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公开(公告)号：US4100212A
公开(公告)日：1978-07-11
申请号：US626000
申请日：1975-10-28
CPC分类号： B01J19/2415 , B01J19/006 , C07C17/10 , B01J2219/00076 , B01J2219/00159 , B01J2219/00164 , B01J2219/00777
摘要： Liquid-phase chlorination of n-paraffins is improved as to yield on chlorine and as to restriction to mono-substitution by passing the paraffins up a reactor divided into stages by baffles and feeding chlorine in controlled amounts to each stage.
摘要翻译： 改善正链烷烃的液相氯化以产生氯和通过将石蜡上升到通过挡板分成阶段的反应器并以受控量向每个阶段供应氯来限制单取代。
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2.发明授权Novel composition for use in agriculture as soil improvers and fertilizers and process for their production 失效用于农业的新型组合物，作为土壤改良剂和肥料及其生产过程
公开(公告)号：US4071347A
公开(公告)日：1978-01-31
申请号：US631275
申请日：1975-11-12
摘要： Novel compositions for use in agriculture as soil improvers and fertilizers comprising as essential components ammonium sulfate and ferric oxide hydrate. By-products obtained in the production of titanium dioxide from ilmenite or ilmenite slag in the sulfate process and substantially consisting of ferrous sulfate heptahydrate are reacted with ammonia and that the reaction product obtained, consisting substantially of ammonium sulfate and ferrous hydrate, is subsequently oxidized until a composition is obtained which substantially consists of ammonium sulfate and ferric oxide hydrate.
摘要翻译： 用于农业的新型组合物作为土壤改良剂和肥料，其包含作为必需组分的硫酸铵和氧化铁水合物。 在硫酸盐工艺中由钛铁矿或钛铁矿矿渣生产二氧化钛，并且基本上由七水硫酸亚铁组成的副产物与氨反应，并且基本上由硫酸铵和水合铁形成的反应产物随后被氧化直到 获得了基本上由硫酸铵和氧化铁水合物组成的组合物。
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公开(公告)号：US4343957A
公开(公告)日：1982-08-10
申请号：US218333
申请日：1980-12-19
CPC分类号： C07C2/70 , C07C2527/173
摘要： Production of cumene by alkylation of benzene with propylene on a solid phosphoric acid catalyst, using in a first step a plurality of catalyst beds in series and in a second step a single catalyst bed, using an overall benzene/propylene molar ratio of at least 5:1, continuously delivering the benzene to the first bed, continuously delivering a series of streams of liquid propylene respectively to the first bed and, in the form of a cold stream, between each pair of contiguous beds, and carrying out a partial recycle of reaction products of the second step as a cold stream between the first and the second step, and using a benzene/propylene molar ratio higher than 13:1 at the inlet of each bed of the first step, and higher than 25:1 at the inlet of the bed of the second step.
摘要翻译： 通过在固体磷酸催化剂上用丙烷烷基化苯来生产枯烯，在第一步中使用多个催化剂床串联，在第二步中使用单一催化剂床，使用总苯/丙烯摩尔比为至少5 ：1，连续地将苯输送到第一床，连续地将一系列液态丙烯流分别连续地输送到第一床，并以冷流的形式在每对连续的床之间进行，并进行部分循环 在第一步骤和第二步骤之间的第二步骤的反应产物作为冷流，并且在第一步骤的每个床的入口处使用高于13:1的苯/丙烯摩尔比，并且在第 第二步床的入口。
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公开(公告)号：US3946068A
公开(公告)日：1976-03-23
申请号：US862955
申请日：1969-10-01
IPC分类号： B01J27/06 , C07C67/055 , C07C69/15 , C07C67/04
CPC分类号： B01J27/06 , C07C67/055 , Y02P20/584
摘要： The palladium and copper ethylene-oxidation catalysts used in vinyl acetate production are regenerated by a process including a galvanic displacement of the metals from solution and their reconversion to halides.
