公开(公告)号：US20120004480A1

公开(公告)日：2012-01-05

申请号：US13151449

申请日：2011-06-02

Applicant: Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

Inventor： Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

IPC: C07C5/10

CPC classification number: C07C7/12 ,  C07C15/04

Abstract: The service life and deactivation rate of a benzene saturation catalyst is improved through use of a new sulfur guard bed containing a chloride additive. This sulfur guard bed, which contains supported CuO material having an increased resistance to reduction, shows such improvement. Thus, the danger of run-away reduction followed by a massive release of water and deactivation of an isomerization catalyst is practically eliminated. The fact that the guard bed material preserves the active metal phase-copper in an active (oxide) form is an important advantage leading to very low sulfur content in the product stream. The sulfur capacity per unit weight of sorbent is also significantly increased, making this sorbent a superior cost effective sulfur guard product. The guard bed is effective in treating mixed phase feed streams.

Abstract translation: 通过使用含有氯化物添加剂的新型硫磺保护床，可提高苯饱和催化剂的使用寿命和失活率。 这种含有具有增加的还原性能的负载型CuO材料的硫磺保护床显示出这种改进。 因此，实际上消除了逃逸减少的危险，随后大量释放水并使异构化催化剂失活。 保护床材料以活性（氧化物）形式保留活性金属相铜的事实是导致产物流中硫含量非常低的重要优点。 吸附剂每单位重量的硫含量也显着增加，使得该吸附剂成为一种优异的成本效益的硫磺防护产品。 防护床在处理混合相进料物流中是有效的。

公开(公告)号：US20100018906A1

公开(公告)日：2010-01-28

申请号：US12177851

申请日：2008-07-22

Applicant: Mark P. Lapinski ,  Richard R. Rosin

Inventor： Mark P. Lapinski ,  Richard R. Rosin

IPC: C10G45/00 ,  B01D53/94 ,  C01B31/18

CPC classification number: B01D53/864 ,  B01D53/02 ,  B01D2251/202 ,  B01D2253/108 ,  B01D2255/1026 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2256/16 ,  B01D2256/24 ,  B01D2257/502 ,  B01J23/96 ,  B01J38/10 ,  C10G35/06

Abstract: One exemplary embodiment can be a process for lowering an amount of carbon monoxide in a stream rich in hydrogen. The process can include passing the stream rich in hydrogen through a carbon monoxide removal zone to produce a product stream having no more than about 10 vppm carbon monoxide and communicating the product stream to a reduction zone receiving a catalyst comprising unreduced metal species.

Abstract translation: 一个示例性实施方案可以是用于降低富含氢气的一氧化碳的量的方法。 该方法可以包括使富含氢的物流通过一氧化碳去除区，以产生具有不超过约10vppm一氧化碳的产物流，并将产物流连通至含有未还原金属物质的催化剂的还原区。

公开(公告)号：US08404105B2

公开(公告)日：2013-03-26

申请号：US13025631

申请日：2011-02-11

Applicant: Mark P. Lapinski ,  Gregory J. Gajda ,  Jeffry T. Donner ,  Richard R. Rosin ,  Marc R. Scheier ,  Simon R. Bare

Inventor： Mark P. Lapinski ,  Gregory J. Gajda ,  Jeffry T. Donner ,  Richard R. Rosin ,  Marc R. Scheier ,  Simon R. Bare

IPC: C10G35/04

CPC classification number: C10G35/085 ,  C10G35/095 ,  C10G35/24

Abstract: One exemplary embodiment can be a process for facilitating a transfer of a metal catalyst component from at least one donor particle to at least one recipient particle in a catalytic naphtha reforming unit. The process can include transferring an effective amount of the metal catalyst component from the at least one donor particle to the at least one recipient particle under conditions to effect such transfer to improve a conversion of a hydrocarbon feed.

Abstract translation: 一个示例性实施方案可以是促进金属催化剂组分从催化石脑油重整单元中的至少一个供体颗粒转移至至少一个受体颗粒的方法。 该方法可以包括在有效量的金属催化剂组分从至少一个供体颗粒转移到至少一个受体颗粒的条件下进行这种转移以提高烃进料的转化率。

公开(公告)号：US20120000825A1

公开(公告)日：2012-01-05

申请号：US13151470

申请日：2011-06-02

Applicant: Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

Inventor： Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

IPC: C10G29/04

CPC classification number: C10G29/04 ,  C10G25/003 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/207

Abstract: The service life and deactivation rate of a reforming catalyst is improved through use of a new sulfur guard bed containing a chloride additive. This sulfur guard bed, which contains supported CuO material having an increased resistance to reduction, shows such improvement. Thus, the danger of run-away reduction followed by a massive release of water causing process upsets in a catalytic reforming process is practically eliminated. The fact that the guard bed material preserves the active metal phase—copper in an active (oxide) form is an important advantage leading to very low sulfur content in the product stream. The sulfur capacity per unit weight of sorbent is also significantly increased, making this sorbent a superior cost effective sulfur guard product.

