上述步骤中测定的标记的抗皮质醇抗体的量。
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3.发明授权Porphyrazine coloring matter, ink composition, recording method, and colored object 有权紫菜色素，油墨组成，记录方法和彩色物品公开(公告)号：US08657433B2
公开(公告)日：2014-02-25
申请号：US13377262
申请日：2010-06-08
申请人： Kenji Ooshima , Takashi Yoneda , Yasuo Kuroda , Akira Kawaguchi
发明人： Kenji Ooshima , Takashi Yoneda , Yasuo Kuroda , Akira Kawaguchi
IPC分类号： B41J2/01
CPC分类号： C09B67/0084 , C09B47/26 , C09D11/328
摘要： Provided is a porphyrazine dye suitable for use in ink-jet recording, the porphyrazine dye giving a cyan ink with a satisfactory hue, having various excellent fastness properties, in particular, ozone resistance, and attaining a high color density. Also provided is an ink composition containing the dye. The porphyrazine dye is a porphyrazine dye represented by formula (1) or a salt thereof. In formula (1), rings A to D each independently represents a benzene ring, a nitrogenous heteroaromatic ring, etc.; E represents an alkylene; X represents sulfoanilino, etc.; R represents a hydrogen atom, sulfo, carboxy, etc.; group F represents phenyl, a nitrogenous heteroaromatic ring, etc.; a is an integer of 1-6; b is 0.00-3.90, excluding 3.90, on average; c is 0.10-4.00, excluding 4.00, on average; and the sum of b and c is 1.00-4.00, excluding 4.00, on average.
摘要翻译： 本发明提供一种适用于喷墨记录的四氮杂卟啉染料，该四氮杂卟啉染料具有令人满意的色调，具有各种优异的牢度特性，特别是耐臭氧性，并获得高色密度的青色墨。 还提供含有该染料的油墨组合物。 四氮杂卟啉染料是由式（1）表示的四氮杂卟啉染料或其盐。 在式（1）中，环A至D各自独立地表示苯环，含氮杂芳环等; E表示亚烷基; X代表磺基苯胺基等。 R代表氢原子，磺基，羧基等; F组表示苯基，含氮杂芳环等; a为1-6的整数; b为0.00-3.90，平均不包括3.90; c为0.10-4.00，平均不包括4.00; b和c的总和平均为1.00-4.00，不包括4.00。
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公开(公告)号：US20120202019A1
公开(公告)日：2012-08-09
申请号：US13498431
申请日：2010-09-21
申请人： Takahiko Matsui , Takashi Yoshimoto , Hiroaki Ohno , Koji Hirota , Takashi Yoneda , Akira Kawaguchi
发明人： Takahiko Matsui , Takashi Yoshimoto , Hiroaki Ohno , Koji Hirota , Takashi Yoneda , Akira Kawaguchi
CPC分类号： C09B43/16 , C09D11/328 , Y10T428/24802
摘要： Azo compounds represented by general formula (1) or salts thereof are provided as highly water-soluble colorants which have hues of yellow, orange, brown or red, and excellent color development properties and which, when used in various recording processes, particularly in an inkjet recording process, ensure various excellent fastnesses such as light fastness, ozone fastness, and fading balance. Ink compositions containing the colorants are also provided. In general formula (1), R1 to R8 are each independently a hydrogen atom, C1-4 alkyl, C1-4 alkoxy, or the like; and X is C1-8 alkylenediamino, xylylenediamino, or the like.
摘要翻译： 提供由通式（1）表示的偶氮化合物或其盐作为具有黄色，橙色，棕色或红色色调的高度水溶性着色剂，并具有优异的显色性，并且当用于各种记录方法时，特别是在 喷墨记录工艺，确保耐光性，耐臭氧性和褪色平衡等各种优异的牢度。 还提供含有着色剂的油墨组合物。 在通式（1）中，R 1至R 8各自独立地为氢原子，C 1-4烷基，C 1-4烷氧基等; X是C 1-8亚烷基二氨基，亚二甲苯基二氨基等。
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5.发明申请PROCESSING SIMULATION METHOD AND APPARATUS, AND PROGRAM MAKING COMPUTER EXECUTE THE METHOD 审中-公开处理模拟方法和装置，程序计算机执行方法公开(公告)号：US20120016507A1
公开(公告)日：2012-01-19
申请号：US13259004
申请日：2009-05-20
IPC分类号： G05B13/04
CPC分类号： G05B19/4069 , G05B2219/49157
摘要： A processing simulation method and apparatus is provided, which can appropriately detect interference between a tool processing area and a shape model of a material without being affected by the accuracy of expression of a tool movement path and the shape model. A tool shape model for processing a material, that includes a strict tool shape, and a tool shape model for checking interference, that is included in the strict tool shape, are generated by tool model setting unit according to an error range set in consideration of the tool movement path and the expression accuracy of the shape model, and the processed material shape model is generated by generating a tool processing area shape model from the tool movement path during processing feed and the tool shape model for processing the material and removing the tool processing area shape model from the material shape model. The tool processing area shape model is generated from a tool movement path during fast feed and the tool shape model for detecting the interference, and the interference between the tool processing area shape model and the material shape model is detected.