摘要翻译： 用于乙酸乙烯酯生产中的钯和铜乙烯 - 氧化催化剂通过包括从溶液中电离位移金属及其再转化成卤化物的方法再生。
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公开(公告)号：US4324941A
公开(公告)日：1982-04-13
申请号：US225220
申请日：1981-01-15
CPC分类号： C07C2/70 , C07C2527/173
摘要： Cumene is prepared by alkylation of benzene with propylene in the presence of a solid phosphoric acid catalyst in a continuous process by delivering liquid benzene and liquid propylene in a molar ratio lower than 6:1, to a liquid reaction medium consisting essentially of benzene and cumene and containing the catalyst, while maintaining the temperature and composition of said medium substantially uniform in each point, operating at 170.degree.-280.degree. C. and in the liquid phase, and with a contact time higher than about 0.4 hours, expressed as the ratio between volume of catalyst and hourly volume of reagents fed in.
摘要翻译： 通过在固体磷酸催化剂存在下，通过将液体苯和低于6:1的摩尔比的液体丙烯输送到基本上由苯和异丙基苯组成的液体反应介质，将苯与丙烯烷基化， 并含有催化剂，同时保持所述介质的温度和组成在每个点上基本上均匀，在170℃-280℃和液相下操作，接触时间高于约0.4小时，以比例 催化剂体积和加入的试剂的小时体积。
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公开(公告)号：US3989742A
公开(公告)日：1976-11-02
申请号：US862913
申请日：1969-10-01
IPC分类号： B01J27/06 , C07C67/055 , C07C69/15 , C07C67/05
CPC分类号： B01J27/06 , C07C67/055
摘要： The copper and palladium ethylene-oxidation catalyst used in the preparation of vinyl acetate is regenerated in a process including deposition of the metals from solution in a Daniell-type galvanic cell and subsequent reconversion to the halides.
摘要翻译： 用于制备乙酸乙烯酯的铜和钯乙烯 - 氧化催化剂在包括从Daniell型原电池中的溶液中沉积金属并随后再转化成卤化物的过程中再生。
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公开(公告)号：US3985794A
公开(公告)日：1976-10-12
申请号：US862914
申请日：1969-10-01
IPC分类号： B01J27/06 , B01J31/40 , C07C67/055 , C07C69/15 , C07C67/05
CPC分类号： B01J27/06 , B01J31/30 , B01J31/403 , B01J31/4038 , B01J31/4076 , C07C67/055 , B01J2231/70 , B01J31/04 , Y02P20/584
摘要： Palladium and copper ethylene-oxidation catalysts, used in production of vinyl acetate, are regenerated by a process including electrolytic deposition of the metals and subsequent reconversion to halides.
摘要翻译： 用于生产乙酸乙烯酯的钯和铜乙烯氧化催化剂通过包括电解沉积金属并随后再转化成卤化物的方法再生。
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8.发明授权Compositions for use in agriculture as soil modifiers and their method of manufacture 失效农业用作土壤改性剂的组合物及其制备方法
公开(公告)号：US3936292A
公开(公告)日：1976-02-03
申请号：US509609
申请日：1974-09-26
IPC分类号： C09K17/00 , C01G23/04 , C05D9/02 , C05G3/04 , C09K17/02 , C09K17/06 , C09K101/00 , C05D3/02 , C01G49/02 , C05D9/00
CPC分类号： C05D9/02 , Y10S71/903
摘要： Compositions useful in agriculture as soil modifiers and fertilizers are prepared by contacting the waste materials, obtained in the manufacture of titanium dioxide from ilmenites by the sulphate process, and which consist essentially of ferrous sulphate, with oxides, hydroxides or carbonates of alkali metals or alkaline earth metals or ammonium carbonate, and then submitting the reaction product to oxidation to convert the ferrous hydroxide into ferric hydroxide. Ferric hydroxide is further converted to ferric sulphate by treatment with sulphuric acid.
