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    EPOXIDISED ELASTOMER COMPOSITIONS MODIFIED BY SILANES
    1.
    发明申请
    EPOXIDISED ELASTOMER COMPOSITIONS MODIFIED BY SILANES 审中-公开
    由SILANES改性的环氧化弹性体组合物

    公开(公告)号：US20140031487A1

    公开(公告)日：2014-01-30

    申请号：US13883101

    申请日：2011-11-03

    申请人： Laurent Guy ,  Thomas Chaussee

    发明人： Laurent Guy ,  Thomas Chaussee

    IPC分类号： C08F279/02

    CPC分类号： C08F279/02 ,  B60C1/00 ,  C08F253/00 ,  C08F230/08

    摘要： This invention relates to the modification of elastomers especially epoxidised rubber by reaction with unsaturated silanes, to the modified elastomers produced and to articles produced by shaping and curing modified elastomer compositions. In a process according to the present invention, the silane has the formula: R″—CH═CH—C(O)X—Y—SiRaR′(3-a)  (I) or R″—C≡C—C(O)X—Y—SiRaR′(3-a)  (II) in which R, R′, a, Y, X and R″ are as defined in the description.

    摘要翻译： 本发明涉及通过与不饱和硅烷反应的弹性体，特别是环氧化橡胶的改性，所制备的改性弹性体和通过改性和固化改性弹性体组合物制备的制品。 在根据本发明的方法中，硅烷具有下式：R“-CH = CH-C（O）XY-SiRaR'（3-a）（I）或R”-C = CC（O） 其中R，R'，a，Y，X和R“如说明书中所定义的XY-SiRaR'（3-a）（II）

    Elastomer Compositions Modified By Silanes
    2.
    发明申请
    Elastomer Compositions Modified By Silanes 审中-公开
    由硅烷改性的弹性体组合物

    公开(公告)号：US20120065319A1

    公开(公告)日：2012-03-15

    申请号：US13318115

    申请日：2010-04-28

    申请人： Michael Backer ,  Thomas Chaussee ,  Francois De Buyl ,  Valerie Smits

    发明人： Michael Backer ,  Thomas Chaussee ,  Francois De Buyl ,  Valerie Smits

    IPC分类号： C08L43/04 ,  C08F291/02

    CPC分类号： C08F253/00 ,  B60C1/00 ,  C08C19/25 ,  C08C19/28 ,  C08F279/02 ,  C08K3/36 ,  C08K5/5425 ,  C08K5/548 ,  C08L51/04 ,  C08F230/08 ,  C08L15/00 ,  C08L7/00 ,  C08L2666/02

    摘要： This invention relates to the modification of elastomers by reaction with unsaturated silanes, to the modified elastomers produced and to articles produced by shaping and curing modified elastomer compositions. It also relates to the use of unsaturated silanes as coupling agents in filled elastomer compositions. In a process according to the present invention, the silane has the formula: R″—CH═CH—C(O)X—Y—SiRaR′(3-a) (I) or R″—C≡C—C(O)X—Y—SiRaR′(3-a) (II) in which R represents a hydrolysable group; R′ represents a hydrocarbyl group having 1 to 6 carbon atoms; a has a value in the range 1 to 3 inclusive; Y represents a divalent organic spacer linkage comprising at least one carbon atom separating the linkage —C(O)X— from the Si atom, X is selected from S or O; and R″ represents hydrogen or a group having an electron withdrawing effect with respect to the —CH═CH— or —C≡C— bond. This provides silanes able to react efficiently with a diene elastomer in the presence of a free radical initiator.

    摘要翻译： 本发明涉及通过与不饱和硅烷反应对所生产的改性弹性体和通过改性和固化改性弹性体组合物制备的制品来改性弹性体。 它还涉及在填充的弹性体组合物中使用不饱和硅烷作为偶联剂。 在根据本发明的方法中，硅烷具有下式：R“-CH = CH-C（O）X-Y-SiRaR'（3-a）（I）或R”-C≡C-C O）X-Y-SiRaR'（3-a）（II）其中R表示可水解基团; R'表示碳原子数1〜6的烃基。 a的值在1到3的范围内; Y表示包含至少一个碳原子的二价有机间隔键，所述碳原子与Si原子分开连接-C（O）X，X选自S或O; 并且R“表示氢或相对于-CH = CH-或-C≡C-键具有吸电子作用的基团。 这提供能够在自由基引发剂存在下与二烯弹性体有效反应的硅烷。

    Elastomer Compositions Modified By Silanes
    3.
    发明申请
    Elastomer Compositions Modified By Silanes 审中-公开
    由硅烷改性的弹性体组合物

    公开(公告)号：US20120059121A1

    公开(公告)日：2012-03-08

    申请号：US13266917

    申请日：2010-04-28

    申请人： Michael Backer ,  Thomas Chaussee ,  Francois De Buyl ,  Valerie Smits

    发明人： Michael Backer ,  Thomas Chaussee ,  Francois De Buyl ,  Valerie Smits

    IPC分类号： C08C19/25 ,  C08K3/36 ,  C08F136/14 ,  C08L15/00

    CPC分类号： C08C19/25 ,  B60C1/00 ,  C08C19/28 ,  C08F279/02 ,  C08K3/36 ,  C08K5/5425 ,  C08K5/548 ,  C08F230/08 ,  C08L15/00 ,  C08L7/00

    摘要： This invention relates to the modification of elastomers by reaction with unsaturated silanes, to the modified elastomers produced and to articles produced by shaping and curing modified elastomer compositions. In a process according to the present, the silane has the formula: R″—CH═CH—C(O)X—Y—SiRaR′(3-a) (I) or R″—C≡C—C(O)X—Y—SiRaR′(3-a) (II) in which R represents a hydrolysable group; R′ represents a hydrocarbyl group having 1 to 6 carbon atoms; a has a value in the range 1 to 3 inclusive; Y represents a divalent organic spacer linkage comprising at least one carbon atom separating the linkage —C(O)X— from the Si atom, X is S or O; and R″ represents hydrogen or a group having an electron withdrawing effect with respect to the —CH═CH— or —C═C— bond; and the silane is reacted with the diene elastomer in the absence of any free radical initiator. This is advantageous because free radical initiators such as peroxides tend to degrade diene elastomers. In addition, safe handling and mixing of peroxides can be difficult for rubber compounders. The grafted diene elastomer produced has improved adhesion to substrates, for example reinforcing cords and fabrics used as reinforcement in rubber articles such as tyres.

    摘要翻译： 本发明涉及通过与不饱和硅烷反应对所生产的改性弹性体和通过改性和固化改性弹性体组合物制备的制品来改性弹性体。 在根据本发明的方法中，硅烷具有下式：R“-CH = CH-C（O）X-Y-SiRaR'（3-a）（I）或R”-C≡C-C ）X-Y-SiRaR'（3-a）（II）其中R表示可水解基团; R'表示碳原子数1〜6的烃基。 a的值在1到3的范围内; Y表示包含至少一个碳原子的二价有机间隔键，所述碳原子与Si原子分开连接-C（O）X，X是S或O; 并且R“表示氢或相对于-CH = CH-或-C≡C-键具有吸电子作用的基团; 并且在不存在任何自由基引发剂的情况下，硅烷与二烯弹性体反应。 这是有利的，因为诸如过氧化物的自由基引发剂倾向于降解二烯弹性体。 另外，对于橡胶混合机，过氧化物的安全处理和混合可能是困难的。 生产的接枝二烯烃弹性体具有改善的与基材的粘合性，例如用作橡胶制品如轮胎中的增强材料的增强帘线和织物。