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公开(公告)号:US20130197290A1
公开(公告)日:2013-08-01
申请号:US13641710
申请日:2011-04-18
IPC分类号: B01J29/44
CPC分类号: B01J29/44 , B01J29/40 , B01J29/405 , B01J35/0006 , B01J35/002 , B01J35/023 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J37/0009 , B01J37/0207 , B01J37/04 , B01J37/08 , B01J37/30 , B01J2229/16 , B01J2229/186 , B01J2229/20 , B01J2229/32 , B01J2229/42 , C07C4/18 , C07C15/04 , C07C2529/40 , C07C2529/44 , C10G35/065 , C10G35/09 , C10G2300/1096 , C10G2400/30 , Y02P20/52
摘要: Process for preparing a catalyst support which process comprises a) mixing pentasil zeolite having a bulk silica to alumina molar ratio in the range of from 20 to 150 with water, a silica source and an alkali metal salt, b) extruding the mixture obtained in step (a), c) drying and calcining the extrudates obtained in step (b), d) subjecting the calcined extrudates obtained in step (c) to ion exchange to reduce the alkali metal content, and e) drying the extrudates obtained in step (d); process for preparing a catalyst by furthermore impregnating such support with platinum in an amount in the range of from 0.001 to 0.1 wt % and tin in an amount in the range of from 0.01 to 0.5 wt %, each on the basis of total catalyst; ethylbenzene dealkylation catalyst obtainable thereby and a process for dealkylation of ethylbenzene which process comprises contacting feedstock containing ethylbenzene with such catalyst.
摘要翻译: 制备催化剂载体的方法,该方法包括:a)将水分二氧化硅源和碱金属盐与本体二氧化硅与氧化铝摩尔比为20-150的pentasil沸石混合,b)将步骤 (a)中,c)干燥和煅烧步骤(b)中获得的挤出物,d)使步骤(c)中获得的煅烧挤出物进行离子交换以降低碱金属含量,和e)干燥步骤 d); 通过进一步用0.001至0.1重量%的量的铂浸渍这种载体并以0.01-0.5重量%的量,锡的总催化剂为基础,制备催化剂的方法; 乙苯脱烷基化催化剂和乙苯的脱烷基化方法,该方法包括使含有乙苯的原料与这种催化剂接触。
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公开(公告)号:US09604204B2
公开(公告)日:2017-03-28
申请号:US13641710
申请日:2011-04-18
IPC分类号: B01J29/06 , B01J29/44 , B01J29/40 , B01J35/00 , B01J37/00 , B01J37/30 , C07C4/18 , C10G35/06 , C10G35/09
CPC分类号: B01J29/44 , B01J29/40 , B01J29/405 , B01J35/0006 , B01J35/002 , B01J35/023 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J37/0009 , B01J37/0207 , B01J37/04 , B01J37/08 , B01J37/30 , B01J2229/16 , B01J2229/186 , B01J2229/20 , B01J2229/32 , B01J2229/42 , C07C4/18 , C07C15/04 , C07C2529/40 , C07C2529/44 , C10G35/065 , C10G35/09 , C10G2300/1096 , C10G2400/30 , Y02P20/52
摘要: Process for preparing a catalyst support which process comprises a) mixing pentasil zeolite having a bulk silica to alumina molar ratio in the range of from 20 to 150 with water, a silica source and an alkali metal salt, b) extruding the mixture obtained in step (a), c) drying and calcining the extrudates obtained in step (b), d) subjecting the calcined extrudates obtained in step (c) to ion exchange to reduce the alkali metal content, and e) drying the extrudates obtained in step (d); process for preparing a catalyst by furthermore impregnating such support with platinum in an amount in the range of from 0.001 to 0.1 wt % and tin in an amount in the range of from 0.01 to 0.5 wt %, each on the basis of total catalyst; ethylbenzene dealkylation catalyst obtainable thereby and a process for dealkylation of ethylbenzene which process comprises contacting feedstock containing ethylbenzene with such catalyst.
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