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公开(公告)号:US6074809A
公开(公告)日:2000-06-13
申请号:US208233
申请日:1998-12-09
申请人: Lydia Simon , Gunter Helling , Beate Weber
发明人: Lydia Simon , Gunter Helling , Beate Weber
IPC分类号: C07D263/56 , G03C7/327 , G03C1/08 , G03C7/26 , G03C7/32
CPC分类号: C07D263/56 , G03C7/3275
摘要: A color photographic silver halide material having a support, at least one photosensitive silver halide emulsion layer and a polymeric cyan coupler associated with the photosensitive silver halide emulsion layer, which coupler contains polymerised units of the formula (I) ##STR1## in which X means a hydrogen atom or a group eliminable under chromogenic development conditions,R.sub.1 means a hydrogen or halogen atom, an optionally substituted alkyl, aryl or acylamino group,R.sub.2 means an optionally substituted alkyl, aryl or heterocyclic group andn means a number from 0 to 3, is distinguished by improved stability of the cyan dye.
摘要翻译: 具有支持体的彩色照相卤化银材料,至少一种光敏卤化银乳剂层和与感光卤化银乳剂层相关联的聚合青色成色剂,该成色剂含有式(I)的聚合单元,其中X表示氢原子 或在显色发展条件下可消除的基团,R 1表示氢或卤素原子,任选取代的烷基,芳基或酰氨基,R 2表示任选取代的烷基,芳基或杂环基,n表示0至3的数, 通过改善青色染料的稳定性。
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公开(公告)号:US5441855A
公开(公告)日:1995-08-15
申请号:US257165
申请日:1994-06-09
申请人: Beate Weber , Jorg Hagemann , Gunter Helling , Markus Geiger
发明人: Beate Weber , Jorg Hagemann , Gunter Helling , Markus Geiger
CPC分类号: G03C7/39216 , C07C39/17 , C08G61/02 , G03C7/396 , G03C2001/03517 , G03C2200/07 , G03C2200/11 , G03C7/3013 , G03C7/36
摘要: A color photographic material which contains in at least one blue-sensitive layer a yellow coupler and a compound of the formula (I) ##STR1## in which R.sub.1 means hydrogen or alkyl,R.sub.2 means hydrogen or alkyl,R.sub.3 means hydrogen or alkyl,1 means 1 to 20X ##STR2## or cycloalkene, R.sub.4 means hydrogen or alkyl,R.sub.5 means hydrogen or alkyl andn means 1 to 6,shows improved light-stability of the yellow dye obtained from said yellow coupler by exposure and processing.
摘要翻译: 在至少一个蓝色敏感层中含有黄色成色剂和式(I)化合物的彩色照相材料,其中R 1表示氢或烷基,R 2表示氢或烷基,R 3表示氢或 烷基,1表示1至20个X或环烯烃,R 4表示氢或烷基,R 5表示氢或烷基,n表示1至6,通过曝光和加工显示由所述黄色成色剂获得的黄色染料的改善的光稳定性 。
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公开(公告)号:US5508157A
公开(公告)日:1996-04-16
申请号:US453665
申请日:1995-05-30
申请人: Beate Weber , Markus Geiger , Gunter Helling , Jorg Hagemann
发明人: Beate Weber , Markus Geiger , Gunter Helling , Jorg Hagemann
CPC分类号: G03C7/3885 , G03C7/3008 , G03C7/39208 , G03C7/39236
摘要: A color photographic silver halide material in which at least one coupler is dissolved or dispersed in a coupler solvent corresponding to the following formula: ##STR1## in which R.sub.1 is alkyl, alkenyl, cycloalkyl or cycloalkenyl,R.sub.2 and R.sub.3 are alkylene or alkenylene,X is CO, NHCO or SO.sub.2,n is 0 or 1 andl, m are numbers of 1 to 5,is distinguished by steep gradation and improved maximum density.
