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    Titanovanadosilicalites as epoxidation catalysts for olefins
    1.
    发明授权
    Titanovanadosilicalites as epoxidation catalysts for olefins 失效
    作为烯烃的环氧化催化剂的钛酸铵

    公开(公告)号：US5744619A

    公开(公告)日：1998-04-28

    申请号：US818265

    申请日：1997-03-17

    申请人： Laszlo T. Nemeth ,  Gregory J. Lewis ,  Richard R. Rosin

    发明人： Laszlo T. Nemeth ,  Gregory J. Lewis ,  Richard R. Rosin

    IPC分类号： C07D301/03 ,  C07D301/12

    CPC分类号： C07D301/12

    摘要： Titanovanadosilicalites have been found to be very selective, active catalysts in the epoxidation of olefins by peroxides. Dilute hydrogen peroxide suffices to afford high yields of the epoxide. Vanadium incorporation at levels of Si:V in the range 100-2500 effectively changes the characteristics of the titanosilicalite into which it is incorporated to give near quantitative conversion of propylene at selectivities greater than 90%.

    摘要翻译： 已经发现，在过氧化物对烯烃的环氧化中，非常有选择性的活性催化剂。 稀释过氧化氢足以提供高产率的环氧化物。 钒含量在100-2500范围内的Si：V水平有效地改变了其掺入其中的钛硅硅沸石的特性，使得选择性大于90％的丙烯接近定量转化。

    Titanostannosilicates and preparation thereof
    2.
    发明授权
    Titanostannosilicates and preparation thereof 失效
    钛酸铵和其制备

    公开(公告)号：US6074624A

    公开(公告)日：2000-06-13

    申请号：US109854

    申请日：1998-07-02

    申请人： Laszlo Nemeth ,  Gregory J. Lewis ,  Richard R. Rosin

    发明人： Laszlo Nemeth ,  Gregory J. Lewis ,  Richard R. Rosin

    IPC分类号： C07D301/12 ,  C01B39/06

    CPC分类号： C07D301/12 ,  Y10S423/22

    摘要： A new family of crystalline titanostannosilicate molecular sieves have been synthesized. These molecular sieves have a microporous three-dimensional framework of TiO.sub.2, SnO.sub.2 and SiO.sub.2 tetrahedral oxide units and are represented by the empirical formula:(Ti.sub.x Sn.sub.y Si.sub.z)O.sub.2where "X", "y" and "z" are the mole fractions of Ti, Sn and Si respectively. These molecular sieves are active catalysts for the epoxidation of olefins by peroxides such as hydrogen peroxide.

    摘要翻译： 已经合成了一种新的结晶钛酸铵分子筛系列。 这些分子筛具有TiO 2，SnO 2和SiO 2四面体氧化物单元的微孔三维框架，并且由经验式（TixSnySiz）O 2表示，其中“X”，“y”和“z”是Ti的摩尔分数， Sn和Si。 这些分子筛是用过氧化物如过氧化氢对烯烃进行环氧化的活性催化剂。

    Titanostannosilicalites: epoxidation of olefins
    3.
    发明授权
    Titanostannosilicalites: epoxidation of olefins 失效
    钛土矿石：烯烃的环氧化

    公开(公告)号：US5780654A

    公开(公告)日：1998-07-14

    申请号：US840531

    申请日：1997-04-22

    申请人： Laszlo Nemeth ,  Gregory J. Lewis ,  Richard R. Rosin

    发明人： Laszlo Nemeth ,  Gregory J. Lewis ,  Richard R. Rosin

    IPC分类号： B01J29/04 ,  C01B39/04 ,  C07B41/04 ,  C07B61/00 ,  C07D301/12 ,  C07D303/04

    CPC分类号： C07D301/12

    摘要： Titanostannosilicalites molecular sieves as new compositions of matter have been found to be very selective, active catalysts in the epoxidation of olefins by peroxides. Dilute hydrogen peroxide suffices to afford high yields of the epoxide with good selectivity. The sieves described within have a unit empirical formula, on an anhydrous basis of (Ti.sub.x Sn.sub.y Si.sub.z)O.sub.2, where 0.0005

    摘要翻译： 已经发现，作为物质的新组合物的Titanostannosilicalites分子筛是非常选择性的，通过过氧化物使烯烃环氧化的活性催化剂。 稀释的过氧化氢足以以良好的选择性提供高产率的环氧化物。 所述筛子具有单位经验公式，以（TixSnySiz）O 2的无水为基准，其中0.0005

    ADSORBENT FOR FEED AND PRODUCTS PURIFICATION IN BENZENE SATURATION PROCESS
    4.
    发明申请
    ADSORBENT FOR FEED AND PRODUCTS PURIFICATION IN BENZENE SATURATION PROCESS 有权
    用于进料和产品的添加剂在苯酐饱和过程中的纯化