摘要翻译： 在农业中用作土壤改性剂和肥料的组合物是通过硫酸盐法从钛铁矿制造二氧化钛获得的废物与碱金属或碱的氧化物，氢氧化物或碳酸盐基本上由硫酸亚铁组成的 地球金属或碳酸铵，然后使反应产物氧化，将氢氧化亚铁转化成氢氧化铁。 氢氧化铁通过用硫酸处理进一步转化成硫酸铁。
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9.发明授权
公开(公告)号：US4025549A
公开(公告)日：1977-05-24
申请号：US521101
申请日：1974-11-05
IPC分类号： B01J23/28 , B01J23/30 , B01J23/31 , B01J23/34 , B01J23/88 , B01J23/887 , B01J23/888 , B01J27/186 , B01J35/08 , C07C51/25 , C07C57/05 , C07C57/055 , C07C67/39 , C07C69/54
CPC分类号： C07C51/252 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/34 , B01J23/8877 , B01J23/8878 , B01J23/8885 , B01J27/186 , B01J35/08 , C07C67/39 , B01J2523/00
摘要： Methyl acrylate alone or in mixture with acrylic acid is prepared by passing a gaseous stream containing methanol, acrolein and oxygen at a velocity of 5 to 50 cm/sec through a fluidized catalytic bed formed of spherical particles 15 to 100 .mu. in size, said particles comprising from 10 to 80 wt.% silica support, the remainder consisting of an active catalytic component defined by one of the general formulae:Mo.sub.a V.sub.b Me.sub.c O.sub.xMo.sub.a W.sub.d Me.sub.c O.sub.yMo.sub.a V.sub.b W.sub.d Me.sub.c O.sub.zwherein Me is Cr, Mn, Fe, Co, Ni, Cu, Zn, Ag, Cd, Au, Hg, Na, Ba, Ca, Ce, Bi, Th, U, Pb, Sb, Sn, P or B; and wherein a is a number from 6 to 12, b from 1 to 6, c from 0 to 5, d from 1 to 6, x from 20.5 to 58.5, y from 21 to 61.5 and z from 23.5 to 76.5.
摘要翻译： 单独或与丙烯酸混合的丙烯酸甲酯通过使含有甲醇，丙烯醛和氧气的气流以5至50cm / sec的速度通过由15至100μm尺寸的球形颗粒形成的流化催化床而制备，所述颗粒 包含10至80重量％的二氧化硅载体，其余由由以下通式之一限定的活性催化组分组成：
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10.发明授权Process for preparing methyl acrylate or mixtures of methyl acrylate and acrylic acid 失效制备丙烯酸甲酯或丙烯酸甲酯和丙烯酸的混合物的方法
公开(公告)号：US4014925A
公开(公告)日：1977-03-29
申请号：US521016
申请日：1974-11-05
IPC分类号： B01J23/28 , B01J23/30 , B01J23/88 , C07C45/35 , C07C51/25 , C07C57/055 , C07C67/39 , C07C69/54
CPC分类号： C07C51/252 , B01J23/28 , B01J23/30 , B01J23/887 , B01J23/8876 , B01J23/8877 , C07C45/35 , C07C67/39 , B01J2523/00
摘要： Methyl acrylate or a mixture of methyl acrylate with acrylic acid are prepared by passing through a fluidized bed of catalyst a gaseous mixture comprising acrolein, methanol and oxygen fed at the bottom of the catalytic bed. A further amount of methanol is fed at one intermediate point at least, between the top and bottom of the catalytic bed. The catalyst is defined by one of the general formulae:Mo.sub.a V.sub.b Me.sub.c O.sub.xMo.sub.a W.sub.d Me.sub.c O.sub.yMo.sub.a V.sub.b W.sub.d Me.sub.c O.sub.zWherein Me is Cr, Mn, Fe, Co, Ni, Cu, Zn, Ag, Cd, Au, Hg, Na, Ba, Ca, Ce, Bi, Th, U, Pb, Sb, Sn, P or B; and wherein a is a value from 6 to 12, b from 1 to 6, c from 0 to 5, d from 1 to 6, x from 20.5 to 58.5, y from 21 to 61.5 and z from 23.5 to 76.5.
摘要翻译： 丙烯酸甲酯或丙烯酸甲酯与丙烯酸的混合物是通过催化剂流化床将催化剂底部进料的丙烯醛，甲醇和氧气的气态混合物进行制备的。 至少在催化床的顶部和底部之间的一个中间点进料另外量的甲醇。 催化剂由以下通式之一定义：
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