摘要翻译: 一种彩色照相卤化银材料,其中至少一种成色剂溶解或分散在对应于下式的成色剂溶剂中:其中R 1是烷基,烯基,环烷基或环烯基,R 2和R 3是亚烷基或 亚烯基,X是CO,NHCO或SO2,n是0或1,l,m是1到5的数,以陡峭的等级和改进的最大密度来区分。
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公开(公告)号:US5441861A
公开(公告)日:1995-08-15
申请号:US112192
申请日:1993-08-26
申请人: Beate Weber , Gunter Helling , Klaus Walz , Markus Geiger , Kaspar Wingender , Jorg Hagemann
发明人: Beate Weber , Gunter Helling , Klaus Walz , Markus Geiger , Kaspar Wingender , Jorg Hagemann
CPC分类号: G03C7/3882 , G03C7/39216
摘要: A color photographic material with at least one silver halide emulsion layer which contains a color coupler distributed in a polymeric oil former and at least one compound of the formula (I) ##STR1## in which R means alkyl, cycloalkyl, alkenyl, aryl, acyl, alkylsulphonyl or arylsulphonyl,R.sub.1 means a chemical bond or a divalent bridging member,R.sub.2 and R.sub.3 mean alkyl, alkoxy, alkenyl, cycloalkyl, aryl or aryloxy or two residues R.sub.2 or R.sub.3 the remaining atoms of a benzene ring condensed with the phenyl residue andm and n mean 0 to 3, wherein all alkyl, alkoxy, cycloalkyl, alkenyl, aryl, aryloxy and acyl residues may be further substituted,is characterized by improved color stability.
摘要翻译: 一种具有至少一个卤化银乳剂层的彩色照相材料,其含有分布在聚合物油形成剂中的至少一种式(I)化合物(I),其中R表示烷基,环烷基,链烯基, 芳基,酰基,烷基磺酰基或芳基磺酰基,R1表示化学键或二价桥连构件,R2和R3表示烷基,烷氧基,烯基,环烷基,芳基或芳氧基或两个残基R2或R3,苯环的剩余原子与 苯基残基,m和n表示0至3,其中所有烷基,烷氧基,环烷基,烯基,芳基,芳氧基和酰基残基可以进一步被取代,其特征在于改进的颜色稳定性。
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公开(公告)号:US6102997A
公开(公告)日:2000-08-15
申请号:US87183
申请日:1998-05-29
申请人: Gunter Helling , Jorg Hagemann , Beate Weber
发明人: Gunter Helling , Jorg Hagemann , Beate Weber
CPC分类号: B41M5/5227 , C09D11/38 , B41M5/5245
摘要: An ink jet system comprising a recording material and at least one colored ink to be applied to the recording material by means of an ink jet nozzle, characterized in that at least either the material or the at least one colored ink contains at least one water-soluble compound of general formulae (I) or (II): ##STR1## wherein R.sub.1, Z.sub.1, Z.sub.2, Z.sub.3, Z.sub.4, Z.sub.5, Z.sub.6, X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5, R.sub.2, R.sub.3, R.sub.4 and n have the meanings given in the description, are distinguished by improved protection of the ink jet dyes from light.
摘要翻译: 一种喷墨系统,包括记录材料和至少一种通过喷墨嘴施加到记录材料上的着色油墨,其特征在于,所述材料或所述至少一种着色油墨中的至少一种含有至少一种含水油墨, 通式(I)或(II)的可溶性化合物:其中R1,Z1,Z2,Z3,Z4,Z5,Z6,X1,X2,X3,X4,X5,R2,R3,R4和n具有 通过改进喷墨染料对光的保护来区分描述。
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公开(公告)号:US5441862A
公开(公告)日:1995-08-15
申请号:US329886
申请日:1994-10-27
申请人: Beate Weber , Gunter Helling , Markus Geiger
发明人: Beate Weber , Gunter Helling , Markus Geiger
CPC分类号: G03C7/3885
摘要: A color photographic recording material with at least one silver halide emulsion layer and a color coupler associated with that layer, which contains in the silver halide emulsion layer or in an adjacent non-photosensitive binder layer a combination of a color coupler and a compound corresponding to general formula (I) or (II): ##STR1## in which R.sub.4 is the residue of a polymer produced by polycondensation andR.sub.1 to R.sub.3, m and n are as defined in the specification, ##STR2## in which R.sub.4 is as defined above and L.sub.1, L.sub.2, X, R.sub.5 to R.sub.11, p, q and r are as defined in the specification,is distinguished by improved stability of the image dyes produced from yellow couplers.