    公开(公告)号：US20120004480A1

    公开(公告)日：2012-01-05

    申请号：US13151449

    申请日：2011-06-02

    申请人： Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

    发明人： Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

    IPC分类号： C07C5/10

    CPC分类号： C07C7/12 ,  C07C15/04

    摘要： The service life and deactivation rate of a benzene saturation catalyst is improved through use of a new sulfur guard bed containing a chloride additive. This sulfur guard bed, which contains supported CuO material having an increased resistance to reduction, shows such improvement. Thus, the danger of run-away reduction followed by a massive release of water and deactivation of an isomerization catalyst is practically eliminated. The fact that the guard bed material preserves the active metal phase-copper in an active (oxide) form is an important advantage leading to very low sulfur content in the product stream. The sulfur capacity per unit weight of sorbent is also significantly increased, making this sorbent a superior cost effective sulfur guard product. The guard bed is effective in treating mixed phase feed streams.

    摘要翻译： 通过使用含有氯化物添加剂的新型硫磺保护床，可提高苯饱和催化剂的使用寿命和失活率。 这种含有具有增加的还原性能的负载型CuO材料的硫磺保护床显示出这种改进。 因此，实际上消除了逃逸减少的危险，随后大量释放水并使异构化催化剂失活。 保护床材料以活性（氧化物）形式保留活性金属相铜的事实是导致产物流中硫含量非常低的重要优点。 吸附剂每单位重量的硫含量也显着增加，使得该吸附剂成为一种优异的成本效益的硫磺防护产品。 防护床在处理混合相进料物流中是有效的。

    Adsorbent for feed and products purification in benzene saturation process
    6.
    发明授权
    Adsorbent for feed and products purification in benzene saturation process 有权
    苯饱和过程中的饲料和产品净化用吸附剂

    公开(公告)号：US08314277B2

    公开(公告)日：2012-11-20

    申请号：US13151449

    申请日：2011-06-02

    申请人： Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

    发明人： Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

    IPC分类号： C07C5/10

    CPC分类号： C07C7/12 ,  C07C15/04

    摘要： The service life and deactivation rate of a benzene saturation catalyst is improved through use of a new sulfur guard bed containing a chloride additive. This sulfur guard bed, which contains supported CuO material having an increased resistance to reduction, shows such improvement. Thus, the danger of run-away reduction followed by a massive release of water and deactivation of an isomerization catalyst is practically eliminated. The fact that the guard bed material preserves the active metal phase-copper in an active (oxide) form is an important advantage leading to very low sulfur content in the product stream. The sulfur capacity per unit weight of sorbent is also significantly increased, making this sorbent a superior cost effective sulfur guard product. The guard bed is effective in treating mixed phase feed streams.

    摘要翻译： 通过使用含有氯化物添加剂的新型硫磺保护床，可提高苯饱和催化剂的使用寿命和失活率。 这种含有具有增加的还原性能的负载型CuO材料的硫磺保护床显示出这种改进。 因此，实际上消除了逃逸减少的危险，随后大量释放水并使异构化催化剂失活。 保护床材料以活性（氧化物）形式保留活性金属相铜的事实是导致产物流中硫含量非常低的重要优点。 吸附剂每单位重量的硫含量也显着增加，使得该吸附剂成为一种优异的成本效益的硫磺防护产品。 防护床在处理混合相进料物流中是有效的。

    Adsorbent for feed and products purification in a reforming process
    7.
    发明授权
    Adsorbent for feed and products purification in a reforming process 有权
    在重整过程中用于饲料和产物纯化的吸附剂

    公开(公告)号：US08313641B2

    公开(公告)日：2012-11-20

    申请号：US13151470

    申请日：2011-06-02

    申请人： Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

    发明人： Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

    IPC分类号： C10G35/04 ,  C10G17/00

    CPC分类号： C10G29/04 ,  C10G25/003 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/207

    摘要： The service life and deactivation rate of a reforming catalyst is improved through use of a new sulfur guard bed containing a chloride additive. This sulfur guard bed, which contains supported CuO material having an increased resistance to reduction, shows such improvement. Thus, the danger of run-away reduction followed by a massive release of water causing process upsets in a catalytic reforming process is practically eliminated. The fact that the guard bed material preserves the active metal phase—copper in an active (oxide) form is an important advantage leading to very low sulfur content in the product stream. The sulfur capacity per unit weight of sorbent is also significantly increased, making this sorbent a superior cost effective sulfur guard product.

    摘要翻译： 通过使用含有氯化物添加剂的新型硫磺保护床，可提高重整催化剂的使用寿命和失活率。 这种含有具有增加的还原性能的负载型CuO材料的硫磺保护床显示出这种改进。 因此，实际上消除了催化重整过程中逃逸减少的危险，随后大量释放水引起过程紊乱。 保护床材料以活性（氧化物）形式保留活性金属相铜的事实是导致产物流中硫含量非常低的重要优点。 吸附剂每单位重量的硫含量也显着增加，使得该吸附剂成为一种优异的成本效益的硫磺防护产品。