NEGATIVE ELECTRODE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERY AND METHOD OF PREPARING THE SAME

    公开(公告)号:US20190010057A1

    公开(公告)日:2019-01-10

    申请号:US15748747

    申请日:2017-01-13

    Applicant: LG Chem, Ltd.

    Abstract: The present invention relates to a negative electrode active material for a lithium secondary battery, which comprises graphite having an alkali carbonate layer formed on a surface thereof, wherein the graphite has an ID/IG ratio of 0.05 to 0.3 in Raman spectroscopy, and a method of preparing the same, wherein, since the negative electrode active material for a lithium secondary battery of the present invention includes the graphite having an alkali carbonate layer formed on the surface thereof, the alkali carbonate layer contributes to the formation of a stable solid electrolyte interface (SEI) to reduce a side reaction with an electrolyte solution including propylene carbonate. Thus, since low-temperature performance and initial efficiency of the lithium secondary battery may be improved, the negative electrode active material for a lithium secondary battery of the present invention is suitable for the preparation of the lithium secondary battery.

    NEGATIVE ELECTRODE ACTIVE MATERIAL AND METHOD OF MANUFACTURING THE SAME
    3.
    发明申请
    NEGATIVE ELECTRODE ACTIVE MATERIAL AND METHOD OF MANUFACTURING THE SAME 有权
    负极电极活性材料及其制造方法

    公开(公告)号:US20160322636A1

    公开(公告)日:2016-11-03

    申请号:US15108028

    申请日:2015-06-10

    Applicant: LG CHEM, LTD.

    Abstract: The present invention relates to a negative electrode active material, and a method of manufacturing the same. The negative electrode active material includes a low crystalline artificial graphite and an amorphous carbon coating layer formed on the low crystalline artificial graphite, wherein an interplanar spacing d002 of (002) plane is in a range of greater than 0.338 nm to less than 0.3396 nm, as measured by X-ray diffraction (XRD). When the negative electrode active material according to one exemplary embodiment of the present invention is used for lithium secondary batteries, a more stable SEI layer can be formed during reacting with an electrolyte solution, thereby improving initial efficiency and reversible capacity of the lithium secondary battery.

    Abstract translation: 负极活性物质及其制造方法技术领域本发明涉及负极活性物质及其制造方法。 负极活性物质包含在低结晶人造石墨上形成的低结晶人造石墨和无定形碳涂层,其中(002)面的面间距d002在大于0.338nm〜小于0.3396nm的范围内, 如通过X射线衍射(XRD)测量的。 当根据本发明的一个示例性实施方案的负极活性材料用于锂二次电池时,可以在与电解质溶液反应期间形成更稳定的SEI层,从而提高锂二次电池的初始效率和可逆容量。

    Negative electrode and method for preparing negative electrode

    公开(公告)号:US11114670B2

    公开(公告)日:2021-09-07

    申请号:US16304998

    申请日:2017-10-26

    Applicant: LG CHEM, LTD.

    Abstract: A negative electrode according to one embodiment of the present invention comprises a current collector and a negative electrode active material layer disposed on the current collector, wherein the negative electrode active material layer includes a first particle and a second particle, the first particle includes a first core including artificial graphite; and a first shell disposed on the first core, said first shell including an oxide of the artificial graphite, wherein a sphericity of the first particle measured through a particle shape analyzer is from 0.94 to 0.98, the second particle is artificial graphite having sphericity measured through the particle shape analyzer of 0.70 to 0.92, and a weight ratio of the first particle and the second particle is from 1:1 to 1:9.

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