摘要翻译: 一种彩色照相记录材料,其具有至少一个卤化银乳剂层和与该层相关联的着色剂,其在卤化银乳剂层中或在相邻的非感光性粘合剂层中包含颜色成色剂和对应于 通式(I)或(II):其中R 4是通过缩聚反应制备的聚合物的残基,并且R 1至R 3,m和n如说明书中所定义, 其中R4如上所定义,L1,L2,X,R5至R11,p,q和r如说明书中所定义,其特征在于由黄色成色剂产生的图像染料的改进的稳定性。
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公开(公告)号:US5731138A
公开(公告)日:1998-03-24
申请号:US592692
申请日:1996-01-26
申请人: Gunter Helling , Beate Weber , Markus Geiger
发明人: Gunter Helling , Beate Weber , Markus Geiger
IPC分类号: G03C7/00 , G03C7/30 , G03C7/38 , G03C7/388 , G03C7/392 , G03C7/396 , G03C1/08 , G03C7/26 , G03C7/32
CPC分类号: G03C7/39296 , G03C7/3008 , G03C7/3825 , G03C7/3882 , G03C7/396
摘要: A color photographic material which contains in at least one layer a stabilizer of the formula (I) ##STR1## in which R.sub.1 means H, alkyl, aryl or acyl; R.sub.2 means --OR.sub.1, --COOH, alkyl, aryl, dialkylamino, acylamino, sulphonamido, acyl or sulphonyl; R.sub.3, R.sub.4, R.sub.5 and R.sub.6 independently of one another mean H, halogen or a residue as R.sub.2 or two adjacent residues --OR.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 may together complete a 5- to 8-membered ring, and a polymer insoluble in water as pH 5 and soluble at pH 11 with an acid value of 30 to 300 and a Tg of.ltoreq.40.degree. C. of the formula (II) ##STR2## in which R.sub.7 mutually independently mean hydrogen, C.sub.1 -C.sub.4 alkyl or CH.sub.2 --COOH, R.sub.8 means alkyl, aryl or aralkyl a means 80 to 95 mol. % and b means 5 to 20 mol. %, is distinguished by improved stability of the image dyes.
摘要翻译: 一种彩色照相材料,其在至少一层中含有式(I)r酰基的稳定剂; R2表示-OR1,-COOH,烷基,芳基,二烷基氨基,酰氨基,磺酰氨基,酰基或磺酰基; R 3,R 4,R 5和R 6彼此独立地表示H,卤素或作为R 2或两个相邻残基-OR 1,R 2,R 3,R 4,R 5和R 6的残基可以一起完成5-至8-元环, 不溶于水的聚合物,其pH值为5,在pH值为11,酸值为30至300,Tg为40℃,式(Ⅱ)其中R7相互独立地表示氢 ,C 1 -C 4烷基或CH 2 -COOH,R 8表示烷基,芳基或芳烷基,是指80至95摩尔。 %和b表示5〜20mol。 %,通过改善图像染料的稳定性来区分。
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公开(公告)号:US5674668A
公开(公告)日:1997-10-07
申请号:US704461
申请日:1996-08-26
申请人: Jorg Hagemann , Gunter Helling , Beate Weber
发明人: Jorg Hagemann , Gunter Helling , Beate Weber
CPC分类号: G03C7/3885 , G03C1/005 , G03C1/8155 , Y10S430/132
摘要: A color photographic recording material having at least one silver halide emulsion layer, which material contains in at least one of its layers a combination of at least one UV absorber of the formula I and at least one low molecular weight or polymeric oil formula containing acid groups, for example of the formula T--�R.sup.21 --(Q.sup.1).sub.p !.sub.q --X.sup.21 --OH (II), exhibits improved absorption for UV light. ##STR1## In the formula I: R.sup.1 and R.sup.3 mean H, halogen, hydroxy, mercapto, alkyl, aryl, alkoxy, aryloxy, acyloxy, alkylthio, arylthio, --NR.sup.5 --R.sup.6, alkoxycarbonyl, carbamoyl or sulphamoyl; R.sup.2 means H, hydroxy, halogen or alkyl; R.sup.4 means alkyl, alkoxy, alkylthio, aryloxy, arylthio or a residue of the formula ##STR2## R.sup.5 means H, alkyl or aryl; R.sup.6 means H, alkyl, aryl, acyl, alkoxycarbonyl, carbamoyl, sulphamoyl or sulphonyl; m, n and o mean 1, 2, 3 or 4, wherein two or more residues R.sup.1, R.sup.2 and R.sup.3 are identical or different; in the formula II: X.sup.21 means ##STR3## T means H or a segment of a polymer skeleton; Q.sup.1 and Q.sup.2 mean --O-- or --NR.sup.22 --; R.sup.21 means alkylene or arylene; R.sup.22 means H, alkyl or aryl; p, q and r mean 0 or 1.
