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23 条记录 (耗时 0.018 秒)

    Process for producing polyhydric alcohols and derivatives
    1.
    发明授权
    Process for producing polyhydric alcohols and derivatives 失效
    多元醇及其衍生物的制造方法

    公开(公告)号：US4199521A

    公开(公告)日：1980-04-22

    申请号：US882395

    申请日：1978-03-01

    申请人： Leonard Kaplan ,  Roy L. Pruett

    发明人： Leonard Kaplan ,  Roy L. Pruett

    IPC分类号： C07C29/158 ,  C07C27/06 ,  C07C29/16

    CPC分类号： C07C29/158

    摘要： This invention relates to an improved process for the manufacture of such valuable chemicals as polyhydric alcohols by the reaction of synthesis gas, i.e., a mixture of hydrogen and carbon monoxide, in the presence of a rhodium carbonyl complex wherein the improvement comprises effecting said reaction in the presence of copper and/or its salts.

    摘要翻译： 本发明涉及在羰基铑络合物的存在下通过合成气（即氢气和一氧化碳的混合物）的反应制备诸如多元醇的有价值化学物质的改进方法，其中改进包括进行所述反应 铜和/或其盐的存在。

    Separation and recovery of unsaturated hydrocarbons by copper (I) complexes
    2.
    发明授权
    Separation and recovery of unsaturated hydrocarbons by copper (I) complexes 失效
    铜（I）配合物分离和回收不饱和烃

    公开(公告)号：US4434317A

    公开(公告)日：1984-02-28

    申请号：US492225

    申请日：1983-05-06

    申请人： Gerald Doyle ,  Roy L. Pruett ,  David W. Savage

    发明人： Gerald Doyle ,  Roy L. Pruett ,  David W. Savage

    IPC分类号： C07C7/152 ,  C07C7/156

    CPC分类号： C07C7/152

    摘要： Alkenes, alkynes or mixtures thereof are removed from feedstreams by a process which comprises contacting the feedstream with a solution of a cuprous fluorinated acetylacetone in an organic solvent containing stabilizing agent to remove alkene, alkyne or mixture thereof by forming a first cuprous complex, decomposing the first cuprous complex whereby stabilizing agent replaces alkene or alkyne in the first cuprous complex to form a second cuprous complex, and separating the displaced component. The formation of the second cuprous complex avoids any deposition of copper metal upon heating.

    摘要翻译： 烯烃，炔烃或其混合物通过一种方法从进料流中除去，该方法包括使进料流与含氟的含氟乙酰丙酮的有机溶剂中的溶液接触，以除去烯烃，炔烃或其混合物，形成第一个亚铜络合物，分解 第一亚铜络合物，由此稳定剂代替第一亚铜络合物中的烯烃或炔烃以形成第二亚铜络合物，并分离置换的组分。 第二种亚铜络合物的形成避免了加热时铜金属的任何沉积。

    Rhodium-catalyzed oxidation process for producing carboxylic acids
    7.
    发明授权
    Rhodium-catalyzed oxidation process for producing carboxylic acids 失效
    用于制备羧酸的铑催化氧化方法

    公开(公告)号：US4343950A

    公开(公告)日：1982-08-10

    申请号：US225527

    申请日：1981-01-16

    申请人： Rocco A. Fiato ,  Roy L. Pruett

    发明人： Rocco A. Fiato ,  Roy L. Pruett

    IPC分类号： B01J31/18 ,  C07C45/50 ,  C07C51/145 ,  C07C51/235

    CPC分类号： B01J31/1875 ,  C07C45/50 ,  C07C51/145 ,  C07C51/235 ,  B01J2531/822

    摘要： A one-step process is disclosed for forming a carboxylic acid and its anhydride directly from the corresponding olefin which comprises reacting the olefin with carbon monoxide, hydrogen and oxygen in the presence of a stable rhodium complex catalyst. The rhodium catalyst is stabilized by a pentavalent Group V ligand, such as a phosphine oxide. The reaction is preferably conducted in an inert organic solvent. In an alternate embodiment, a carboxylic acid may be obtained by oxidation of an aldehyde (produced, for example, by hydroformylation of the corresponding olefin) in the presence of a rhodium complex catalyst stabilized by a pentavalent Group V ligand. This reaction is also preferably conducted in an inert organic solvent.

    摘要翻译： 公开了从相应的烯烃直接形成羧酸及其酸酐的一步法，该方法包括使烯烃与一氧化碳，氢和氧在稳定的铑配位催化剂存在下反应。 铑催化剂由五价V族配体如氧化膦稳定。 该反应优选在惰性有机溶剂中进行。 在替代实施方案中，羧酸可以通过在由五价V族配体稳定的铑配合物催化剂的存在下，通过氧化醛（例如通过相应的烯烃的加氢甲酰化来制备）获得。 该反应也优选在惰性有机溶剂中进行。

    Cyclic hydroformylation process
    8.
    发明授权
    Cyclic hydroformylation process 失效
    循环加氢甲酰化过程

    公开(公告)号：US4247486A

    公开(公告)日：1981-01-27

    申请号：US776934

    申请日：1977-03-11

    申请人： Everard A. V. Brewester ,  Roy L. Pruett

    发明人： Everard A. V. Brewester ,  Roy L. Pruett

    IPC分类号： C07C45/50 ,  C07C47/02

    CPC分类号： C07C45/50 ,  Y02P20/582

    摘要： Hydroformylating alpha-olefins in a cyclic homogeneous liquid phase process utilizing a modified rhodium catalyst, the improvement which involves utilizing a gas recycle to maintain the liquid level in the reaction and control build-up of high molecular weight components.