摘要翻译： 提供一种处理模拟方法和装置，其可以适当地检测工具处理区域和材料的形状模型之间的干扰，而不受工具移动路径和形状模型的表达精度的影响。 由工具模型设定单元根据考虑到的设定的误差范围，生成包含在严格的工具形状中的用于处理材料的工具形状模型（包括严格的工具形状）和用于检查干涉的工具形状模型 通过在处理进给期间从工具移动路径生成工具处理区域形状模型和用于处理材料并移除工具的工具形状模型来生成工具移动路径和形状模型的表达精度以及加工材料形状模型 加工区域形状模型从材料形状模型。 刀具加工区域形状模型由快速进给期间的刀具运动路径和用于检测干涉的刀具形状模型产生，并且检测刀具加工区域形状模型与材料形状模型之间的干涉。
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6.发明申请公开(公告)号：US20120013678A1
公开(公告)日：2012-01-19
申请号：US13258124
申请日：2010-04-14
CPC分类号： C09B47/26 , B41M5/5218 , C09B47/064 , C09D11/328
摘要： The present invention relates to a porphyrazine coloring matter or a salt thereof represented by the following formula (1) [wherein, the rings of A to D are each independently a benzene ring or a 6-membered nitrogen-containing heteroaromatic ring, E is alkylene, X is a sulfo-substituted anilino group or the like which may further have a substituent, R1 is a C1-C6 alkyl group, b is 0.00 or more and less than 3.90 as an average value, c is 0.10 or more and less than 4.00 as an average value, and the sum of b and c is 1.00 or more and less than 4.00 as an average value]. The ink composition containing the porphyrazine coloring matter of the present invention has a good hue as a cyan ink, is excellent in various fastness properties, particularly in ozone fastness, allows a high print density, has properties hardly causing bronze phenomenon, and can provide a porphyrazine coloring matter suitable for inkjet recording and an ink composition containing this.
摘要翻译： 本发明涉及由下式（1）表示的四氮杂卟啉色素或其盐[其中，A至D的环各自独立地为苯环或6元含氮杂芳环，E为亚烷基 X为可以进一步具有取代基的磺基取代的苯胺基等，R 1为C 1〜C 6烷基，b为0.00以上且小于3.90，作为平均值，c为0.10以上且小于 4.00作为平均值，b和c之和为1.00以上且小于4.00作为平均值]。 含有本发明的四氮杂卟啉色素的油墨组合物作为青色油墨具有良好的色相，具有优异的各种牢度性能，特别是耐臭氧性，允许高印刷密度，具有几乎不引起青铜现象的性质，并且可以提供 适用于喷墨记录的四氮杂卟啉色素和含有它的油墨组合物。
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7.发明申请公开(公告)号：US20110242198A1
公开(公告)日：2011-10-06
申请号：US13139402
申请日：2009-12-22
申请人： Takashi Yoneda , Akira Kawaguchi
发明人： Takashi Yoneda , Akira Kawaguchi
CPC分类号： C09B47/26 , B41M5/0023 , B41M5/5218 , C09B47/00 , C09D11/328
摘要： The present invention relates to a porphyrazine coloring matter or a salt thereof represented by the following formula (1): [wherein, the rings A to D are independently a benzene ring or a nitrogen-containing heteroaromatic ring, the number of the nitrogen-containing heteroaromatic ring is more than 0.00 and less than 1.00 as an average value, the rest are benzene rings, E is alkylene, X and Y are a sulfo-substituted anilino group and the like, b is 0.00 or more and less than 3.90 as an average value, c is 0.10 or more and less than 4.00 as an average value, and the sum of b and c is more than 3.00 and less than 4.00 as an average value]. The ink composition containing the porphyrazine coloring matter of the present invention or a salt thereof is an ink composition which has a hue closer to the standard color as a cyan ink, is excellent in various fastnesses, particularly in ozone fastness, and can provide recorded images having a high print density and thus having a good balance, and further it is suitable for inkjet recording.
摘要翻译： 本发明涉及由下式（1）表示的四氮杂卟啉色素或其盐：其中环A至D独立地为苯环或含氮杂芳环，含氮 杂芳环的平均值大于0.00且小于1.00，其余为苯环，E为亚烷基，X和Y为磺基取代的苯胺基等，b为0.009以上且小于3.90 平均值c作为平均值为0.10以上且小于4.00，b和c的和大于3.00且小于4.00作为平均值]。 含有本发明的四氮杂卟啉色素的油墨组合物或其盐是具有作为青色油墨更接近标准颜色的色调的油墨组合物，其各种牢度，特别是耐臭氧性优异，并且可以提供记录图像 具有高的印刷密度，从而具有良好的平衡性，并且还适用于喷墨记录。
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8.发明授权公开(公告)号：US07901497B2
公开(公告)日：2011-03-08
申请号：US12734038
申请日：2008-10-30
CPC分类号： C09D11/328 , B41M3/14 , C09B47/16
摘要： The present invention relates to an aqueous solution composition (water-based ink composition) containing a water-soluble naphthalocyanine coloring matter represented by the following formula (1): wherein, M represents a hydrogen atom, a metal atom, a metal oxide, a metal hydroxide or a metal halide, X represents a carbonyl group or a sulfonyl group, W1 to W4 are each independently a hydrogen atom, an ionic hydrophilic group or the like, at least one of W1 to W4 is a group other than a hydrogen atom, and n represents an integer number of 1 to 24, respectively, or a salt thereof, and a novel naphthalocyanine coloring matter, and said compound is useful as a near-infrared ray absorbent because it has a high absorption in the near-infrared region, and it is useful as a near-infrared ray absorbing water-based ink because it has an excellent storage stability in aqueous solution.