摘要翻译: 一种具有至少一个卤化银乳剂层的彩色照相记录材料,该材料在其至少一层中含有至少一种式I的UV吸收剂与至少一种含有酸基团的低分子量或聚合物油配方的组合 ,例如式T- [R21-(Q1)p] q-X21-OH(Ⅱ)表现出改进的UV光吸收。 (I)在式I中,R 1和R 3表示H,卤素,羟基,巯基,烷基,芳基,烷氧基,芳氧基,酰氧基,烷硫基,芳硫基,-NR5-R6,烷氧基羰基,氨基甲酰基或氨磺酰基。 R2表示H,羟基,卤素或烷基; R 4表示烷基,烷氧基,烷硫基,芳氧基,芳硫基或式烷基,芳基,酰基,烷氧基羰基,氨基甲酰基,氨磺酰基或磺酰基的残基; m,n和o表示1,2,3或4,其中两个或多个残基R1,R2和R3相同或不同; 在公式II中:X21表示骨架; Q1和Q2表示-O-或-NR22-; R21表示亚烷基或亚芳基; R22表示H,烷基或芳基; p,q和r表示0或1。
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公开(公告)号:US06207283B1
公开(公告)日:2001-03-27
申请号:US09185150
申请日:1998-11-03
申请人: Peter Bell , Günter Helling , Beate Weber , Ralf Büscher , Lothar Endres , Lothar Rosenhahn , Rainer Scheerer , Lydia Simon , Thomas Stetzer
发明人: Peter Bell , Günter Helling , Beate Weber , Ralf Büscher , Lothar Endres , Lothar Rosenhahn , Rainer Scheerer , Lydia Simon , Thomas Stetzer
IPC分类号: B41M500
CPC分类号: G03C7/396 , B41M5/5272 , C08G63/672 , C08G65/332 , C08G65/3344 , G03C1/043 , Y10T428/273 , Y10T428/31504 , Y10T428/31768
摘要: A polymer of the formula (I): in which X1 means H or (R1)1+1—L1CO—, X2 means —(L2)m—OH or R1 means —COO−M+, —SO3−M+ or (M+)2PO32−, L1 means alkylene, arylene, aralkylene or cycloalkylene, L2 means the residue of a polyether having an average molecular weight of 200 to 3000 (number average), M+ means a cation, l means a number from 0 to 4, m means a number 0 or 1 and n means a number from 0 to 20, wherein m+n is ≧1.
摘要翻译: 式(I)的聚合物:其中X1表示H或(R1)1 + 1-L1CO-,X2表示 - (L2)m-OH或R1表示-COO-M +,-SO3-M +或(M +)2PO32- ,L1表示亚烷基,亚芳基,亚芳基或亚环烷基,L2表示平均分子量为200〜3000(数均)的聚醚的残基,M +表示阳离子,l表示0〜4的数,m表示数 0或1,n表示0至20的数,其中m + n为> = 1。
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公开(公告)号:US06890707B2
公开(公告)日:2005-05-10
申请号:US10612809
申请日:2003-07-02
申请人: Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
发明人: Ralf Weimann , Markus Geiger , Cuong Ly , Klaus Sinzger , Beate Weber , Heinz Wiesen
IPC分类号: G03C5/08 , G03C1/035 , G03C1/09 , G03C5/04 , G03C7/00 , G03C7/30 , G03C7/34 , G03C7/392 , G03C1/08 , G03C7/25 , G03C7/32
CPC分类号: G03C7/346 , G03C1/09 , G03C5/04 , G03C7/30 , G03C7/3022 , G03C7/39204 , G03C2001/03517 , G03C2001/093 , G03C2200/19
摘要: A print material having a support, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the silver halide crystals of the red-sensitive layer have a chloride content of at least 95 mol %, contain 20 to 500 nmol of iridium per mol of silver halide and the cyan coupler is of the formula in which R1 means a hydrogen atom or an alkyl group, R2 means an alkyl, aryl or hetaryl group, R3 means an alkyl or aryl group, R4 means an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z means a hydrogen atom or a group eliminable under the conditions of chromogenic development, is distinguished in that it is equally ideally suitable for analogue and scanning exposure and exhibits very good latent image stability.
摘要翻译: 具有载体的印刷材料,至少一种含有至少一种青色成色剂的感红卤化银乳剂层,至少一种包含至少一种品红成色剂的至少一种感光卤化银乳剂层和至少一种感蓝卤化银乳剂 含有至少一种黄色成色剂的层,其特征在于,红色敏感层的卤化银晶体的氯化物含量为至少95摩尔%,每摩尔卤化银含有20-500nmol的铱,青色成色剂为 其中R 1表示氢原子或烷基的式R 2是指烷基,芳基或杂芳基,R 3表示 烷基或芳基,R 4表示烷基,烯基,烷氧基,芳氧基,酰氧基,酰氨基,磺酰氧基,氨磺酰氨基,亚磺酰氨基,脲基,羟基羰基,羟基羰基氨基,氨基甲酰基,烷硫基,芳硫基,烷基氨基或芳基氨基 基团或氢原子,Z表示氢原子或取代基 在显色发展的条件下,其特征在于它同样理想地适用于模拟和扫描曝光,并且表现出非常好的潜像稳定性。
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