Abstract translation: 重整催化剂的使用寿命和失活率是通过使用含有氯添加剂的新硫保护床的改进。 这个硫保护床，其包含支持的CuO材料具有还原增加的电阻，示出了这种改进。 因此，失控减少随后的水在催化重整工艺造成过程紊乱释放出大量的危险实际上消除。 保护床材料以活性（氧化物）形式保留活性金属相铜的事实是导致产物流中硫含量非常低的重要优点。 每吸附剂的单位重量的硫容量也显著增加，使得该吸附剂优越的成本效益的防硫产物。

公开(公告)号：US20110136655A1

公开(公告)日：2011-06-09

申请号：US13025631

申请日：2011-02-11

Applicant: Mark P. Lapinski ,  Gregory J. Gajda ,  Jeffry T. Donner ,  Richard R. Rosin ,  Marc R. Schreier ,  Simon R. Bare

Inventor： Mark P. Lapinski ,  Gregory J. Gajda ,  Jeffry T. Donner ,  Richard R. Rosin ,  Marc R. Schreier ,  Simon R. Bare

IPC: B01J38/00 ,  B01J23/90

CPC classification number: C10G35/085 ,  C10G35/095 ,  C10G35/24

Abstract: One exemplary embodiment can be a process for facilitating a transfer of a metal catalyst component from at least one donor particle to at least one recipient particle in a catalytic naphtha reforming unit. The process can include transferring an effective amount of the metal catalyst component from the at least one donor particle to the at least one recipient particle under conditions to effect such transfer to improve a conversion of a hydrocarbon feed.

Abstract translation: 一个示例性实施方案可以是促进金属催化剂组分从催化石脑油重整单元中的至少一个供体颗粒转移至至少一个受体颗粒的方法。 该方法可以包括在有效量的金属催化剂组分从至少一个供体颗粒转移到至少一个受体颗粒的条件下进行这种转移以提高烃进料的转化率。

公开(公告)号：US20100116714A1

公开(公告)日：2010-05-13

申请号：US12269366

申请日：2008-11-12

Applicant: Mark P. Lapinski ,  Richard R. Rosin ,  Marc R. Schreier

Inventor： Mark P. Lapinski ,  Richard R. Rosin ,  Marc R. Schreier

IPC: C10G35/06

CPC classification number: C10G35/06 ,  B01J23/08 ,  B01J27/13 ,  B01J27/32 ,  B01J38/02 ,  B01J38/10 ,  B01J38/44 ,  B01J38/48 ,  B01J38/60 ,  C10G35/085 ,  C10G2300/1044 ,  C10G2300/70

Abstract: One exemplary embodiment can be a process for facilitating adding a promoter metal to at least one catalyst particle in situ in a catalytic naphtha reforming unit. The process can include introducing a compound comprising the promoter metal to the catalyst naphtha reforming unit and adding an effective amount of the promoter metal from the compound comprising the promoter metal to the catalyst particle under conditions to effect such addition and improve a conversion of a hydrocarbon feed.

Abstract translation: 一个示例性实施方案可以是促进助催化剂金属在催化石脑油重整单元中原位加入至少一种催化剂颗粒的方法。 该方法可以包括将催化剂石脑油重整单元引入包含助催化剂金属的化合物，并且在实施这种添加的条件下将有效量的助催化剂金属从包含促进剂金属的化合物加入催化剂颗粒中，并改善烃的转化率 饲料。

公开(公告)号：US07687049B2

公开(公告)日：2010-03-30

申请号：US12177851

申请日：2008-07-22

Applicant: Mark P. Lapinski ,  Richard R. Rosin

Inventor： Mark P. Lapinski ,  Richard R. Rosin

IPC: B01D53/94 ,  C01D3/06

CPC classification number: B01D53/864 ,  B01D53/02 ,  B01D2251/202 ,  B01D2253/108 ,  B01D2255/1026 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2256/16 ,  B01D2256/24 ,  B01D2257/502 ,  B01J23/96 ,  B01J38/10 ,  C10G35/06

Abstract: One exemplary embodiment can be a process for lowering an amount of carbon monoxide in a stream rich in hydrogen. The process can include passing the stream rich in hydrogen through a carbon monoxide removal zone to produce a product stream having no more than about 10 vppm carbon monoxide and communicating the product stream to a reduction zone receiving a catalyst comprising unreduced metal species.