摘要翻译： 本发明涉及含有下述式（1）表示的水溶性萘酞菁色素的水溶液组合物（水性油墨组合物）：其中，M表示氢原子，金属原子，金属氧化物， 金属氢氧化物或金属卤化物，X表示羰基或磺酰基，W1至W4各自独立地为氢原子，离子性亲水基等，W1至W4中的至少一个为氢原子以外的基团 ，n表示1〜24的整数或其盐，和新的萘酞菁色素，所述化合物可用作近红外线吸收剂，因为其在近红外区域具有高吸收 作为近红外线吸收水性油墨是有用的，因为它在水溶液中具有优异的储存稳定性。
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9.发明申请WATER-SOLUBLE NAPHTHALOCYANINE COLORING MATTER AND WATER- BASED INK CONTAINING THE SAME 有权水溶性萘二甲酰亚胺颜料和含有水的墨水公开(公告)号：US20100236448A1
公开(公告)日：2010-09-23
申请号：US12734038
申请日：2008-10-30
IPC分类号： C09D11/02 , C09B47/04 , C07D487/22
CPC分类号： C09D11/328 , B41M3/14 , C09B47/16
摘要： The present invention relates to an aqueous solution composition (water-based ink composition) containing a water-soluble naphthalocyanine coloring matter represented by the following formula (1): (wherein, M represents a hydrogen atom, a metal atom, a metal oxide, a metal hydroxide or a metal halide, X represents a carbonyl group or a sulfonyl group, W1 to W4 are each independently a hydrogen atom, an ionic hydrophilic group or the like, at least one of W1 to W4 is a group other than a hydrogen atom, and n represents an integer number of 1 to 24, respectively) or a salt thereof, and a novel naphthalocyanine coloring matter; and said compound is useful as a near-infrared ray absorbent because it has a high absorption in the near-infrared region, and it is useful as an near-infrared ray absorbing water-based ink because it has an excellent storage stability in aqueous solution.
摘要翻译： 本发明涉及含有下式（1）表示的水溶性萘酞菁色素的水溶液组合物（水性油墨组合物）：（其中，M表示氢原子，金属原子，金属氧化物， 金属氢氧化物或金属卤化物，X表示羰基或磺酰基，W1至W4各自独立地为氢原子，离子性亲水基等，W1至W4中的至少一个为氢以外的基团 原子，n分别为1〜24的整数）或其盐，和新的萘酞菁色素; 并且所述化合物由于在近红外区域具有高吸收性而可用作近红外线吸收剂，并且作为近红外线吸收水性油墨是有用的，因为它在水溶液中具有优异的储存稳定性 。
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公开(公告)号：US20090151599A1
公开(公告)日：2009-06-18
申请号：US12226043
申请日：2007-04-05
IPC分类号： C09B47/04 , C09B62/016 , C09D11/02 , B05D5/00
CPC分类号： C09B47/00 , C09B47/0675 , C09B47/0678 , C09B47/26 , C09D11/328 , C09D11/40
摘要： The present invention relates to a porphyrazine coloring matter represented by the following formula (1): (wherein, A, B, C and D independently represents a 6-membered ring having aromaticity, at least one or more is a benzene ring, at least one or more contains a nitrogen-containing heteroaromatic ring; in addition, E represents alkylene and each of X and Y independently represents a substituted or unsubstituted anilino group or a substituted or unsubstituted naphthylamino group; and b is 0 to 2.9, c is 0.1 to 3 and the sum of b and c is 1 to 3) which has a good hue as a cyan ink, is excellent in light fastness, ozone fastness and moisture fastness, and does not cause bronze phenomenon, as well as is thus suitable for inkjet recording.
摘要翻译： 本发明涉及由下式（1）表示的四氮杂卟啉色素：（其中，A，B，C和D独立地表示具有芳香性的6元环，至少一个或多个为苯环，至少 一个或多个含有含氮杂芳环;此外，E表示亚烷基，X和Y各自独立地表示取代或未取代的苯胺基或取代或未取代的萘基氨基; b为0〜2.9，c为0.1〜 3，b和c之和为1〜3）作为青色墨水具有良好的色相，耐光性，耐臭氧性和耐湿牢度优异，不会引起青铜现象，因此适用于喷墨 记录。
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