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公开(公告)号：US20140309462A1
公开(公告)日：2014-10-16
申请号：US14357345
申请日：2012-11-09
IPC分类号： C07C17/087 , C07C17/25 , C07C17/38
CPC分类号： C07C17/38 , B01J27/12 , B01J27/135 , B01J37/26 , C07C17/087 , C07C17/206 , C07C17/25 , C07C19/10 , C07C21/18
摘要： The present disclosure provides a fluorination process which involves reacting a hydrohaloalkene of the formula RfC—Cl═CH2 with HF in a reaction zone in the presence of a fluorination catalyst selected from the group consisting of TaF5 and TiF4 to produce a product mixture containing a hydrohaloalkane of the formula RfCFClCH3, wherein Rf is a perfluorinated alkyl group.
摘要翻译： 本公开提供了一种氟化方法，其涉及在选自TaF 5和TiF 4的氟化催化剂的存在下，在反应区中使式RfC-Cl = CH 2的氢卤代烯烃与HF反应，以产生含有氢卤代烷烃的产物混合物 式RfCFClCH 3，其中Rf是全氟化烷基。
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公开(公告)号：US08487145B2
公开(公告)日：2013-07-16
申请号：US13417582
申请日：2012-03-12
申请人： Mario Joseph Nappa , Andrew Jackson
发明人： Mario Joseph Nappa , Andrew Jackson
IPC分类号： C07C17/00
CPC分类号： C07C17/25 , B01J23/26 , B01J35/1019 , C07C21/18
摘要： Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) contacting 1,1,1,2,3-pentafluoropropane with a catalyst comprised of chromium (III) oxide having a surface area of at least 150 m2/g and having an alkali metal loading of at least 7 milligrams of alkali metal per 100 square meters of catalyst surface area, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in (a).
摘要翻译： 公开了一种制备2,3,3,3-四氟丙烯的方法，包括：（a）将1,1,1,2,3-五氟丙烷与由表面积为 至少150m2 / g，并且每100平方米的催化剂表面积具有至少7毫克碱金属的碱金属负荷，以产生包含2,3,3,3-四氟丙烯和氟化氢的产物混合物; 和（b）从（a）中制备的产物混合物回收所述2,3,3,3-四氟丙烯。
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公开(公告)号：US20120172638A1
公开(公告)日：2012-07-05
申请号：US13172987
申请日：2011-06-30
CPC分类号： C07C17/25 , B01J23/26 , B01J37/0036 , B01J37/038 , C07C21/18
摘要： Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) contacting 1,1,1,2,tetrafluoro-2-chloropropane with a catalyst comprised of chromium (III) oxide, and at least 1% of an alkali metal, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in step (a) above.
摘要翻译： 公开了一种制备2,3,3,3-四氟丙烯的方法，其包括：（a）将1,1,1,2，四氟-2-氯丙烷与由氧化铬（III）组成的催化剂和至少 1％的碱金属，以制备包含2,3,3,3-四氟丙烯的产物混合物; 和（b）从上述步骤（a）中制备的产物混合物中回收所述2,3,3,3-四氟丙烯。
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公开(公告)号：US20100312025A1
公开(公告)日：2010-12-09
申请号：US12792969
申请日：2010-06-03
申请人： MARIO JOSEPH NAPPA , Andrew Jackson
发明人： MARIO JOSEPH NAPPA , Andrew Jackson
IPC分类号： C07C17/23
摘要： Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) dehydrofluorinating 1,1,1,2,3-pentafluoropropane in the presence of a dehydrofluorination catalyst comprised of chromium (III) oxide, and alkali metal, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene and less than 20 parts per hundred 1,3,3,3-tetrafluoro-1-propene; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in (a).
摘要翻译： 公开了一种制备2,3,3,3-四氟丙烯的方法，包括：（a）在由氧化铬（III）组成的脱氟化氢催化剂存在下，将1,1,1,2,3-五氟丙烷脱氟化氢，和 碱金属，以制备包含2,3,3,3-四氟丙烯和少于20份/ 100,3,3,3-四氟-1-丙烯的产物混合物; 和（b）从（a）中制备的产物混合物回收所述2,3,3,3-四氟丙烯。
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公开(公告)号：US08227649B2
公开(公告)日：2012-07-24
申请号：US13188787
申请日：2011-07-22
申请人： Mario Joseph Nappa , Andrew Jackson
发明人： Mario Joseph Nappa , Andrew Jackson
IPC分类号： C07C17/00
摘要： Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) contacting 1,1,1,2,3-pentafluoropropane with a catalyst comprised of chromium (III) oxide and from 0.1% to 2% of an alkali metal disposed on the surface of said catalyst, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in (a).
摘要翻译： 公开了一种制备2,3,3,3-四氟丙烯的方法，包括：（a）将1,1,1,2,3-五氟丙烷与由氧化铬（III）和0.1％至2 设置在所述催化剂表面上的碱金属的％，以产生包含2,3,3,3-四氟丙烯和氟化氢的产物混合物; 和（b）从（a）中制备的产物混合物回收所述2,3,3,3-四氟丙烯。
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公开(公告)号：US09102580B2
公开(公告)日：2015-08-11
申请号：US14357345
申请日：2012-11-09
IPC分类号： C07C17/087 , C07C17/25 , C07C17/38 , C07C17/20 , B01J37/26 , B01J27/12 , B01J27/135
CPC分类号： C07C17/38 , B01J27/12 , B01J27/135 , B01J37/26 , C07C17/087 , C07C17/206 , C07C17/25 , C07C19/10 , C07C21/18
摘要： The present disclosure provides a fluorination process which involves reacting a hydrohaloalkene of the formula RfC—Cl═CH2 with HF in a reaction zone in the presence of a fluorination catalyst selected from the group consisting of TaF5 and TiF4 to produce a product mixture containing a hydrohaloalkane of the formula RfCFClCH3, wherein Rf is a perfluorinated alkyl group.