Abstract translation: 一个示例性实施方案可以是用于降低富含氢气的一氧化碳的量的方法。 该方法可以包括使富含氢的物流通过一氧化碳去除区，以产生具有不超过约10vppm一氧化碳的产物流，并将产物流连通至含有未还原金属物质的催化剂的还原区。

公开(公告)号：US5439864A

公开(公告)日：1995-08-08

申请号：US172980

申请日：1993-12-27

Applicant: Richard R. Rosin ,  Steven A. Bradley

Inventor： Richard R. Rosin ,  Steven A. Bradley

IPC: B01J20/20 ,  B01J21/18 ,  B01J35/10

CPC classification number: B01J20/20 ,  B01J21/18 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/109

Abstract: This invention relates to a shaped composition composed of a carbonaceous pyropolymer having recurring units containing at least carbon and hydrogen atoms. The composition is characterized by a crush strength of at least 6 kg and has a bimodal pore distribution having maxima at pore diameters of about 60 to 900 .ANG. and about 120 to 160 .ANG..

Abstract translation: 本发明涉及由具有至少含有碳原子和氢原子的重复单元的含碳焦聚合物组成的成形组合物。 该组合物的特征在于至少6kg的压碎强度，并且具有在孔直径为约60至900安培和约120至160安培的情况下具有最大值的双峰孔分布。

公开(公告)号：US08314277B2

公开(公告)日：2012-11-20

申请号：US13151449

申请日：2011-06-02

Applicant: Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

Inventor： Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

IPC: C07C5/10

CPC classification number: C07C7/12 ,  C07C15/04

Abstract: The service life and deactivation rate of a benzene saturation catalyst is improved through use of a new sulfur guard bed containing a chloride additive. This sulfur guard bed, which contains supported CuO material having an increased resistance to reduction, shows such improvement. Thus, the danger of run-away reduction followed by a massive release of water and deactivation of an isomerization catalyst is practically eliminated. The fact that the guard bed material preserves the active metal phase-copper in an active (oxide) form is an important advantage leading to very low sulfur content in the product stream. The sulfur capacity per unit weight of sorbent is also significantly increased, making this sorbent a superior cost effective sulfur guard product. The guard bed is effective in treating mixed phase feed streams.

Abstract translation: 通过使用含有氯化物添加剂的新型硫磺保护床，可提高苯饱和催化剂的使用寿命和失活率。 这种含有具有增加的还原性能的负载型CuO材料的硫磺保护床显示出这种改进。 因此，实际上消除了逃逸减少的危险，随后大量释放水并使异构化催化剂失活。 保护床材料以活性（氧化物）形式保留活性金属相铜的事实是导致产物流中硫含量非常低的重要优点。 吸附剂每单位重量的硫含量也显着增加，使得该吸附剂成为一种优异的成本效益的硫磺防护产品。 防护床在处理混合相进料物流中是有效的。

公开(公告)号：US08313641B2

公开(公告)日：2012-11-20

申请号：US13151470

申请日：2011-06-02

Applicant: Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

Inventor： Vladislav I. Kanazirev ,  Jayant K. Gorawara ,  Dana K. Sullivan ,  Richard R. Rosin

IPC: C10G35/04 ,  C10G17/00

CPC classification number: C10G29/04 ,  C10G25/003 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/207

Abstract: The service life and deactivation rate of a reforming catalyst is improved through use of a new sulfur guard bed containing a chloride additive. This sulfur guard bed, which contains supported CuO material having an increased resistance to reduction, shows such improvement. Thus, the danger of run-away reduction followed by a massive release of water causing process upsets in a catalytic reforming process is practically eliminated. The fact that the guard bed material preserves the active metal phase—copper in an active (oxide) form is an important advantage leading to very low sulfur content in the product stream. The sulfur capacity per unit weight of sorbent is also significantly increased, making this sorbent a superior cost effective sulfur guard product.

Abstract translation: 通过使用含有氯化物添加剂的新型硫磺保护床，可提高重整催化剂的使用寿命和失活率。 这种含有具有增加的还原性能的负载型CuO材料的硫磺保护床显示出这种改进。 因此，实际上消除了催化重整过程中逃逸减少的危险，随后大量释放水引起过程紊乱。 保护床材料以活性（氧化物）形式保留活性金属相铜的事实是导致产物流中硫含量非常低的重要优点。 吸附剂每单位重量的硫含量也显着增加，使得该吸附剂成为一种优异的成本效益的硫磺防护产品。