    摘要翻译： 在使用改性铑催化剂的环状均相液相方法中加氢甲酰化α-烯烃，其改进涉及利用气体循环以保持反应中的液体水平并控制高分子量组分的积聚。

    Process for producing imines and/or amines from alcohols
    9.
    发明授权
    Process for producing imines and/or amines from alcohols 失效
    从醇生产亚胺和/或胺的方法

    公开(公告)号：US5103058A

    公开(公告)日：1992-04-07

    申请号：US609209

    申请日：1990-11-05

    申请人： Roy L. Pruett ,  Michael J. Keenan ,  Edmund J. Mozeleski

    发明人： Roy L. Pruett ,  Michael J. Keenan ,  Edmund J. Mozeleski

    IPC分类号： B01J23/06 ,  C07B61/00 ,  C07C209/52 ,  C07C209/62 ,  C07C211/03 ,  C07C211/08 ,  C07C249/02 ,  C07C251/08

    CPC分类号： C07C209/62 ,  C07C249/02

    摘要： Process for producing aliphatic imines and/or amines from aliphatic monohydric alcohols, such as higher molecular weight oxo alcohols, including ether alcohols, comprising the steps of dehydrogenating the alcohol to an aldehyde in situ in the presence of a zinc oxide and/or zinc salt/metal hydroxide dehydrogenation catalyst and a soluble amount of a primary aliphatic amine which condenses immediately with the aldehyde under reflux conditions, with continuous water removal, to form the corresponding aliphatic imine (Schiff base). The corresponding aliphatic amine can be formed by reducing or reductively aminating the imine in known manner to form corresponding primary, secondary or tertiary amines as desired. The step of forming the imine is most critical, and the present zinc/metal hydroxide dehydrogenation catalyst system has been found to provide a gentle, inexpensive and efficient conversion of the alcohol to the aldehyde for reaction with the gradually-added primary amine, coupled with the continuous removal of the water of condensation in order to prevent undesired secondary reactions which reduce the yield.

    摘要翻译： 用于由脂族一元醇如高分子量羰基合成醇（包括醚醇）生产脂族亚胺和/或胺的方法，包括以下步骤：在氧化锌和/或锌盐存在下使醇原位脱氢 /金属氢氧化物脱氢催化剂和可溶量的伯脂肪胺，其在回流条件下立即与醛冷凝，并连续除水，形成相应的脂族亚胺（席夫碱）。 相应的脂族胺可以通过以已知方式还原或还原胺化亚胺形成，以根据需要形成相应的伯，仲或叔胺。 形成亚胺的步骤是至关重​​要的，并且已经发现现有的锌/金属氢氧化物脱氢催化剂体系可以提供温和，便宜和有效的醇转化为醛，以与逐渐加入的伯胺反应，加上 连续除去冷凝水，以防止不希望的二次反应降低产率。

    Separation and recovery of carbon monoxide by copper (I) complexes
    10.
    发明授权
    Separation and recovery of carbon monoxide by copper (I) complexes 失效
    铜（I）配合物分离和回收一氧化碳

    公开(公告)号：US4508694A

    公开(公告)日：1985-04-02

    申请号：US492173

    申请日：1983-05-06

    申请人： Gerald Doyle ,  Roy L. Pruett ,  David W. Savage

    发明人： Gerald Doyle ,  Roy L. Pruett ,  David W. Savage

    IPC分类号： B01D53/14 ,  C01B32/40 ,  C07C1/00 ,  C07C7/152 ,  C07C7/156 ,  C07C67/00 ,  B01D53/34

    CPC分类号： C07C7/152

    摘要： Carbon monoxide is removed from feedstreams by a process which comprises contacting the feedstream with a solution of a cuprous fluorinated acetylacetonate in an organic solvent containing a stabilizing agent to remove CO by forming a first cuprous complex, decomposing the first cuprous complex whereby the stabilizing agent which replaces CO in the first cuprous complex to form a second cuprous complex, and separating the displaced CO. The formation of the second cuprous complex avoids any deposition of copper metal upon heating.

    摘要翻译： 从进料流中除去一氧化碳，该方法包括使进料流与含有稳定剂的有机溶剂中的含氟乙酰丙酮化合物的溶液接触，通过形成第一种亚铜络合物除去CO，分解第一种亚铜络合物，由此稳定剂 替代第一个亚铜络合物中的CO以形成第二个亚铜络合物，并分离置换的CO。第二亚铜络合物的形成避免了加热时铜金属的任何沉积。