摘要翻译： 本公开提供了一种氟化方法，其涉及在选自TaF 5和TiF 4的氟化催化剂的存在下，在反应区中使式RfC-Cl = CH 2的氢卤代烯烃与HF反应，以产生含有氢卤代烷烃的产物混合物 式RfCFClCH 3，其中Rf是全氟化烷基。
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公开(公告)号：US08586804B2
公开(公告)日：2013-11-19
申请号：US13278511
申请日：2011-10-21
IPC分类号： C07C17/25
摘要： Disclosed is a process for the dehydrochlorination of 1,1,1,3-tetrachloropropane comprising contacting 1,1,1,3,tetrachloropropane in the vapor phase in a reaction zone with a catalyst comprising iron, to produce a product mixture comprising 1,1,3-trichloro-1-propene; and recovering said 1,1,3-trichloro-1-propene from the product mixture produced. Also disclosed is a process for the dehydrochlorination of 1,1,1,3-tetrachloropropane comprising heating 1,1,1,3-tetrachloropropane in the liquid phase to produce a mixture comprising 1,1,3-trichloro-1-propene, cooling said mixture, separating hydrogen chloride from said mixture and recovering 1,1,3-trichloro-1-propene.
摘要翻译： 公开了1,1,1,3-四氯丙烷的脱氯化氢的方法，包括使反应区中的气相中的1,1,1,3，四氯丙烷与包含铁的催化剂接触，以产生包含1， 1,3-三氯-1-丙烯; 并从所生产的产物混合物回收所述1,1,3-三氯-1-丙烯。 还公开了1,1,1,3-四氯丙烷的脱氯化氢的方法，包括在液相中加热1,1,1,3-四氯丙烷以产生包含1,1,3-三氯-1-丙烯， 冷却所述混合物，从所述混合物中分离出氯化氢并回收1,1,3-三氯-1-丙烯。
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公开(公告)号：US20120172639A1
公开(公告)日：2012-07-05
申请号：US13417582
申请日：2012-03-12
申请人： MARIO JOSEPH NAPPA , Andrew Jackson
发明人： MARIO JOSEPH NAPPA , Andrew Jackson
IPC分类号： C07C17/25
CPC分类号： C07C17/25 , B01J23/26 , B01J35/1019 , C07C21/18
摘要： Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) contacting 1,1,1,2,3-pentafluoropropane with a catalyst comprised of chromium (III) oxide having a surface area of at least 150 m2/g and having an alkali metal loading of at least 7 milligrams of alkali metal per 100 square meters of catalyst surface area, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in (a).
摘要翻译： 公开了一种制备2,3,3,3-四氟丙烯的方法，包括：（a）将1,1,1,2,3-五氟丙烷与由表面积为 至少150m2 / g，并且每100平方米的催化剂表面积具有至少7毫克碱金属的碱金属负荷，以产生包含2,3,3,3-四氟丙烯和氟化氢的产物混合物; 和（b）从（a）中制备的产物混合物回收所述2,3,3,3-四氟丙烯。
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公开(公告)号：US07985884B2
公开(公告)日：2011-07-26
申请号：US12792969
申请日：2010-06-03
申请人： Mario Joseph Nappa , Andrew Jackson
发明人： Mario Joseph Nappa , Andrew Jackson
IPC分类号： C07C17/00
摘要： Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) dehydrofluorinating 1,1,1,2,3-pentafluoropropane in the presence of a dehydrofluorination catalyst comprised of chromium (III) oxide, and alkali metal, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene and less than 20 parts per hundred 1,3,3,3-tetrafluoro-1-propene; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in (a).
摘要翻译： 公开了一种制备2,3,3,3-四氟丙烯的方法，包括：（a）在由氧化铬（III）组成的脱氟化氢催化剂存在下，将1,1,1,2,3-五氟丙烷脱氟化氢，和 碱金属，以制备包含2,3,3,3-四氟丙烯和少于20份/ 100,3,3,3-四氟-1-丙烯的产物混合物; 和（b）从（a）中制备的产物混合物回收所述2,3,3,3-四氟丙烯。
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公开(公告)号：US08263817B2
公开(公告)日：2012-09-11
申请号：US13172987
申请日：2011-06-30
IPC分类号： C07C17/25
CPC分类号： C07C17/25 , B01J23/26 , B01J37/0036 , B01J37/038 , C07C21/18
摘要： Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) contacting 1,1,1,2,tetrafluoro-2-chloropropane with a catalyst comprised of chromium (III) oxide, and at least 1% of an alkali metal, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in step (a) above.
摘要翻译： 公开了一种制备2,3,3,3-四氟丙烯的方法，其包括：（a）将1,1,1,2，四氟-2-氯丙烷与由氧化铬（III）组成的催化剂和至少 1％的碱金属，以制备包含2,3,3,3-四氟丙烯的产物混合物; 和（b）从上述步骤（a）中制备的产物混合物中回收所述2,3,3,3-四氟丙烯。
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