公开(公告)号：US3673115A

公开(公告)日：1972-06-27

申请号：US3673115D

申请日：1969-12-30

Applicant: LEVER BROTHERS LTD

Inventor： LINSEN BASTIAAN GERARDUS ,  OSINGA THEO JAN

IPC: B01J21/08 ,  B01J23/755 ,  B01J35/10 ,  B01J37/03 ,  B01J37/18 ,  C07B61/00 ,  C09K5/04 ,  C11C3/12 ,  B01J11/22

CPC classification number: C09K5/041 ,  B01J21/08 ,  B01J23/755 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/031 ,  B01J37/18 ,  Y10S502/509

Abstract: In a process for the preparation of a nickel-on-silica catalyst, the use of an intimate mixture of an organic base, which base is substantially insoluble in the suspension of silica in aqueous nickel salt solution, as a means of withdrawing hydrogen ions from the solution and causing precipitation of nickel from the solution on to the silica carrier.

Abstract translation: 在制备二氧化硅镍催化剂的方法中，使用有机碱的紧密混合物，该有机碱基本上不溶于二氧化硅在镍盐水溶液中的悬浮液，作为将氢离子从 溶液并使镍从溶液沉淀到二氧化硅载体上。

公开(公告)号：US3668148A

公开(公告)日：1972-06-06

申请号：US3668148D

申请日：1970-04-06

Applicant: LEVER BROTHERS LTD

Inventor： BEEK WILHELMUS PETRUS VAN ,  OSINGA THEO JAN

IPC: B01J37/02 ,  B01J23/755 ,  B01J37/03 ,  B01J11/82 ,  B01J11/06

CPC classification number: B01J37/031 ,  B01J23/755 ,  B01J35/0053

Abstract: A process for preparing a catalyst comprising a metallic catalytic agent on a particulate carrier is disclosed which provides improved uniformity of distribution and fineness of division with narrowness of particle size distribution of the metallic catalytic agent on the carrier. The particles of carrier are suspended by agitation in an aqueous solution of a salt of the metallic catalytic agent and of a source, on heating in aqueous solution, of hydroxyl ions. The suspension is heated in a sealed vessel above 100* C to precipitate the metal or the particles with uniformity of distribution and fineness of division with narrowness of particle size distribution. The metal is converted by conventional procedures to the appropriate active, oxidized or reduced, state. The process is particularly significant with carriers, such as alumina and silica, that in alkaline media are liable to undergo structural charges.

Abstract translation: 公开了一种制备包含颗粒载体上的金属催化剂的催化剂的方法，其提供了分散性的均匀性以及载体上的金属催化剂的粒度分布不均匀的分裂细度。 通过搅拌将载体颗粒悬浮在金属催化剂的盐和源的水溶液中，在水溶液中加热羟基离子。 将该悬浮液在高于100℃的密封容器中加热，以均匀分布的细度和粒度分布的狭窄沉淀金属或颗粒。 金属通过常规方法转化为适当的活性，氧化或还原状态。 该方法对于载体如氧化铝和二氧化硅在碱性介质中易于经历结构电荷是特别重要的。

公开(公告)号：US3637529A

公开(公告)日：1972-01-25

申请号：US3637529D

申请日：1970-04-06

Applicant: LEVER BROTHERS LTD

Inventor： BEEK WILHELMUS PETRUS VAN ,  OSINGA THEO JAN

IPC: B01J37/02 ,  B60P1/64 ,  B65D90/14 ,  B66F3/24 ,  B01J11/24

CPC classification number: B60P1/6409 ,  B01J37/0201 ,  B01J37/0203 ,  B65D90/143 ,  B65D90/146 ,  B66F3/24

Abstract: A process for preparing a catalyst comprising a metallic catalytic agent on a particulate carrier is disclosed which provides improved uniformity of distribution and fineness of division with narrowness of particle size distribution of the metallic catalytic agent on the carrier. The carrier is impregnated with an aqueous solution of a salt of the metallic catalytic agent and of a source, on heating in aqueous solution, of hydroxyl ions. The impregnated carrier is heated without substantial loss by evaporation of the aqueous solution to precipitate the metal or the particles with uniformity of distribution and fineness of division with narrowness of particle size distribution. The metal is converted by conventional methods to the appropriate active, oxidized or reduced, state. The process is particularly significant with carriers, such as alumina and silica, that in alkaline media are liable to undergo structural charges.