摘要:
A rapid, centrifugal method to prepare polysilazanes and separate them from their ammonium halide-anhydrous, liquid ammonia by-product is coupled with several, alternative methods to recover ammonium halide and anhydrous, liquid ammonia from the by-product. Some reactive modes of by-product recovery lead to sodium chloride as the sole waste product of, optionally, to ammonia borane as a secondary product of the process.
摘要:
A rapid, centrifugal method to prepare polysilazanes and separate them from their ammonium halide-anhydrous, liquid ammonia by-product is coupled with several, alternative methods to recover ammonium halide and anhydrous, liquid ammonia from the by-product. Some reactive modes of by-product recovery lead to sodium chloride as the sole waste product of, optionally, to ammonia borane as a secondary product of the process.
摘要:
A cosmetic composition which provides a semi-permanent, crosslinked film on a keratinous substrate, comprising a film-forming polymer having functional groups capable of cross-linking upon exposure to a cross-linking agent reactive with the functional groups; a cross-linking agent reactive with the functional groups of the film-forming polymer; a dissipatable blocking agent which is operable prior to dissipation, to block the cross-linking agent from cross-linking the functional groups of the film-forming polymer, and which, after dissipation, leaves the cross-linking agent free to cross-link the functional groups of the film-forming polymer.
摘要:
The compositions of this invention comprise uncrosslinked reaction mixtures comprising (1) at least one organic monomer, oligomer or polymer comprising a multiplicity of organic, electrophilic substituents, and (2) at least one metal-containing polymer comprising a metal-nitrogen polymer.Preferred compositions of this invention comprise reaction mixtures comprising (1) at least one organic monomer, oligomer or polymer comprising a multiplicity of organic, electrophilic substituents, and (2) at least one of: silicon-nitrogen polymers, aluminum-nitrogen polymers and boron-nitrogen and polymer combinations thereof comprising a multiplicity of sequentially bonded repeat units the compositions comprising the reaction products of the reaction mixtures, and the compositions obtained by crosslinking the reaction products of the reaction mixtures. The crosslinking may be effected through at least one of thermal-based, radiation-based free radical-based or ionic-based crosslinking mechanisms. Furthermore, the reaction mixtures, the composition comprising the reaction products and the crosslinked composition may further comprise at least one filler or reinforcement. The composition may be molded or shaped by various techniques into numerous useful articles. Furthermore, the compositions may be applied as coatings by various techniques onto numerous articles to enhance the articles usefulness.
摘要:
Organometallic ceramic precursor binders are used to fabricate shaped bodies by different techniques. Exemplary shape making techniques which utilize hardenable, liquid, organometallic, ceramic precursor binders include the fabrication of negatives of parts to be made (e.g., sand molds and sand cores for metalcasting, etc.), as well as utilizing ceramic precursor binders to make shapes directly (e.g., brake shoes, brake pads, clutch parts, grinding wheels, polymer concrete, refractory patches and liners, etc.). A preferred embodiment of the invention involves the fabrication of preforms used in the formation of composite articles.
摘要:
It has been found that water stable articles, such as films and sheets, can be prepared from chemically delaminated vermiculite platelets if radical or ionically polymerizable organo-substituted onium salts are ionically bonded to the platelets and the resulting system cured.
摘要:
Polysilazane/polysiloxane block copolymers particularly suitable for the preparation of durable, adherent silicon-containing coatings comprising polymeric segments of a polysilazane and polysiloxane are disclosed.
摘要:
A compound of the formula: wherein: n, y, and z are each independently integers ranging from 1 to 100,000; R1 through R6, and R8 are each independently H, C1-6 alkyl, hydroxyalkyl, substituted or unsubstituted aminoalkyl; or R4 and R5 together form a substituted or unsubstituted heterocyclic 5 to 6 membered ring wherein the substituents are selected from C1-6 alkyl, hydroxyalkyl, or aminoalkyl; R7 is H or SR1, or S—R7 in the above formula together form an isothiouronium salt or Bunte salt; X is a linking group; and D is a chromophore that absorbs visible light; hair dye compositions containing the polymeric compound; and a method for dyeing hair.
摘要翻译:下式的化合物:其中:n,y和z各自独立地为1至100,000的整数; R 1至R 6和R 8各自独立地为H,C 1-6烷基,羟基烷基,取代或未取代的氨基烷基; 或R4和R5一起形成取代或未取代的杂环5至6元环,其中取代基选自C 1-6烷基,羟基烷基或氨基烷基; R 7是上式中的H或SR 1或S-R 7一起形成异硫脲 盐或e盐; X为连接基团; D是吸收可见光的发色团; 含有聚合物的染发剂组合物; 和染发方法。
摘要:
A method for improving and/or treating one or more conditions of the skin selected from the group consisting of texture, luminosity, radiance, fine lines, wrinkles, skin pigmentation irregularities, sallowness, and photodamage comprising applying to the skin a cosmetic composition comprising 0.01-30% by weight of the total composition of 3-hydroxybenzoic acid and the compositions used therefor.
摘要:
This invention relates to the discovery of organometallic ceramic precursor binders used to fabricate shaped bodies by different techniques. Exemplary shape making techniques which utilize hardenable, liquid, organometallic, ceramic precursor binders include the fabrication of negatives of parts to be made (e.g., sand molds and sand cores for metalcasting, etc.), as well as utilizing ceramic precursor binders to make shapes directly (e.g., brake shoes, brake pads, clutch parts, grinding wheels, polymer concrete, refractory patches and liners, etc.). In a preferred embodiment, this invention relates to thermosettable, liquid ceramic precursors which provide suitable-strength sand molds sand cores at very low binder levels and which, upon exposure to molten metalcasting exhibit low emissions toxicity as a result of their high char yields of ceramic upon exposure to heat.